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MSDS Material Safety Data Sheet
CAS

07-02-0
7440-02-0
7440-47-3
7439-96-5
7439-98-7
7440-50-8
7440-33-7

File Name: content_lincolnelectric_com---4431highalloysaweldingwireslsw.asp
Safety data sheet
ISO 11014-1 / 91/155/EEC

Print: 07-02-05 Doc.No. sds-4431 rev.02
Page 1 of 4
Product name(s): LNS 304H LNS 316L LNS 4462
LNS 304L LNS 318 LNS 4500
LNS 307 LNS 347 LNS CrMn 18/7
LNS 309L LNS 4455 LNS Zeron 100X


1. PRODUCT AND COMPANY DESIGNATION

Product Type SA welding wire
Supplier Lincoln Smitweld B.V.
Address P.O. Box 253
NL-6500 AG Nijmegen
The Netherlands
Telephone +31.243.522.911
Telefax +31.243.522.456

2. DETAILS OF COMPOSITION

Type: Preparation or substance

Dangerous ingredients (if applicable):

Name Concentration CAS-no.
Nickel (metal) < 15 7440-02-0
Chromium and chromium alloys or compounds (as Cr) < 30 7440-47-3
Manganese and/or manganese alloys or compounds(as Mn) < 10 7439-96-5
Molybdenum alloys (as Mo) <5 7439-98-7
Copper (as Cu) <1 7440-50-8
Tungsten and/or alloys (as W) <1 7440-33-7
3. POTENTIAL RISKS

Classification

During welding fumes will be formed. The content is depending on the wire type and the base material.
Primarily iron oxide; secondarily complex oxides of manganese, nickel, chromium, molybdenum, copper
and tungsten may be formed. Also ozone and nitrogen dioxide can be formed by arc radiation.


4. FIRST AID MEASURES

If inhaled Not applicable (During welding fume can be
inhaled: bring patient in fresh air; breath in fresh air
deeply. Contact physician if necessary).
If skin contact occurs Not applicable.
If it comes into contact with eyes Not applicable.
If swallowed Not applicable (During welding: see if inhaled).
Remarks


5. FIRE PREVENTION MEASURES

Suitable extinguishing media All known extinguishing substances may be used.
Remarks
Safety data sheet
ISO 11014-1 / 91/155/EEC

Print: 07-02-05 Doc.No. sds-4431 rev.02
Page 2 of 4
Product name(s): LNS 304H LNS 316L LNS 4462
LNS 304L LNS 318 LNS 4500
LNS 307 LNS 347 LNS CrMn 18/7
LNS 309L LNS 4455 LNS Zeron 100X



6. MEASURE IN CASE OF UNINTENTIONAL RELEASE

Personal protective measures None.
Environmental protection measures No special measures are required.
Cleaning methods Dispose material according to point 13.

7. HANDLING AND STORAGE (for safety)

Handling No special measures are necessary.
Storage
Special requirements No special measures are necessary.
Incompatible products Not applicable.
Packaging material No special requirements.


8. EXPLOSION PREVENTION/PERSONEL PROTECTION


Measures to limit explosions No further measures.


Remark
During welding fumes will be formed. The content is depending on the wire type and the base material.
Primarily iron oxide; secondarily complex oxides of manganese, nickel, chromium, molybdenum,
copper and tungsten may be formed. Also ozone and nitrogen dioxide can be formed by arc radiation.

Possible reaction products:

MAC-value (NL) [mg/m3] TGG 8
CAS-no Description
Welding fume 3,5
7439-96-5 Manganese oxide 1
1313-99-1 Nickel oxide 0,1
CrVI compounds
13765-19-0 0,025
7440-33-7 Tungsten oxide (as W) 1
7439-98-7 Molybdenum oxide 10
10028-15-6 Ozone 0,12 (TGG 15 min.)
10102-44-0 Nitrogen dioxide 4

Personal protection
Breathing protection None (see item 16).
Ensure adequate ventilation. Possibly use
breathing masks see UVV (VGB 15) paragraph 27.
Protection of hands Use suitable hand protection.
Eye protection Use protective glasses.
Protection of skin and body Use well fitting working clothes and during welding a
welding helmet.
Safety data sheet
ISO 11014-1 / 91/155/EEC

Print: 07-02-05 Doc.No. sds-4431 rev.02
Page 3 of 4
Product name(s): LNS 304H LNS 316L LNS 4462
LNS 304L LNS 318 LNS 4500
LNS 307 LNS 347 LNS CrMn 18/7
LNS 309L LNS 4455 LNS Zeron 100X



8. EXPLOSION PREVENTION/PERSONEL PROTECTION

Hygiene regulations In case of dust or smoke: keep foodstuffs sealed.
Avoid direct skin contact.
Store and wash working clothes separately.
Clean face and hands thoroughly before
eating/drinking.


9. PHYSICAL AND CHEMICAL PROPERTIES

Further information
Physical state
Form Wire.
Colour
Odour None.

Other information
pH value Not applicable.
Melting point 1000 - 1500掳C.
Ignition point Not applicable.
Explosion limits Non-explosive.
Density -
Solubility in water Insoluble.


10. STABILITY AND REACTIVITY

Avoid contact with Strong acid and base solutions.
Dangerous residual products Not known for unused product; see also item 8.

11. DATA REGARDING TOXICITY


Acute Component Method Value
- - - -

Sensitisation Not known.
Chronical Not known.

See also item 3.


12. ECOLOGICAL DATA

No harmful effects of this product on the environment are known.
Safety data sheet
ISO 11014-1 / 91/155/EEC

Print: 07-02-05 Doc.No. sds-4431 rev.02
Page 4 of 4
Product name(s): LNS 304H LNS 316L LNS 4462
LNS 304L LNS 318 LNS 4500
LNS 307 LNS 347 LNS CrMn 18/7
LNS 309L LNS 4455 LNS Zeron 100X


13. DISPOSAL DATA

Product Contact government for regulations.

Packaging Contact government for regulations.

14. TRANSPORT INFORMATION

ADR/RID No dangerous substance.
ADN/ADNR No dangerous substance.
IMDG No dangerous product.
ICAO/IATA-DGR No dangerous substance.

15. REGULATIONS

Protect yourself and others. Take precautions when welding. Follow your employers鈥? safety practice, which
should be based on manufacturers hazard data available to your employer. Fumes and gases can be
dangerous to your health. Arc rays can injure eyes and burn skin. Electric shock can kill. Read and
understand the manufacturers instructions and your employer's safety practices. Keep your head out of the
fumes. Use enough ventilation, exhaust at the arc, or both, to keep fumes and gases from your breathing
zone, and the general area. Wear correct eye, ear and body protection. Do not touch live electrical parts.
U.K.: see WMA No.236 and 237 and HSE Guidance Note EH 40. U.S.A.: See American Standard Z 49.1
"Safety in Welding and Cutting", published by the American Welding Society, 550 Le Jeune Rd, Miami,
Florida 33126-5699; OSHA Safety and Health Standards, 29 CFR 1910, available from U.S. Government
printing office, Washington D.C. 20402-0001.

16. OTHER INFORMATION

All national/local prescriptions remain applicable. The data given in this sheet relate to the unused product,
unless specified otherwise. During usage dangerous products can be formed (welding fume, radiation,
etc.).
Above-mentioned values are no guarantee for product properties. They are based on current knowledge.


Change(s) in respect to the previous revision are indicated in r e d .


T h i s S a f e t y D a t a S h e e t i s p r e p a r e d f o r d a t a b a s e p u r p o s e s and is valid without signature.

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