**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 100-97-0 |Methenamine | 100.0 | 202-905-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN F
Risk Phrases: 11 42/43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. May cause sensitization by inhalation and skin
contact.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye irritation. Causes redness and pain.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Causes redness and pain.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation. May cause respiratory
sensitization.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Containers
may explode in the heat of a fire. Dust can be an explosion hazard
when exposed to heat or flame. Flammable solid. May re-ignite after
fire is extinguished. May be ignited by friction, heat, sparks, or
flame.
Extinguishing Media:
Use water fog, dry chemical, carbon dioxide, or regular foam. Cool
containers with flooding quantities of water until well after fire is
out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Remove all sources of
ignition. Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Avoid contact with eyes, skin, and clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep container tightly closed. Avoid ingestion and
inhalation. Use with adequate ventilation. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Store in a cool, dry place.
Keep container closed when not in use. Keep away from strong acids.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 100-97-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: colorless
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 200 deg C
Autoignition Temperature: Not applicable.
Flash Point: 482 deg F ( 250.00 deg C)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 270 deg C
Solubility in water: Very soluable
Specific Gravity/Density: 1.33 (water=1)
Molecular Formula: C6H12N4
Molecular Weight: 140.1108
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Hygroscopic: absorbs
moisture or water from the air.
Conditions to Avoid:
Incompatible materials, dust generation, exposure to moist air or
water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, sodium peroxide.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, formaldehyde.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 100-97-0: MN4725000
LD50/LC50:
CAS# 100-97-0: Oral, mouse: LD50 = 569 mg/kg.
Carcinogenicity:
Methenamine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish toxicity: LC50 (96 hr) Pimephales promelas = 49800 mg/l
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: HEXAMETHYLENETETRAMINE
Hazard Class: 4.1
UN Number: 1328
Packing Group: III
IMO
Shipping Name: HEXAMETHYLENETETRAMINE
Hazard Class: 4.1
UN Number: 1328
Packing Group: III
RID/ADR
Shipping Name: HEXAMETHYLENETETRAMINE
Hazard Class: 4.1
UN Number: 1328
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 11 Highly flammable.
R 42/43 May cause sensitization by inhalation and
skin contact.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 22 Do not breathe dust.
S 24 Avoid contact with skin.
S 37 Wear suitable gloves.
WGK (Water Danger/Protection)
CAS# 100-97-0: 1
Canada
CAS# 100-97-0 is listed on Canada's DSL List.
CAS# 100-97-0 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 100-97-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/29/1999 Revision #3 Date: 5/01/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,4,5-Trichlorophenyl Disulfide, 98%
| 3808-87-5 |
|
6-Bromo-1-hexanol, 95% (gc)
| 4286-55-9 |
|
Benzyl Benzoate, 99+%
| 120-51-4 |
|
3-Methylcyclohexanol, 99% Mixture of Cis and Trans Isomers
| 591-23-1 |
|
Hexamethylenediamine
| 124-09-4 |
|
syn-2-Methoxy-imino-2-(2-furyl)-acetic acid, sodium salt 99+%
| 65866-86-6 |
|
6,7-Dinitroquinoxaline, 99%
| 68836-13-5 |
|
Hexamethylenetetramine
| 100-97-0 |
|
(s)-(+)-2-Amino-3-methyl-1-butanol, 96%
| 2026-48-4 |
|
Hexanes
| 96-37-7 |
|
Hexane
| 0-01-1 |
|
Triethyl borate, 97%
| 150-46-9 |
|
5-Butylhydantoic acid, 98% (titr.)
| 63059-33-6 |
|
2-Methyl-1,3-dioxolane, 99+% (gc)
| 497-26-7 |
|
1,2-Propyleneglycol diacetate, 98%
| 623-84-7 |
|
Diethyl N-Butylmalonate, 99%
| 133-08-4 |
|
Ethyl Isonipecotate, 97%
| 1126-09-6 |
|
3-Chloro-2-nitrobenzoic acid, 98%
| 4771-47-5 |
|
Acetone cyanohydrin
| 75-86-5 |
|
Hydrazine anhydrous
| 302-01-2 |
|
Hydrazine hydrate, 100% (Hydrazine, 64%)
| 302-01-2 |
|
Bathophenanthrolinedisulfonic acid, disodium salt hydrate, 98%
| 52746-49-3 |
|
Hydrazine dihydrochloride
| 5341-61-7 |
|
Glutaryl Dichloride, 97%
| 2873-74-7 |
|
4-Hydroxyquinoline, 98%
| 611-36-9 |
|
(Dimethylaminomethylene)Malononitrile
| 16849-88-0 |
|
Hydrazine Sulfate
| 10034-93-2 |
|
Copper (I) Cyanide, 99%
| 544-92-3 |
|
Azure ii
| 37247-10-2 |
|
3-Phenoxy-1-propanol, 97%
| 6180-61-6 |
|
1-Methyl-6,7-Dimethoxy-3,4-Dihydroisoquinoline, 99+%
| 4721-98-6 |
|
Hydriodic acid >47% (covers range of products)
| 7732-18-5 |
|
Dimethyl Trans-1,4-Cyclohexanedi-Carboxylate, 99+%
| 3399-22-2 |
|
Hydrobromic acid 44-50% in water
| 7732-18-5 |
|
Fluorosilicic Acid
| 7732-18-5 |
|
Ethyl stains-all
| 3028-94-2 |
|
Phenylethyl Isovalerate, 99%
| 140-26-1 |
|
4-Chloro-3-fluoroanisole, 97%
| 501-29-1 |
|
5-Methoxy-1-indanone , 98%
| 5111-70-6 |
|
1,3-Cyclohexanebis(methylamine), 99%
| 2579-20-6 |
|
4-Fluorobenzyl chloride, 98%
| 352-11-4 |
|
Hydrochloric acid 32-38% solution
| 7647-01-0 |
|
3-Chloro-2-chloromethyl-1-propene, 96%
| 1871-57-4 |
|
Hydrofluoric acid, 47-51%
| 7664-39-3 |
|
4-Amino-2,2,6,6-Tetramethylpiperidino-oxy, Free Radical, 97%
| 14691-88-4 |
|
Iodic Acid
| 7782-68-5 |
|
Hydrogen Peroxide 20-40%
| 7722-84-1 |
|
n-Acetyl-l-glutamic acid, 99%
| 1188-37-0 |
|
Sym-Dimethylhydrazine Dihydrochloride, 99+%
| 306-37-6 |
|
Cyanamide, 99+%, contains stabilizer and a trace of moisture
| 420-04-2 |
|
|