WARCO PREMIUM LUBRICANTS
MATERIAL SAFETY DATA SHEET
Warco Hydraulic Oils
05/06/2008
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Any Questions Call: Emergency Telephone: NFPA/HMIS Hazard Code
(24 HOURS)
4=Extreme Health=0/0
Warco Products Inc.
3=High Fire=1/1
CHEMTREC
(A subsidiary of API
2=Moderate Reactivity=0/0
(800) 424 9300
International, Inc.)
1=Slight Personal
12505 SW Herman Rd.
Protection Index: NA
0=Insignificant
Tualatin, OR 97062 USA
Tel: (503) 692-3800
SECTION 1 CHEMICAL PRODUCT AND
COMPANY IDENTIFICATION
PRODUCT NAME 鈥? WARCO HYDRAULIC OIL AW 32, 46, 68, 100
SECTION 2 COMPOSITION/INFORMATION
ON INGREDIENTS
100.0% WARCO HYDRAULIC OIL AW
CONTAINING AMOUNT LIMIT/QTY AGENCY/TYPE
COMPONENTS
LUBRICATING BASE OIL.
SEVERELY REFINED PETROLEUM DISTILLATE
> 98.00% 5 mg/m3 (mist) ACGIH TWA
10 mg/m3 (mist) ACGIH STEL
5mg/m3 (mist) OSHA PEL
The BASE OIL may be a mixture of any of the following: CAS 64741884,
CAS 64741895, CAS64741964, CAS 64741975, CAS 64742525, CAS 64742536,
CAS 64742547, CAS 64742558, CAS 64742570, CAS 64742627, CAS 647426550, or CAS 72623837.
ADDITIVES INCLUDING THE FOLLOWING
<2.00%
ZINC ALKYL DITHIOPHOSPHATE
Chemical Name: PHOSPHRODITHIOIC ACID,O,O-DI-C1-14-ALKYL ESTERS, ZINC SALT
CAS68649423 <1.00% NONE NA
COMPOSITION COMMENT:
All the components of this material are on the Toxic Substance Control
Act Chemical Substances Inventory.
This product fits the ACGIH definition for mineral oil mist. The ACGIH
TLV IS 5 mg/m3, the OSHA PEL is 5mg/m3
WARCO PREMIUM LUBRICANTS
MATERIAL SAFETY DATA SHEET
Warco Hydraulic Oils
05/06/2008
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SECTION 3 HAZARDS IDENTIFICATION
IMMEDIATE HEALTH EFFECTS
EYE:
Not expected to cause prolonged or significant eye irritation.
SKIN:
Contact with the skin is not expected to cause prolonged or significant irritation. Not expected to be
harmful to internal organs if absorbed through the skin. High-Pressure Equipment Information: Accidental
high-velocity injection under the skin of materials of this type may result in serious injury. Seek medical
attention at once should an accident like this occur. The initial wound at the injection site may not appear
to be serious at first; but, if left untreated, could result in disfigurement or amputation of the affected part.
INGESTION:
Not expected to be harmful if swallowed.
INHALATION:
Contains a petroleum-based mineral oil. May cause respiratory irritation or other pulmonary affects
following prolonged or repeated inhalation of oil mist at airborne levels above the recommended mineral
oil mist exposure limit.
SECTION 4 FIRST AID MEASURES
EYE:
No specific first aid measures are required because this material is not expected to cause eye irritation.
As a precaution removes contact lenses, if worn, and flush eyes with water.
SKIN:
No specific first aid measures are required because this material is not expected to be harmful if
swallowed. Do not induce vomiting. As a precaution, give the person a glass of water or milk to drink
and get medical advice. Never give anything by mouth to an unconscious person.
INHALATION:
If exposed to excessive levels of material in the air, move the exposed person to fresh air. Get medical
attention if coughing or respiratory discomfort occurs.
NOTE TO PHYSICIANS:
In an accident involving high-pressure equipment, this product may be injected under the skin. Such an
accident may result in a small, sometimes bloodless, puncture wound. However, because of its driving
force, material injected into a fingertip can be deposited into the palm of the hand. Within 24 hours, there
is usually a great deal of swelling, discoloration, and intense throbbing pain. Immediate treatment at a
surgical emergency center is recommended.
SECTION 5 FIRE FIGHTING MEASURES
FIRE CLASSIFICATION:
Classification (29 CFR 1910, 1200): Not classified by OSHA as flammable or combustible.
FIRE COMMENT:
Leaks/punctures in high pressure systems using materials of this type can create a fire hazard when in
the cicinityof ignition sources (eg. Open flame, pilotlights, sparks, or electric arcs).
FLAMMABLE PROPERTIES:
FLASH POINT: (COC) 365F (180C) Min.
