**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 74-76% | 231-791-2 |
|----------------|--------------------------------------|----------|-----------|
| 16961-83-4 |FLUOROSILICIC ACID | 24-35% | 241-034-8 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. The toxicological properties of this substance have not been
fully investigated. Ingestion of large amounts of fluoride may cause
salivation, nausea, vomiting, abdominal pain, fever, labored
breathing. Inorganic fluorides can be harmful. Acute exposure to
fluorine compounds can lead to digestive tract burns, and abdominal
pain. Exposure to fluoride compounds can result in systemic toxic
effects on the heart, liver, and kidneys. It may also deplete
calcium levels in the body leading to hypocalcemia and death.
Contains fluoride. Fluoride can reduce calcium levels leading to
fatal hypocalcemia. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. The toxicological
properties of this substance have not been fully investigated.
Aspiration may lead to pulmonary edema. May cause systemic effects.
Chronic:
Chronic inhalation and ingestion may cause chronic fluoride
poisoning (fluorosis) characterized by weight loss, weakness,
anemia, brittle bones, and stiff joints. Effects may be delayed.
Chronic exposure to fluoride compounds may cause systemic toxicity.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Containers can build up pressure if exposed to heat and/or fire. As
in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases may
be generated by thermal decomposition or combustion. Use water spray
to keep fire-exposed containers cool. Use extinguishing media
appropriate to the surrounding fire. Substance is noncombustible.
Vapors may be heavier than air. They can spread along the ground
and collect in low or confined areas.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Do not get on skin or in eyes. Avoid ingestion and inhalation. Do not
ingest or inhale. Use with adequate ventilation. Discard contaminated
shoes.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area. Avoid storage in glass containers.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7732-18-5:
CAS# 16961-83-4:
United Kingdom, WEL - TWA: (listed as silica, amorphous): 6 mg/m3
(inhalable dust); 2.4 mg/m3 TWA (respirable dust)
United Kingdom, WEL - STEL: (listed as silica, amorphous): 18 mg/
STEL (inhalable dust); 7.2 mg/m3 STEL (respirable dust)
Russia: (listed as silica, amorphous): 1 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: acrid odor - pungent odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.2740g/cm3
Molecular Formula: H2F6Si
Molecular Weight: 144.09
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, glass.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, hydrogen fluoride gas, silicon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7732-18-5: ZC0110000
CAS# 16961-83-4: VV8225000
LD50/LC50:
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 16961-83-4: Oral, rat: LD50 = 430 mg/kg.
Carcinogenicity:
Water -
Not listed by ACGIH, IARC, or NTP.
FLUOROSILICIC ACID -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLUOROSILICIC ACID
Hazard Class: 8
UN Number: 1778
Packing Group: II
IMO
Shipping Name: FLUOROSILICIC ACID
Hazard Class: 8
UN Number: 1778
Packing Group: II
RID/ADR
Shipping Name: FLUOROSILICIC ACID
Hazard Class: 8
UN Number: 1778
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 27 Take off immediately all contaminated clothing.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7732-18-5: No information available.
CAS# 16961-83-4: 2
Canada
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 16961-83-4 is listed on Canada's DSL List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 16961-83-4 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 16961-83-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 12/12/1997 Revision #4 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,4,5-Trichlorophenyl Disulfide, 98%
| 3808-87-5 |
|
6-Bromo-1-hexanol, 95% (gc)
| 4286-55-9 |
|
Benzyl Benzoate, 99+%
| 120-51-4 |
|
3-Methylcyclohexanol, 99% Mixture of Cis and Trans Isomers
| 591-23-1 |
|
Hexamethylenediamine
| 124-09-4 |
|
syn-2-Methoxy-imino-2-(2-furyl)-acetic acid, sodium salt 99+%
| 65866-86-6 |
|
6,7-Dinitroquinoxaline, 99%
| 68836-13-5 |
|
Hexamethylenetetramine
| 100-97-0 |
|
(s)-(+)-2-Amino-3-methyl-1-butanol, 96%
| 2026-48-4 |
|
Hexanes
| 96-37-7 |
|
Hexane
| 0-01-1 |
|
Triethyl borate, 97%
| 150-46-9 |
|
5-Butylhydantoic acid, 98% (titr.)
| 63059-33-6 |
|
2-Methyl-1,3-dioxolane, 99+% (gc)
| 497-26-7 |
|
1,2-Propyleneglycol diacetate, 98%
| 623-84-7 |
|
Diethyl N-Butylmalonate, 99%
| 133-08-4 |
|
Ethyl Isonipecotate, 97%
| 1126-09-6 |
|
3-Chloro-2-nitrobenzoic acid, 98%
| 4771-47-5 |
|
Acetone cyanohydrin
| 75-86-5 |
|
Hydrazine anhydrous
| 302-01-2 |
|
Hydrazine hydrate, 100% (Hydrazine, 64%)
| 302-01-2 |
|
Bathophenanthrolinedisulfonic acid, disodium salt hydrate, 98%
| 52746-49-3 |
|
Hydrazine dihydrochloride
| 5341-61-7 |
|
Glutaryl Dichloride, 97%
| 2873-74-7 |
|
4-Hydroxyquinoline, 98%
| 611-36-9 |
|
(Dimethylaminomethylene)Malononitrile
| 16849-88-0 |
|
Hydrazine Sulfate
| 10034-93-2 |
|
Copper (I) Cyanide, 99%
| 544-92-3 |
|
Azure ii
| 37247-10-2 |
|
3-Phenoxy-1-propanol, 97%
| 6180-61-6 |
|
1-Methyl-6,7-Dimethoxy-3,4-Dihydroisoquinoline, 99+%
| 4721-98-6 |
|
Hydriodic acid >47% (covers range of products)
| 7732-18-5 |
|
Dimethyl Trans-1,4-Cyclohexanedi-Carboxylate, 99+%
| 3399-22-2 |
|
Hydrobromic acid 44-50% in water
| 7732-18-5 |
|
Fluorosilicic Acid
| 7732-18-5 |
|
Ethyl stains-all
| 3028-94-2 |
|
Phenylethyl Isovalerate, 99%
| 140-26-1 |
|
4-Chloro-3-fluoroanisole, 97%
| 501-29-1 |
|
5-Methoxy-1-indanone , 98%
| 5111-70-6 |
|
1,3-Cyclohexanebis(methylamine), 99%
| 2579-20-6 |
|
4-Fluorobenzyl chloride, 98%
| 352-11-4 |
|
Hydrochloric acid 32-38% solution
| 7647-01-0 |
|
3-Chloro-2-chloromethyl-1-propene, 96%
| 1871-57-4 |
|
Hydrofluoric acid, 47-51%
| 7664-39-3 |
|
4-Amino-2,2,6,6-Tetramethylpiperidino-oxy, Free Radical, 97%
| 14691-88-4 |
|
Iodic Acid
| 7782-68-5 |
|
Hydrogen Peroxide 20-40%
| 7722-84-1 |
|
n-Acetyl-l-glutamic acid, 99%
| 1188-37-0 |
|
Sym-Dimethylhydrazine Dihydrochloride, 99+%
| 306-37-6 |
|
Cyanamide, 99+%, contains stabilizer and a trace of moisture
| 420-04-2 |
|
|