WARCO PREMIUM LUBRICANTS
MATERIAL SAFETY DATA SHEET
WARCO DOT 3 BRAKE FLUID
1 of 6
Any Questions Call: Emergency Telephone: NFPA/HMIS Hazard Code
(24 HOURS) 4=Extreme Health=0/0
Warco Products Inc.
3=High Fire=1/1
(A subsidiary of API International, Inc.)
12505 SW Herman Rd. CHEMTREC 2=Moderate Reactivity=0/0
Tualatin, OR 97062 USA (800) 424 9300 1=Slight Personal
Tel: (503) 692-3800
Protection Index: NA
0=Insignificant
1. CHEMICAL PRODUCT IDENTIFICATION
COMMON NAME: Dot 3 Brake Fluid (H-130) (00209111)
Glycol ether blend
CHEMICAL NAME:
NA - Mixture
FORMULA:
NA - Mixture
PRODUCT CAS NO.:
2. INGREDIENTS: COMPOSITION/INFORMATION
% LD 50/LC 50
INGREDIENT WEIGHT PEL-OSHA TLV-ACGIH ROUTE/SPECIES
Triethylene glycol monobutyl ether 25.00 - 29.00 None None
LD50: 5300 mg/kg
CAS No.: 143-22-6 Established Established
oral/rat
RTECS No.: KJ9450000
Diethylene glycol 16.00 - 20.00 None None LD50: 12565 mg/kg
CAS No.: 111-46-6 Established Established oral/rat
RTECS No.: ID5950000
Diethylene glycol monobutyl ether 10.00 - 14.00 None None LD50: 5660 mg/kg
CAS No.: 112-34-5 Established Established oral/rat
RTECS No.: KJ19100000
Polyethylene glycol hexylether 11.00 - 15.00 None None LD50: 2400 mg/kg
CAS No.: 112-59-4 Established Established oral/rat
RTECS No.: KL2625000
Diethylene glycol monopropyl ether 2.00 - 6.00 None None
No Data
CAS No.: 6881-94-3 Established Established
RTECS No.: No Data
Triethylene glycol monomethyl ether 7.00 - 11.00 None None
LD50: 11300 mg/kg
CAS No.: 112-35-6 Established Established
oral/rat
RTECS No.: KL6390000
Polyethylene glycol 4.00 - 8.00 None None
LD50: 22 gm/kg
CAS No.: 25322-68-3 Established Established
iv/rat
RTECS No.: TQ3500000
Triethylene glycol ethyl ether 2.00 - 6.00 None None
LD50: 7750 mg/kg
CAS No.: 112-50-5 Established Established
oral/rat
RTECS No.: KK8950000
Triethylene glycol 1.00 - 5.00 None None
LD50: 17 gm/kg
CAS No.: 112-27-6 Established Established
oral/rat
RTECS No.: YE4550000
Diethylene glycol methyl ether 0.00 - 4.00 No Data No Data LD50: 4 mL/kg
CAS No.: 111-77-3 oral/rat
RTECS No.: KL6125000
WARCO PREMIUM LUBRICANTS
MATERIAL SAFETY DATA SHEET
WARCO DOT 3 BRAKE FLUID
2 of 6
LD50: 5500 mg/kg
Diethylene glycol monoethyl ether 3.00 - 6.00 None None
oral/rat
CAS No.: 111-90-0 Established Established
RTECS No.: KK8750000
100 mg/m3 (C)
Ethylene glycol 0.00 - 4.00 50 ppm (ceiling)
L50: 4700 mg/kg
CAS No.: 107-21-1
oral/rat
RTECS No.: KW2975000
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Non-flammable amber liquid with mild odor which may cause severe eye irritation and possible damage. Inhalation and ingestion may
affect the central nervous system (CNS) and damage the kidneys. Skin contact may cause irritation. Inhalation is not expected due to
low volatility; however, airborne mists or fumes are toxic if inhaled. Avoid skin and eye contact.
POTENTIAL HEALTH EFFECTS
EYE: Contact may cause severe irritation, conjunctivitis, and diminished sensation. Diethylene glycol monobutyl ether may damage the
cornea.
SKIN: Skin contact may cause irritation. Brake fluid may be slowly absorbed through the skin. Excessive exposure for extended periods
of time involving large areas of skin would be necessary for absorption of harmful amounts.
INGESTION: Product contains approximately 2% ethylene glycol which is toxic via ingestion. Ingestion of substantial quantities may
adversely affect the central nervous system (CNS), lungs, liver and kidneys. Lethal kidney damage has followed ingestion of ethylene
glycol. Hepatotoxicity is common following ingestion of diethylene glycol.
INHALATION: Inhalation is not expected due to the relatively low volatility of this product. Inhalation of fumes or mists caused by heating
or agitating may cause respiratory irritation. High concentrations may cause CNS depression or kidney damage.
