**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 107-11-9 |Allylamine | 97.0 | 203-463-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T F
Risk Phrases: 11 23/24/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Toxic by inhalation, in contact with skin and if
swallowed.Corrosive.
Potential Health Effects
Eye:
Causes severe eye burns. Vapor or mist may cause irritation and
severe burns. May cause conjunctivitis. Lachrymator (substance
which increases the flow of tears).
Skin:
May be fatal if absorbed through the skin. Causes severe burns.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
May be fatal if inhaled. Exposure to high concentrations may produce
narcosis, nausea and loss of consciousness. Causes respiratory tract
irritation with possible burns. May cause severe tearing,
conjunctivitis, corneal edema, coughing, nausea, and pulmonary
edema.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Remove contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Combustion
generates toxic fumes. Use water spray to keep fire-exposed
containers cool. Extremely flammable liquid and vapor. Vapors may be
heavier than air. They can spread along the ground and collect in
low or confined areas. Will be easily ignited by heat, sparks or
flame. Containers may explode when heated.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. For large fires, use water
spray, fog or alcohol-resistant foam. Do NOT use straight streams of
water. Cool containers with flooding quantities of water until well
after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition. A
vapor suppressing foam may be used to reduce vapors. Water spray may
reduce vapor but may not prevent ignition in closed spaces.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Ground and bond containers when transferring
material. Do not get in eyes, on skin, or on clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep container tightly closed. Keep away from heat, sparks
and flame. Do not ingest or inhale. Use only in a chemical fume hood.
Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Keep from contact
with oxidizing materials. Store in a cool, dry, well-ventilated area
away from incompatible substances. Keep away from acids.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use only under a chemical fume hood.
Exposure Limits
CAS# 107-11-9:
Germany: 5 mg/m3 TWA
Germany: Skin absorber
Russia: 0.5 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear light yellow
Odor: Strong ammoniacal odor
pH: Not available.
Vapor Pressure: 242 mm Hg @25C
Viscosity: 0.44 cP 25 deg C
Boiling Point: 55-58C
Freezing/Melting Point: -123 deg C
Autoignition Temperature: 705 deg F ( 373.89 deg C)
Flash Point: -20 deg C ( -4.00 deg F)
Explosion Limits, lower: 2.0 vol %
Explosion Limits, upper: 22.00 vol %
Decomposition Temperature:
Solubility in water: soluble
Specific Gravity/Density: .7610g/cm3
Molecular Formula: C3H7N
Molecular Weight: 57.09
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Metals, oxidizing agents, acids, amines, halogenated agents,
alkalies, chlorine, hypochlorite.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide.
Hazardous Polymerization: May occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 107-11-9: BA5425000
LD50/LC50:
CAS# 107-11-9: Draize test, rabbit, skin: 500 mg/24H Severe;
Inhalation, rat: LC50 = 177 ppm/8H; Oral, mouse: LD50 = 57 mg/kg;
Oral, rat: LD50 = 102 mg/kg; Skin, rabbit: LD50 = 35 mg/kg.
Carcinogenicity:
Allylamine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Bacteria: Phytobacterium phosphoreum: EC50 = 16 mg/L; 5, 15 minutes;
Microtox test; 14.9-15.1 degrees C
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ALLYLAMINE
Hazard Class: 6.1 (3)
UN Number: 2334
Packing Group:
IMO
Shipping Name: ALLYLAMINE
Hazard Class: 6.1 (3)
UN Number: 2334
Packing Group: I
RID/ADR
Shipping Name: ALLYLAMINE
Hazard Class: 6.1
UN Number: 2334
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 11 Highly flammable.
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 107-11-9: 2
Canada
CAS# 107-11-9 is listed on Canada's DSL List.
CAS# 107-11-9 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 107-11-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/10/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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