AUTOIGNITION: NDA
WARCO PREMIUM LUBRICANTS
MATERIAL SAFETY DATA SHEET
Warco Hydraulic Oils
05/06/2008
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FLAMMABILITY LIMITS (% by volume in air): Lower: NA Upper: NA
EXTINGUISHING MEDIA
CO2, Dry Chemical, Foam, Water Fog
NFPA RATINGS: Health 0; flammability1; Reactivity 0.
FIRE FIGHTING INSTRUCTIONS:
This material will burn although it is not easily ignited. For fires involving this material, do not enter any
enclosed or confined fire space without proper protective equipment, including self-contained breathing
apparatus.
COMBUSTION PRODUCTS:
Normal combustionforms carbon dioxide and water vapor; incomplete combustion can produce carbon
monoxide.
SECTION 6 ACCIDENTAL RELEASE MEASURES
CHEMTREC EMERGENCY NUMBER (24 hr): (800)424-9300 or (703)527-3887
International Collect Calls Accepted
ACCIDENTAL RELEASE MEASURES:
Stop the source of the leak or release. Clean up releases as soon as possible, observing precautions in
Exposure Controls/Personal Protection. Contain liquid to prevent further contamination of soil, surface
water or groundwater. Clean up small spills using appropriate techniques such as sorbent materials or
pumping. Where feasible and appropriate, remove contaminated soil. Follow prescribed procedures for
reporting and responding to larger releases.
SECTION 7 HANDLING AND STORAGE
DO NOT USE IN HIGH PRESSURE SYSTEMS in the vicinity of flames, sparks and hot surfaces. Use
only in well ventilated areas. Keep container closed.
Container is not designed to contain pressure. Do not use pressure to empty container or it may rupture
with explosive force. Empty containers retain product residue (solid, liquid, and/or vapor) and can be
dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat,
flame, sparks, static electricity, or other sources of ignition. They may explode and cause injury or death.
Empty containers should be completely drained, properly closed, and promptly returned to a drum
reconditioner, or properly disposed of. Avoid contaminating soil or releasing this material into sewage
and drainage systems and bodies of water.
SECTION 8 EXPOSURE CONTROLS/ PERSONAL PROTECTION
GENERAL CONSIDERATIONS :
Consider the potential hazards fo this material (see Section 3), applicable exposure limits, job activities,
and other substance in the work place when designing engineering controls and selecting personal
protective equipment. If engineering controls or work practices are not adequate to prevent exposure to
harmful levels of this material , the personal protective equipment listed below is recommended. The
user should read and understand all instructions and limitations supplied with the equipment since
protection is usually provided for a limited time or under certain circumstances.
ENGINEERING CONTROLS:
WARCO PREMIUM LUBRICANTS
MATERIAL SAFETY DATA SHEET
Warco Hydraulic Oils
05/06/2008
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Use in a well-ventilated area. If user operations generate an oil mist, use process enclosures, local
exhaust ventilation , or other engineering controls to control airborne levels below the recommended
Mineral oil mist exposure limits.
PROTECTIVE PROTECTIVE EQUIPMENT EYE/FACE PROTECTIN:
No special eye protection is normally required. Where splashing is possible, wear safety glasses with
side shields as a good safety practice.
SKIN PROTECTION:
No special protective clothing is normally required. Where splashing is possible, select protective
clothing depending on operations conducted, physical requirements and other substances. Suggested
materials for protective gloves include: < Viton>
Respiratory Protection:
No respiratory protection is normally required, If user operations. If user operations generate an oil mist,
determine if airborne concentrations are below the recommended mineral oil mist exposure limits, If not
wear a NIOSH approved respirator and provides adequate protection from measured concentrations of
this material, Use the following elements for air-purifying respirators: particulate.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL DESCRIPTION:
Pale yellow liquid.
pH: NA
VAPOR PRESSURE: <0.01 mm Hg at 100F
VAPOR DENSITY
(AIR=1): Heavier than air.
BOILING POINT: >600F (>315C)
FREEZING POINT: NA
MELTING POINT: NA
SOLUBILITY: Soluble in hyrdrocarbon solvents; insoluble in water.
SPECIFIC GRAVITY: 0.86 鈥? 0.90 @ 15.6/15.6C
VISCOSITY: 22 鈥? 198 cSt @ 40C (Min.)
SECTION 10 STABILITY AND REACTIVITY
HAZARDOUS DECOMPOSITION PRODUCTS:
H2S may be released at high temperatures.
CHEMICAL STABILITY
Stable.
CONDITIONS TO AVOID:
No data available.
INCOMPATIBILITY WITH OTHER MATERIALS:
May react with strong oxidizing agents, such as chlorates, nitrates, peroxides, etc.
HAZARDOUS POLYMERIZATION:
Polymerization will not occur.
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MATERIAL SAFETY DATA SHEET
Warco Hydraulic Oils
05/06/2008
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SECTION 11 TOXICOLOGICAL INFORMATION
EYE EFFECTS:
The ehe irritation hazard is based on data for a similar material.