SIGNS AND SYMPTOMS: Eye contact can cause irritation, redness, swelling, and tear formation. Information concerning overexposure
to glycol ethers is generally from substantial ingestion in adults. Symptoms of overexposure may be delayed and can include nausea,
vomiting, diarrhea, CNS stimulation followed by depression, hyperventilation, and metabolic acidosis.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Overexposure may aggravate pre-existing eye and skin conditions.
CHRONIC EFFECTS: Repeated inhalation, ingestion or skin absorption of glycol ethers over time may result in toxicity symptoms and
may adversely affect the liver and kidneys. Chronic glycol ether inhalation has resulted in tremor, lethargy, headache, blurred vision,
personality changes and coma.
Medical Surveillance: If overexposure is suspected, kidney function tests and nervous system examination may be advisable.
CARCINOGENICITY: NTP: No IARC: No OSHA: No
4. FIRST AID MEASURES
EYE CONTACT: Remove contact lenses at once, flush eyes with water for 15 minutes. Seek medical attention.
SKIN CONTACT: Wash thoroughly with soap and water and remove contaminated clothing. If irritation persists, seek medical attention.
INHALATION: If overcome by mists or fumes, remove to fresh air. If breathing is difficult administer oxygen. If breathing has stopped,
WARCO PREMIUM LUBRICANTS
MATERIAL SAFETY DATA SHEET
WARCO DOT 3 BRAKE FLUID
3 of 6
give artificial respiration. Seek medical attention.
OTHER: Ingestion of small amounts should not be harmful. If substantial quantities are ingested, seek medical attention immediately.
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
FLASH POINT: > 210 潞F
NFPS HAZARD CLASSIFICATION:
HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0
LEL: No Data UEL: No Data
FLAMMABLE LIMITS:
EXTINGUISHING MEDIA: Non-flammable. Vapors may be flammable when exposed to heat, sparks or flames. Apply water spray and/or
foam gently to surface of liquid to avoid frothing from water turning to steam below the liquid surface. Frothing may be violent. Do not use
direct stream.
FIRE FIGHTING EQUIPMENT: Firefighters should wear a NIOSH/MSHA approve full-facepiece, self-contained breathing apparatus operated
in positive pressure mode and full turnout gear.
6. ACCIDENTAL RELEASE MEASURES
Absorb small spills with suitable sorbent material and place in tightly closed containers for later disposal. For large spills, isolate hazard
area and deny entry to unauthorized or unprotected personnel. Dike well ahead of spill with suitable sorbent material. Clean-up personnel
should wear personal protective equipment appropriate for the magnitude of exposure
7. HANDLING AND STORAGE
Store in cool, well ventilated area away from oxidizers and ignition sources. Do not eat, drink or smoke in areas where this product is
being used or stored. Avoid skin contact. Do not let brake fluid get in the eyes. Wash hands thoroughly after handling and before breaks
and meals.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
RESPIRATORY PROTECTION: Under normal working conditions at or below the PEL, none is required. Respiratory protection
is dependent upon the magnitude of exposure and should be selected in accordance with 29 CFR Part 1910.134. For
concentrations of ethylene glycol to 500 ppm, a NIOSH-MSHA-approved dust-mist respirator with organic vapor cartridge should
be worn.
SKIN PROTECTION: Appropriate gloves, apron, etc., as necessary to prevent contact.
EYE PROTECTION: Splash proof goggles should be worn when the possibility of contact exists
PERSONNEL SAMPLING PROCEDURE:
Air sampling for total particulates: Pre-weighed polyvinyl chloride filter, 5.0 碌m pore size (NIOSH 0500)
WARCO PREMIUM LUBRICANTS
MATERIAL SAFETY DATA SHEET
WARCO DOT 3 BRAKE FLUID
4 of 6
Air sampling for ethylene glycol: Glass fiber filter and XAD-7 tube (NIOSH 5523)
ENGINEERING CONTROLS: General ventilation. Local exhaust when product is heated or agitated.
9. PHYSICAL AND CHEMICAL PROPERTIES
Clear, light amber liquid
APPEARANCE:
Mild
ODOR:
BOILING POINT: 450 掳F or greater
No Data
VAPOR PRESSURE:
No Data
VAPOR DENSITY:
Soluble
SOLUBILITY IN WATER:
1.028-1.036
SPECIFIC GRAVITY:
No Data
FREEZING POINT:
9.5-10.5
pH:
% VOLATILE: No Data
No Data
VAPOR DENSITY:
10. STABILITY AND REACTIVITY
STABILITY: Avoid heat. Some polyethylene glycols have a solvent action on certain plastics.
INCOMPATIBILITY: Explosive hydrogen gas is released when diethylene glycol is mixed with sodium hydroxide at high temperatures.
Diethylene glycol ethers and ethylene glycol may react with oxidizing materials such as permanganates and dichromates when exposed to
heat or flames.
HAZARDOUS DECOMPOSITION PRODUCTS: No Data
HAZARDOUS POLYMERIZATION: Will not occur.
