**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | Balance | 231-791-2 |
|----------------|--------------------------------------|----------|-----------|
| 13536-59-9 |Deuterium Bromide | 47 | 236-894-6 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: C
Risk Phrases: 34 37
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns. Irritating to respiratory system.Corrosive.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns. May cause chemical conjunctivitis and corneal damage.
Skin:
May cause severe irritation and possible burns. May cause skin rash
(in milder cases), and cold and clammy skin with cyanosis or pale
color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. The toxicological properties of this substance have not been
fully investigated. May cause systemic effects.
Inhalation:
May cause respiratory tract irritation. May cause severe irritation
of the respiratory tract with sore throat, coughing, shortness of
breath and delayed lung edema. Causes chemical burns to the
respiratory tract. The toxicological properties of this substance
have not been fully investigated. Aspiration may lead to pulmonary
edema. May cause systemic effects.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid. Do NOT allow victim to rub eyes or keep eyes
closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Vapors may be heavier
than air. They can spread along the ground and collect in low or
confined areas. Containers may explode when heated.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Cool containers with
flooding quantities of water until well after fire is out. Use water
spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Absorb spill using an absorbent, non-combustible
material such as earth, sand, or vermiculite. Do not use combustible
materials such as sawdust. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Do
not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin,
or on clothing. Keep container tightly closed. Do not ingest or
inhale. Discard contaminated shoes.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep
refrigerated. (Store below 4C/39F.) Storage under a nitrogen
blanket has been recommended.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7732-18-5:
CAS# 13536-59-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear slightly yellow
Odor: bromine-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 126 deg C @ 760.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: BrD
Molecular Weight: 81.93
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, bromine.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7732-18-5: ZC0110000
CAS# 13536-59-9 unlisted.
LD50/LC50:
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 13536-59-9.
Carcinogenicity:
Water -
Not listed by ACGIH, IARC, or NTP.
Deuterium Bromide -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: HYDROBROMIC ACID
Hazard Class: 8
UN Number: 1788
Packing Group: II
IMO
Shipping Name: HYDROBROMIC ACID
Hazard Class: 8
UN Number: 1788
Packing Group: II
RID/ADR
Shipping Name: BROMIC ACID
Hazard Class: 8
UN Number: 1788
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
R 37 Irritating to respiratory system.
Safety Phrases:
S 7/9 Keep container tightly closed and in a
well-ventilated place.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7732-18-5: No information available.
CAS# 13536-59-9: No information available.
Canada
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 13536-59-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 13536-59-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Choline (Pract) (45% in Methanol)
| 62-49-7 |
|
2-Phenylpyridine, 98%
| 1008-89-5 |
|
Potassium Thioacetate, 98+%
| 10387-40-3 |
|
??-Propiolactone, 98%
| 57-57-8 |
|
Ethyl 3-iodobenzoate, 98%
| 58313-23-8 |
|
(+)-2,2,2-Trifluoro-1-(9-Anthryl)Ethanol, 98+%
| 60646-30-2 |
|
o-Acetotoluidide
| 120-66-1 |
|
2-Methylcyclohexanone, 98%
| 583-60-8 |
|
2,3-Dichlorobenzaldehyde,99%
| 6334-18-5 |
|
Iron Phthalocyanine, 96% (uv-vis)
| 132-16-1 |
|
4-Nitrophthalic Anhydride, 98% (Titr.)
| 5466-84-2 |
|
(+)-1-(9-Fluorenyl)ethyl chloroformate, 0.5 w/v % solution in acetone
| 67-64-1 |
|
2-Methoxy-1-naphthaldehyde, 99%
| 5392-12-1 |
|
Methyl-1-methyl-2-pyrrole acetate, 96%
| 51856-79-2 |
|
1-Ethoxy-2-propanol,90-95%,remainder 2-eth oxy-1-propanol
| 1569-02-4 |
|
m-Methoxycinnamic acid, 97%, predominantly trans
| 6099-04-3 |
|
Carbamylcholine Chloride, 99.0-101.0% (on the Dried Substance)
| 51-83-2 |
|
2-methanesulphonyl-2-acetyl pyridine
| |
|
2,5-Dimethylbenzoic Acid, 98%
| 610-72-0 |
|
6,7-Dimethoxy-3,4-Dihydroisoquinoline Hydrochloride, 99+%
| 20232-39-7 |
|
Tetramethylammonium Acetate, 95% (Titr.)
| 10581-12-1 |
|
(Chloromethylene)dimethylammonium chloride 96% (1h-nmr)
| 3724-43-4 |
|
o-Anisaldehyde, 98%
| 135-02-4 |
|
2,3-Dihydroxybenzaldehyde, 97%
| 24677-78-9 |
|
(S)-2-Amino-3-(Dimethylamino)propanoic Acid, Dihydrochloride,
| 0-00-1 |
|
Dimethylamine, 40 Wt% Solution in Water
| 124-40-3 |
|
n-(4-Vinylphenyl)maleimide
| 19007-91-1 |
|
2-Chloro-6-Fluorobenzoic Acid, 98%
| 434-75-3 |
|
1,2-Dicarboxy-Cis-4,5-Dihydroxycyclohexa- 2,6-Diene, 95%
| 130073-64-2 |
|
3-Nitrobenzyl bromide, 99%
| 3958-57-4 |
|
Potassium diphosphate, C.P.
| 7320-34-5 |
|
2-Bromothiophene, 98%
| 1003-09-4 |
|
2-Nonanone, 99+%
| 821-55-6 |
|
4-Methylesculetin
| 529-84-0 |
|
p-Toluic acid, 98%
| 99-94-5 |
|
Dilauryl Phosphite, Tech.
| 21302-90-9 |
|
Amberlite ir-120 na ion-exchange resin
| 9002-23-7 |
|
DL-Alpha-Hydroxycaproic Acid, 95+%
| 6064-63-7 |
|
tert-Butylhydroquinone diacetate
| 7507-48-4 |
|
2,5-Dimercapto-1,3,4-Thiadiazole, 98% (Titr.)
| 1072-71-5 |
|
n-Butyl disulfide, 98%
| 629-45-8 |
|
(R)-(-)-5-oxo-2-Tetrahydrofurancarboxylic acid, 99% (99% e.e.)
| 53558-93-3 |
|
Deuterium Bromide, 47 wt% Solution in D2O, 99+ Atom % D
| 7732-18-5 |
|
L-(-)-Pipecolinic Acid, 99%
| 3105-95-1 |
|
(S)-(+)-2-Amino-1-propanol, 98%
| 2749-11-3 |
|
Sodium formaldehydesulfoxylate dihydrate, 98%
| 6035-47-8 |
|
1-Chlorononane, 99%
| 2473-01-0 |
|
Allylamine, 97%
| 107-11-9 |
|
Triethyloxonium tetrafluoroborate, 1M solution in methylene chloride
| 75-09-2 |
|
N,N'-Dimethylethylenediamine
| 110-70-3 |
|
|