SKIN EFFECTS:
The skin irritation hazard is based on data for a similar material
ACUTE ORAL EFFECTS:
The acute oral toxicity is based on data for a similar material.
ACUTE INHALATION EFFECTS:
The acute respiratory toxicity is based on data for a similar material.
ADDITIONAL TOXICOLOGY INFORMATION:
This product contains petroleum base oils which may be refined by various processes including severe
solvent extraction, severe hyrdrotreating. None of the oils requires a cancer warning under the OSHA
Hazard Communication Standard (29 CFR 1910. 1200). These oils have not been listed in the National
Toxicology Program (NTP) Annual Report nor have they been classified by the International Agency for
Research on Cancer (IARC) as; carcinogenic to humans (Group 1), probably carcinogenic to humans
(Group 2A), or possibly carcinogenic to humans (Group 2B).
This product contains zinc alkyl dithiophosphates (ZDDPs). Several ZDDPs have been reported to have
weak mutagenic activity in cultured mammalian cells but only concentrations that were toxic to the test
cells. We do not believe that there is any mutagenic risk to workers exposed to ZDDPs.
SECTION 12 ECOLOGICAL INFORMATION
ECOTOXICITY:
This material is not expected to be harmful to aquatic organisms.
ENVIRONMENTAL FATE:
This material is not expected to be readily biodegradable.
SECTION 13 DISPOSAL CONSIDERATIONS
Oil collection services are available for used oil recycling or disposal. Place contaminated materials in
containers and dispose of in a manner consistent with applicable regulations. Contact your sales
representative or local environmental or health authorities for approved disposal or recycling methods.
SECTION 14 TRANSPORT INFORMATION
The description shown may not apply to all shippling situations. Consult 49CFR, or appropriate
Dangerous Godds Regulations, for additional description requirements (e.g., technical name) and mode-
specific or quantity-specific shipping requirements.
DOT SHIPPING NAME: NONE
DOT HAZARD CLASS: NONE
DOT IDENTIFICATION NUMBER: NONE
DOT PACKING GROUP: N/A
ADDITIONAL INFO: Petroleum Lubricating Oil 鈥? Not Hazardous by U.S. DOT.
ADR/R ID Hazard class 鈥? Not applicable.
WARCO PREMIUM LUBRICANTS
MATERIAL SAFETY DATA SHEET
Warco Hydraulic Oils
05/06/2008
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SECTION 15 REGULATORY INFORMATION
SARA 311 CATEGORIES: 1. Immediate (Acute) Health Effects: NO
2. Delayed (Chronic) Health Effects: NO
3. Fire Hazard: NO
4.Sudden Release of Pressure Hazard: NO
5. Reactivity Hazard: NO
REGULATORY LISTS SEARCHED:
01=SARA 313 11=NJ RTK 22=TSCA Sect 5(a)(2)
02=MASS RTK 12=CERCLA 302.4 23=TSCA Sect 6
03=NTP Carcinogen 13=MN RTK 24=TSCA Sect 12(b)
04=CA Prop 65-Carcin 14=ACGIH TWA 25=TSCA Sect 8(a)
05=CA Prop 65-Repro Tox 15=ACGIH STEL 26=TSCA Sect 8(d)
06=IARC Group 1 16=ACGIH Calc TLV 27=TSCA Sect 4(a)
07=IARC Group2A 17=OSHA PEL 28=Canadian WHMIS
08=IARC Group 2B 18=DOT Marine Pollutant 29=OSHA CEILING
09=SARA 302/304 19=Chevron TWA 30=Chevron STEL
10=PARTK 20=EPA Carcinogen
The following components of this material are found on the regulatory lists indicated.
PHOSPHORODITHIOIC ACID,O,O-DI-C1-14-ALKYL ESTERS, ZINC SALTS is found on lists: 01,11,
SEVERELY REFINED PETROLEUM DISTILLATE is found on lists: 14, 15, 17,
NEW JERSEY RTK CLASSIFICATION:
Under the New Jersey Right-To-Know Act L. 1983 Chapter 315 N.J.S.A. 34:5A-1 et seq., the product is to
be identified as follows:
PETROLEUM OIL
WHMIS CLASSIFICATION:
This product is not considered a controlled product according to the criteria of the Canadian Controlled
Products Regulation.
SECTION 16 OTHER INFORMATION
NFPA RATINGS: Health 0; Flammability 1; Reactivity 0;
HMIS RATIINGS: Health 1; Flammability 1; Reactivity 0;
(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:-Personal Protection Equipment Index
recommendation,
*- Chronic Effect Indicator). These values oare obtained using the guidelines or published evaluations
prepared by the National Fire Protection Association (NFPA) or the National Paint and Coating
Association (for HMIS ratings).
REVISION STATEMENT:
This is a new Material Safety Date Sheet.
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