**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 420-04-2 |Cyanamide | 99+ | 206-992-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 21 25 36/38 43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful in contact with skin. Toxic if swallowed. Irritating to eyes
and skin. May cause sensitization by skin contact.Hygroscopic
(absorbs moisture from the air).Heat sensitive.
Potential Health Effects
Eye:
Dust may cause mechanical irritation. Causes severe eye
irritation.
Skin:
Causes severe skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. Causes digestive tract irritation.
Inhalation:
Dust is irritating to the respiratory tract.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Combustible
solid. May be ignited by heat, sparks, and flame.
Extinguishing Media:
Do NOT get water inside containers. Use dry chemical, dry sand, or
carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Keep refrigerated. (Store below 4C/39F.) Keep
containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 420-04-2:
United Kingdom, WEL - TWA: 2 mg/m3 TWA
United Kingdom, WEL - STEL: 6 mg/m3 STEL
Belgium - TWA: 2 mg/m3 VLE
France - VME: 2 mg/m3 VME
Germany: 0.58 ppm TWA (inhalable fraction); 1 mg/m3 TWA (inhalabl
fraction)
Germany: Skin absorber
Malaysia: 2 mg/m3 TWA
Netherlands: 2 mg/m3 MAC
Russia: 0.5 mg/m3 TWA
Spain: 2 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: colorless
Odor: none reported
pH: Not available.
Vapor Pressure: 3.75103 mm Hg @ 20 C
Viscosity: Not available.
Boiling Point: 83 deg C
Freezing/Melting Point: 45 - 46 deg C
Autoignition Temperature: Not available.
Flash Point: 142 deg C ( 287.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 1.0700g/cm3
Molecular Formula: CH2N2
Molecular Weight: 42.04
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Thermally unstable.
Conditions to Avoid:
Excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents - strong reducing agents - acids - bases.
Hazardous Decomposition Products:
Hydrogen cyanide, nitrogen oxides, carbon monoxide, carbon dioxide,
nitrogen.
Hazardous Polymerization: May occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 420-04-2: GS5950000
LD50/LC50:
CAS# 420-04-2: Oral, mouse: LD50 = 388 mg/kg; Oral, rabbit: LD50 =
150 mg/kg; Oral, rat: LD50 = 125 mg/kg; Skin, rabbit: LD50 = 590
mg/kg; Skin, rat: LD50 = 84 mg/kg.
Carcinogenicity:
Cyanamide -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Bioconcentration in acquatic organisms is expected to be low.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 21 Harmful in contact with skin.
R 25 Toxic if swallowed.
R 36/38 Irritating to eyes and skin.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 3 Keep in a cool place.
S 22 Do not breathe dust.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 420-04-2: 2
Canada
CAS# 420-04-2 is listed on Canada's DSL List.
CAS# 420-04-2 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 420-04-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/05/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,4,5-Trichlorophenyl Disulfide, 98%
| 3808-87-5 |
|
6-Bromo-1-hexanol, 95% (gc)
| 4286-55-9 |
|
Benzyl Benzoate, 99+%
| 120-51-4 |
|
3-Methylcyclohexanol, 99% Mixture of Cis and Trans Isomers
| 591-23-1 |
|
Hexamethylenediamine
| 124-09-4 |
|
syn-2-Methoxy-imino-2-(2-furyl)-acetic acid, sodium salt 99+%
| 65866-86-6 |
|
6,7-Dinitroquinoxaline, 99%
| 68836-13-5 |
|
Hexamethylenetetramine
| 100-97-0 |
|
(s)-(+)-2-Amino-3-methyl-1-butanol, 96%
| 2026-48-4 |
|
Hexanes
| 96-37-7 |
|
Hexane
| 0-01-1 |
|
Triethyl borate, 97%
| 150-46-9 |
|
5-Butylhydantoic acid, 98% (titr.)
| 63059-33-6 |
|
2-Methyl-1,3-dioxolane, 99+% (gc)
| 497-26-7 |
|
1,2-Propyleneglycol diacetate, 98%
| 623-84-7 |
|
Diethyl N-Butylmalonate, 99%
| 133-08-4 |
|
Ethyl Isonipecotate, 97%
| 1126-09-6 |
|
3-Chloro-2-nitrobenzoic acid, 98%
| 4771-47-5 |
|
Acetone cyanohydrin
| 75-86-5 |
|
Hydrazine anhydrous
| 302-01-2 |
|
Hydrazine hydrate, 100% (Hydrazine, 64%)
| 302-01-2 |
|
Bathophenanthrolinedisulfonic acid, disodium salt hydrate, 98%
| 52746-49-3 |
|
Hydrazine dihydrochloride
| 5341-61-7 |
|
Glutaryl Dichloride, 97%
| 2873-74-7 |
|
4-Hydroxyquinoline, 98%
| 611-36-9 |
|
(Dimethylaminomethylene)Malononitrile
| 16849-88-0 |
|
Hydrazine Sulfate
| 10034-93-2 |
|
Copper (I) Cyanide, 99%
| 544-92-3 |
|
Azure ii
| 37247-10-2 |
|
3-Phenoxy-1-propanol, 97%
| 6180-61-6 |
|
1-Methyl-6,7-Dimethoxy-3,4-Dihydroisoquinoline, 99+%
| 4721-98-6 |
|
Hydriodic acid >47% (covers range of products)
| 7732-18-5 |
|
Dimethyl Trans-1,4-Cyclohexanedi-Carboxylate, 99+%
| 3399-22-2 |
|
Hydrobromic acid 44-50% in water
| 7732-18-5 |
|
Fluorosilicic Acid
| 7732-18-5 |
|
Ethyl stains-all
| 3028-94-2 |
|
Phenylethyl Isovalerate, 99%
| 140-26-1 |
|
4-Chloro-3-fluoroanisole, 97%
| 501-29-1 |
|
5-Methoxy-1-indanone , 98%
| 5111-70-6 |
|
1,3-Cyclohexanebis(methylamine), 99%
| 2579-20-6 |
|
4-Fluorobenzyl chloride, 98%
| 352-11-4 |
|
Hydrochloric acid 32-38% solution
| 7647-01-0 |
|
3-Chloro-2-chloromethyl-1-propene, 96%
| 1871-57-4 |
|
Hydrofluoric acid, 47-51%
| 7664-39-3 |
|
4-Amino-2,2,6,6-Tetramethylpiperidino-oxy, Free Radical, 97%
| 14691-88-4 |
|
Iodic Acid
| 7782-68-5 |
|
Hydrogen Peroxide 20-40%
| 7722-84-1 |
|
n-Acetyl-l-glutamic acid, 99%
| 1188-37-0 |
|
Sym-Dimethylhydrazine Dihydrochloride, 99+%
| 306-37-6 |
|
Cyanamide, 99+%, contains stabilizer and a trace of moisture
| 420-04-2 |
|
|