11. TOXICOLOGICAL INFORMATION
INGESTION: Lethal doses (LDLo) of 398 mg/kg to 16 g/kg have been reported for ethylene glycol in man. It has been estimated that the
single oral dose of diethylene glycols resulting in lethality in humans is approximately 1 ml/kg. Deaths in animals from ingestion of
diethylene glycol monomethyl ether and diethylene glycol monopentyl ether occurred at high dosages and were caused by renal injury or
CNS depression.
SKIN: Experimental data in animals show mild to severe skin irritation associated with exposure to glycol ethers.
EYE: Limited data was available. Eye effects for various ingredients were described as mild to severe without further qualification.
Triethylene glycol monobutyl ether may damage the eyes.
INHALATION: A TCLo of 10000 mg/m3 was reported for human inhalation of ethylene glycol. Cyanosis, excitement and general
anesthetic behavior were exhibited. An LCLo of 130 mg/m3 /2H was reported for mouse inhalation of diethylene glycol.
WARCO PREMIUM LUBRICANTS
MATERIAL SAFETY DATA SHEET
WARCO DOT 3 BRAKE FLUID
5 of 6
CHRONIC: Long-term exposure to diethylene glycol has resulted in tumors in laboratory animals, (oral/rat).
SUB-CHRONIC: Rats in an inhalation experiment with diethylene glycol mono-n-butyl ether (5 mg/m3 /24H/17 W-C) exhibited changes in
the brain and coverings and blood. Mice orally dosed with ethylene glycol (546 gm/kg/13 W-C) exhibited adverse effects of the liver, kidney,
ureter, and bladder as well as weight loss or decreased weight gain. Rabbit inhalation of ethylene glycol (12 mg/m3 /8H/90-D-I) resulted in
various effects including corneal damage and death in the multiple dose data field.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL FATE: Ethers generally do not absorb light in the UV spectrum and are resistant to hydrolysis. Direct photolysis in the
atmosphere and hydrolysis in water and soil are probably not significant degradative processes for the ethers in this product.
Environmental fate data for glycols present in this product was unavailable. It is indicated that important fate processes for diethylene glycol
mono-butyl ether may include biodegradation in soil and water and reactions with photochemically produced hydroxyl radicals in the
atmosphere.
13. DISPOSAL CONSIDERATIONS
Recycle, reclaim and dispose of in accordance with applicable local, state and federal regulations. Dispose per 40 CFR Part 261 and 262.
14. TRANSPORT INFORMATION
TRANSPORTATION AND HAZARDOUS MATERIALS DESCRIPTION
DOT: Not classified.
15. REGULATORY INFORMATION
OSHA HAZARD COMMUNICATION RULE. 29 CFR 1910.1200:
This product is considered hazardous under the criteria of this rule.
SARA HAZARD CATEGORY: This product has been reviewed according to the EPA Hazard Categories promulgated under Sections 311
and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered under applicable definitions, to
meet the following categories: Immediate Health Hazard
CERCLA/SUPERFUND, 40 CFR 117, 302:
This product contains glycol ethers and ethylene glycol, Reportable Quantity (RQ) Substances and if 1+ pounds are released, notification to
the National Response Center in Wash., D.C.: (1-800-424-8802) is required.
SARA 313 INFORMATION:
This product contains the following substances subject to the reporting requirements of section 313 of Title III of the Superfund Amendments
and Reauthorization Act of 1986 and 40 CFR Part 372:
CHEMICAL NAME CAS NUMBER
ethylene glycol 107-21-1
WARCO PREMIUM LUBRICANTS
MATERIAL SAFETY DATA SHEET
WARCO DOT 3 BRAKE FLUID
6 of 6
glycol ethers 1 Not Applicable
1
Includes mono- and di-ethers of ethylene glycol, diethylene glycol and triethylene glycol. Polymers are excluded from the glycol ether
category.
SARA 302 (EHS): None
CALIFORNIA PROPOSITION 65: This product does not contain ingredients known to the State of California to cause cancer or reproductive
toxicity.
CANADIAN WHMIS: D2B
16. OTHER INFORMATION
ACGIH American Conference of Governmental Industrial Hygienists
CAS: Chemical Abstracts Service
(C): Ceiling Limit
DOT: Department of Transportation
IARC: International Agency for Research on Cancer
MSHA: Mine Safety and Health Administration
NFPA: National Fire Protection Association
NIOSH: National Institute for Occupational Safety and Health
NTP: National Toxicology Program
OSHA: Occupational Safety and Health Administration
PEL: Permissible Exposure Limit
DISCLAIMER
The information in this MATERIAL SAFETY DATA SHEET should be provided to all who will use,
handle, store, transport, or otherwise be exposed to this material. This information has been
prepared for the guidance of plant engineering, operations and management, and for persons
working with or handling this material. The manufacturer believes this information to be reliable
and up-to-date as of the date of publication, but makes no warranty that it is.
PNOC: Particulate Not Otherwise Classified
PNOR: Particulate Not Otherwise Regulated
SARA: Superfund Amendment and Reauthorization Act
TLV: Threshold Limit Value
Revision Date 6/2/98 New product formulation
|