**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1003-09-4 |2-Bromothiophene | 98% | 213-699-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 10 22 23/24
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful if swallowed. Toxic by inhalation and in contact
with skin.The toxicological properties of this material have not
been fully investigated.Stench.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
The toxicological properties of this substance have not been fully
investigated. May cause headache. May cause nausea and vomiting.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Will burn
if involved in a fire. Combustible liquid.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Wash area with soap and water.
Remove all sources of ignition. Use a spark-proof tool. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use spark-proof tools and explosion
proof equipment. Avoid contact with eyes, skin, and clothing. Keep
away from heat, sparks and flame. Avoid ingestion and inhalation. Use
only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a dry area. Keep refrigerated. (Store below
4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use only under a
chemical fume hood.
Exposure Limits
CAS# 1003-09-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear slight brown
Odor: Stench.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 149 - 151 deg C @ 760.00mm Hg
Freezing/Melting Point: <-10 deg C
Autoignition Temperature: Not available.
Flash Point: 52 deg C ( 125.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: immiscible with water
Specific Gravity/Density: 1.6840g/cm3
Molecular Formula: C4H3BrS
Molecular Weight: 163.03
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Strong bases; strong oxidizing agents; strong reducing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen bromide,
hydrogen sulfide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1003-09-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-Bromothiophene -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Water Danger/Protection: WGK 2
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S.*
Hazard Class: 6.1 (3)
UN Number: 2929
Packing Group: II
IMO
Shipping Name: TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S.
Hazard Class: 6.1 (3)
UN Number: 2929
Packing Group: II
RID/ADR
Shipping Name: TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2929
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 10 Flammable.
R 22 Harmful if swallowed.
R 23/24 Toxic by inhalation and in contact with
skin.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 28 After contact with skin, wash immediately
with...
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1003-09-4: No information available.
Canada
CAS# 1003-09-4 is listed on Canada's DSL List.
CAS# 1003-09-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1003-09-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Choline (Pract) (45% in Methanol)
| 62-49-7 |
|
2-Phenylpyridine, 98%
| 1008-89-5 |
|
Potassium Thioacetate, 98+%
| 10387-40-3 |
|
??-Propiolactone, 98%
| 57-57-8 |
|
Ethyl 3-iodobenzoate, 98%
| 58313-23-8 |
|
(+)-2,2,2-Trifluoro-1-(9-Anthryl)Ethanol, 98+%
| 60646-30-2 |
|
o-Acetotoluidide
| 120-66-1 |
|
2-Methylcyclohexanone, 98%
| 583-60-8 |
|
2,3-Dichlorobenzaldehyde,99%
| 6334-18-5 |
|
Iron Phthalocyanine, 96% (uv-vis)
| 132-16-1 |
|
4-Nitrophthalic Anhydride, 98% (Titr.)
| 5466-84-2 |
|
(+)-1-(9-Fluorenyl)ethyl chloroformate, 0.5 w/v % solution in acetone
| 67-64-1 |
|
2-Methoxy-1-naphthaldehyde, 99%
| 5392-12-1 |
|
Methyl-1-methyl-2-pyrrole acetate, 96%
| 51856-79-2 |
|
1-Ethoxy-2-propanol,90-95%,remainder 2-eth oxy-1-propanol
| 1569-02-4 |
|
m-Methoxycinnamic acid, 97%, predominantly trans
| 6099-04-3 |
|
Carbamylcholine Chloride, 99.0-101.0% (on the Dried Substance)
| 51-83-2 |
|
2-methanesulphonyl-2-acetyl pyridine
| |
|
2,5-Dimethylbenzoic Acid, 98%
| 610-72-0 |
|
6,7-Dimethoxy-3,4-Dihydroisoquinoline Hydrochloride, 99+%
| 20232-39-7 |
|
Tetramethylammonium Acetate, 95% (Titr.)
| 10581-12-1 |
|
(Chloromethylene)dimethylammonium chloride 96% (1h-nmr)
| 3724-43-4 |
|
o-Anisaldehyde, 98%
| 135-02-4 |
|
2,3-Dihydroxybenzaldehyde, 97%
| 24677-78-9 |
|
(S)-2-Amino-3-(Dimethylamino)propanoic Acid, Dihydrochloride,
| 0-00-1 |
|
Dimethylamine, 40 Wt% Solution in Water
| 124-40-3 |
|
n-(4-Vinylphenyl)maleimide
| 19007-91-1 |
|
2-Chloro-6-Fluorobenzoic Acid, 98%
| 434-75-3 |
|
1,2-Dicarboxy-Cis-4,5-Dihydroxycyclohexa- 2,6-Diene, 95%
| 130073-64-2 |
|
3-Nitrobenzyl bromide, 99%
| 3958-57-4 |
|
Potassium diphosphate, C.P.
| 7320-34-5 |
|
2-Bromothiophene, 98%
| 1003-09-4 |
|
2-Nonanone, 99+%
| 821-55-6 |
|
4-Methylesculetin
| 529-84-0 |
|
p-Toluic acid, 98%
| 99-94-5 |
|
Dilauryl Phosphite, Tech.
| 21302-90-9 |
|
Amberlite ir-120 na ion-exchange resin
| 9002-23-7 |
|
DL-Alpha-Hydroxycaproic Acid, 95+%
| 6064-63-7 |
|
tert-Butylhydroquinone diacetate
| 7507-48-4 |
|
2,5-Dimercapto-1,3,4-Thiadiazole, 98% (Titr.)
| 1072-71-5 |
|
n-Butyl disulfide, 98%
| 629-45-8 |
|
(R)-(-)-5-oxo-2-Tetrahydrofurancarboxylic acid, 99% (99% e.e.)
| 53558-93-3 |
|
Deuterium Bromide, 47 wt% Solution in D2O, 99+ Atom % D
| 7732-18-5 |
|
L-(-)-Pipecolinic Acid, 99%
| 3105-95-1 |
|
(S)-(+)-2-Amino-1-propanol, 98%
| 2749-11-3 |
|
Sodium formaldehydesulfoxylate dihydrate, 98%
| 6035-47-8 |
|
1-Chlorononane, 99%
| 2473-01-0 |
|
Allylamine, 97%
| 107-11-9 |
|
Triethyloxonium tetrafluoroborate, 1M solution in methylene chloride
| 75-09-2 |
|
N,N'-Dimethylethylenediamine
| 110-70-3 |
|
|