**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 10034-93-2 |HYDRAZINE SULFATE | >99 | 233-110-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T N
Risk Phrases: 23/24/25 43 45 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed. May
cause sensitization by skin contact. May cause cancer. Very toxic to
aquatic organisms, may cause long-term adverse effects in the aquatic
environment.Corrosive.Carcinogen.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns. May cause eye injury.
Skin:
May cause skin sensitization, an allergic reaction, which becomes
evident upon re-exposure to this material. May cause severe skin
irritation with possible burns, especially if skin is wet or moist.
Ingestion:
May cause liver and kidney damage. May cause severe digestive tract
irritation with abdominal pain, nausea, vomiting and diarrhea. May
cause corrosion and permanent tissue destruction of the esophagus and
digestive tract. Exposure may cause anemia and other blood
abnormalities. May be harmful if swallowed.
Inhalation:
Irritation may lead to chemical pneumonitis and pulmonary edema. May
cause liver and kidney damage. May cause severe irritation of the
upper respiratory tract with pain, burns, and inflammation. May cause
effects similar to those described for ingestion.
Chronic:
Prolonged or repeated skin contact may cause sensitization
dermatitis and possible destruction and/or ulceration. May cause
liver and kidney damage. May cause cancer according to animal
studies. May cause digestive tract disturbances.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air. Combustion generates toxic fumes.
Extinguishing Media:
For small fires, use water spray, dry chemical, carbon dioxide or
chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Do not get on skin and clothing. Do not
ingest or inhale.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use process enclosure,
local exhaust ventilation, or other engineering controls to control
airborne levels.
Exposure Limits
CAS# 10034-93-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white
Odor: none reported
pH: 1.3 (0.2M solution)
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 489 deg F
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 254 deg C
Solubility in water: Soluble in water.
Specific Gravity/Density: 1.4 (water=1)
Molecular Formula: H4N2.H2SO4
Molecular Weight: 130.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Oxidizing agents, combustible materials, sodium amide.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 10034-93-2: MV9625000
LD50/LC50:
CAS# 10034-93-2: Draize test, rabbit, eye: 20 mg/24H Moderate; Oral,
mouse: LD50 = 434 mg/kg; Oral, rat: LD50 = 601 mg/kg.
Carcinogenicity:
HYDRAZINE SULFATE -
California: carcinogen, initial date 1/1/88
NTP: Suspect carcinogen
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, INORGANIC, NOS(Hydrazinium sulfate)
Hazard Class: 6.1
UN Number: 3288
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, INORGANIC, NOS(Hydrazinium sulfate)
Hazard Class: 6.1
UN Number: 3288
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, INORGANIC, NOS(Hydrazinium sulfate)
Hazard Class: 6.1
UN Number: 3288
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 45 May cause cancer.
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 43 May cause sensitization by skin contact.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 10034-93-2: No information available.
Canada
CAS# 10034-93-2 is listed on Canada's DSL List.
CAS# 10034-93-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10034-93-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/12/1997 Revision #6 Date: 5/05/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,4,5-Trichlorophenyl Disulfide, 98%
| 3808-87-5 |
|
6-Bromo-1-hexanol, 95% (gc)
| 4286-55-9 |
|
Benzyl Benzoate, 99+%
| 120-51-4 |
|
3-Methylcyclohexanol, 99% Mixture of Cis and Trans Isomers
| 591-23-1 |
|
Hexamethylenediamine
| 124-09-4 |
|
syn-2-Methoxy-imino-2-(2-furyl)-acetic acid, sodium salt 99+%
| 65866-86-6 |
|
6,7-Dinitroquinoxaline, 99%
| 68836-13-5 |
|
Hexamethylenetetramine
| 100-97-0 |
|
(s)-(+)-2-Amino-3-methyl-1-butanol, 96%
| 2026-48-4 |
|
Hexanes
| 96-37-7 |
|
Hexane
| 0-01-1 |
|
Triethyl borate, 97%
| 150-46-9 |
|
5-Butylhydantoic acid, 98% (titr.)
| 63059-33-6 |
|
2-Methyl-1,3-dioxolane, 99+% (gc)
| 497-26-7 |
|
1,2-Propyleneglycol diacetate, 98%
| 623-84-7 |
|
Diethyl N-Butylmalonate, 99%
| 133-08-4 |
|
Ethyl Isonipecotate, 97%
| 1126-09-6 |
|
3-Chloro-2-nitrobenzoic acid, 98%
| 4771-47-5 |
|
Acetone cyanohydrin
| 75-86-5 |
|
Hydrazine anhydrous
| 302-01-2 |
|
Hydrazine hydrate, 100% (Hydrazine, 64%)
| 302-01-2 |
|
Bathophenanthrolinedisulfonic acid, disodium salt hydrate, 98%
| 52746-49-3 |
|
Hydrazine dihydrochloride
| 5341-61-7 |
|
Glutaryl Dichloride, 97%
| 2873-74-7 |
|
4-Hydroxyquinoline, 98%
| 611-36-9 |
|
(Dimethylaminomethylene)Malononitrile
| 16849-88-0 |
|
Hydrazine Sulfate
| 10034-93-2 |
|
Copper (I) Cyanide, 99%
| 544-92-3 |
|
Azure ii
| 37247-10-2 |
|
3-Phenoxy-1-propanol, 97%
| 6180-61-6 |
|
1-Methyl-6,7-Dimethoxy-3,4-Dihydroisoquinoline, 99+%
| 4721-98-6 |
|
Hydriodic acid >47% (covers range of products)
| 7732-18-5 |
|
Dimethyl Trans-1,4-Cyclohexanedi-Carboxylate, 99+%
| 3399-22-2 |
|
Hydrobromic acid 44-50% in water
| 7732-18-5 |
|
Fluorosilicic Acid
| 7732-18-5 |
|
Ethyl stains-all
| 3028-94-2 |
|
Phenylethyl Isovalerate, 99%
| 140-26-1 |
|
4-Chloro-3-fluoroanisole, 97%
| 501-29-1 |
|
5-Methoxy-1-indanone , 98%
| 5111-70-6 |
|
1,3-Cyclohexanebis(methylamine), 99%
| 2579-20-6 |
|
4-Fluorobenzyl chloride, 98%
| 352-11-4 |
|
Hydrochloric acid 32-38% solution
| 7647-01-0 |
|
3-Chloro-2-chloromethyl-1-propene, 96%
| 1871-57-4 |
|
Hydrofluoric acid, 47-51%
| 7664-39-3 |
|
4-Amino-2,2,6,6-Tetramethylpiperidino-oxy, Free Radical, 97%
| 14691-88-4 |
|
Iodic Acid
| 7782-68-5 |
|
Hydrogen Peroxide 20-40%
| 7722-84-1 |
|
n-Acetyl-l-glutamic acid, 99%
| 1188-37-0 |
|
Sym-Dimethylhydrazine Dihydrochloride, 99+%
| 306-37-6 |
|
Cyanamide, 99+%, contains stabilizer and a trace of moisture
| 420-04-2 |
|
|