**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 3958-57-4 |3-Nitrobenzyl bromide | 99 | 223-557-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Lachrymator
(substance which increases the flow of tears).
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears). May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation. May cause burning sensation,
coughing, wheezing, laryngitis, shortness of breath, headache,
nausea, and vomiting. Can produce delayed pulmonary edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid. Get medical aid immediately. Flush skin with plenty
of water for at least 15 minutes while removing contaminated clothing
and shoes. Immediately flush skin with plenty of water for at least
15 minutes while removing contaminated clothing and shoes. Wash
clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water runoff can cause environmental damage. Dike
and collect water used to fight fire. During a fire, irritating and
highly toxic gases may be generated by thermal decomposition or
combustion. Containers may explode when heated. Combustible material;
may burn but does not ignite readily. Water hydrolyzes material
liberating acidic gas which in contact with metal surfaces can
generate flammable and/or explosive hydrogen gas.
Extinguishing Media:
Do NOT use water directly on fire. Use foam, dry chemical, or carbon
dioxide. DO NOT USE WATER! In case of fire, use carbon dioxide, dry
chemical powder or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal. Provide
ventilation. Do not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Minimize dust generation and accumulation. Keep container tightly
closed. Do not get on skin or in eyes. Avoid ingestion and
inhalation. Do not ingest or inhale. Use with adequate ventilation.
Wash clothing before reuse. Discard contaminated shoes.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep away
from water. Keep containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low. Use
adequate general or local explosion-proof ventilation to keep
airborne levels to acceptable levels.
Exposure Limits
CAS# 3958-57-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: off-white to tan
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 58 - 59 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 125 deg C
Solubility in water: Insoluble.
Specific Gravity/Density: Not available.
Molecular Formula: C7H6BrNO2
Molecular Weight: 216.03
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable, however, may violently decompose at temperatures above
125C.
Conditions to Avoid:
Incompatible materials, moisture, excess heat, temperatures above
125C.
Incompatibilities with Other Materials:
Oxidizing agents, bases, alcohols, amines, steel, moisture.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide,
hydrogen bromide, nitrogen, chloride fumes.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 3958-57-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3-Nitrobenzyl bromide -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 27 Take off immediately all contaminated clothing.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 3958-57-4: No information available.
Canada
CAS# 3958-57-4 is listed on Canada's NDSL List.
CAS# 3958-57-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3958-57-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/15/1999 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Choline (Pract) (45% in Methanol)
| 62-49-7 |
|
2-Phenylpyridine, 98%
| 1008-89-5 |
|
Potassium Thioacetate, 98+%
| 10387-40-3 |
|
??-Propiolactone, 98%
| 57-57-8 |
|
Ethyl 3-iodobenzoate, 98%
| 58313-23-8 |
|
(+)-2,2,2-Trifluoro-1-(9-Anthryl)Ethanol, 98+%
| 60646-30-2 |
|
o-Acetotoluidide
| 120-66-1 |
|
2-Methylcyclohexanone, 98%
| 583-60-8 |
|
2,3-Dichlorobenzaldehyde,99%
| 6334-18-5 |
|
Iron Phthalocyanine, 96% (uv-vis)
| 132-16-1 |
|
4-Nitrophthalic Anhydride, 98% (Titr.)
| 5466-84-2 |
|
(+)-1-(9-Fluorenyl)ethyl chloroformate, 0.5 w/v % solution in acetone
| 67-64-1 |
|
2-Methoxy-1-naphthaldehyde, 99%
| 5392-12-1 |
|
Methyl-1-methyl-2-pyrrole acetate, 96%
| 51856-79-2 |
|
1-Ethoxy-2-propanol,90-95%,remainder 2-eth oxy-1-propanol
| 1569-02-4 |
|
m-Methoxycinnamic acid, 97%, predominantly trans
| 6099-04-3 |
|
Carbamylcholine Chloride, 99.0-101.0% (on the Dried Substance)
| 51-83-2 |
|
2-methanesulphonyl-2-acetyl pyridine
| |
|
2,5-Dimethylbenzoic Acid, 98%
| 610-72-0 |
|
6,7-Dimethoxy-3,4-Dihydroisoquinoline Hydrochloride, 99+%
| 20232-39-7 |
|
Tetramethylammonium Acetate, 95% (Titr.)
| 10581-12-1 |
|
(Chloromethylene)dimethylammonium chloride 96% (1h-nmr)
| 3724-43-4 |
|
o-Anisaldehyde, 98%
| 135-02-4 |
|
2,3-Dihydroxybenzaldehyde, 97%
| 24677-78-9 |
|
(S)-2-Amino-3-(Dimethylamino)propanoic Acid, Dihydrochloride,
| 0-00-1 |
|
Dimethylamine, 40 Wt% Solution in Water
| 124-40-3 |
|
n-(4-Vinylphenyl)maleimide
| 19007-91-1 |
|
2-Chloro-6-Fluorobenzoic Acid, 98%
| 434-75-3 |
|
1,2-Dicarboxy-Cis-4,5-Dihydroxycyclohexa- 2,6-Diene, 95%
| 130073-64-2 |
|
3-Nitrobenzyl bromide, 99%
| 3958-57-4 |
|
Potassium diphosphate, C.P.
| 7320-34-5 |
|
2-Bromothiophene, 98%
| 1003-09-4 |
|
2-Nonanone, 99+%
| 821-55-6 |
|
4-Methylesculetin
| 529-84-0 |
|
p-Toluic acid, 98%
| 99-94-5 |
|
Dilauryl Phosphite, Tech.
| 21302-90-9 |
|
Amberlite ir-120 na ion-exchange resin
| 9002-23-7 |
|
DL-Alpha-Hydroxycaproic Acid, 95+%
| 6064-63-7 |
|
tert-Butylhydroquinone diacetate
| 7507-48-4 |
|
2,5-Dimercapto-1,3,4-Thiadiazole, 98% (Titr.)
| 1072-71-5 |
|
n-Butyl disulfide, 98%
| 629-45-8 |
|
(R)-(-)-5-oxo-2-Tetrahydrofurancarboxylic acid, 99% (99% e.e.)
| 53558-93-3 |
|
Deuterium Bromide, 47 wt% Solution in D2O, 99+ Atom % D
| 7732-18-5 |
|
L-(-)-Pipecolinic Acid, 99%
| 3105-95-1 |
|
(S)-(+)-2-Amino-1-propanol, 98%
| 2749-11-3 |
|
Sodium formaldehydesulfoxylate dihydrate, 98%
| 6035-47-8 |
|
1-Chlorononane, 99%
| 2473-01-0 |
|
Allylamine, 97%
| 107-11-9 |
|
Triethyloxonium tetrafluoroborate, 1M solution in methylene chloride
| 75-09-2 |
|
N,N'-Dimethylethylenediamine
| 110-70-3 |
|
|