**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 106-52-5 |4-Hydroxy-N-Methylpiperidine | 98 | 203-406-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.The toxicological
properties of this material have not been fully investigated.Air
sensitive.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated.
Inhalation:
Causes respiratory tract irritation. Inhalation may be fatal as a
result of spasm, inflammation, edema of the larynx and bronchi,
chemical pneumonitis and pulmonary edema.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Will burn
if involved in a fire. Use water spray to keep fire-exposed
containers cool. Combustible liquid. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined
areas. Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Do NOT get water
inside containers. Use water spray, dry chemical, carbon dioxide, or
appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
Place under an inert atmosphere. Do not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use only in a well-ventilated area. Avoid contact with eyes, skin,
and clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Avoid ingestion and inhalation.
Handle under an inert atmosphere. Store protected from air. Do not
allow contact with water. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames. Keep from contact with moist air and steam.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a cool, dry, well-ventilated area away from
incompatible substances. Do not expose to air. Store protected from
moisture. Store under an inert atmosphere.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 106-52-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Viscous liquid
Color: yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 200 deg C @ 760.00mm Hg
Freezing/Melting Point: 29 - 31 deg C
Autoignition Temperature: Not available.
Flash Point: 87 deg C ( 188.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: miscible with water
Specific Gravity/Density:
Molecular Formula: C6H13NO
Molecular Weight: 115.17
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, exposure to air,
excess heat.
Incompatibilities with Other Materials:
Strong acids, strong bases, strong oxidizing agents, strong reducing
agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 106-52-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Hydroxy-N-Methylpiperidine -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 106-52-5: 2
Canada
CAS# 106-52-5 is listed on Canada's NDSL List.
CAS# 106-52-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 106-52-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/17/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
N,N-Dibutylaniline, 99% (GC)
| 613-29-6 |
|
1,1,1,3,3,3-Hexafluoroacetone sesquihydrate, 98% (gc)
| 684-16-2 |
|
2-Biphenylyl Glycidyl Ether, 95%
| 7144-65-2 |
|
2,4-Dichlorobenzamide, 98%
| 2447-79-2 |
|
Isobutyl methacrylate, 99% (gc), stabilized with 15-20 ppm MEHQ
| 97-86-9 |
|
Picolinic acid n-oxide, 97%
| 824-40-8 |
|
N,n'-dimethylpiperazine, 98%
| 106-58-1 |
|
1,4-Dichlorobutane
| 110-56-5 |
|
1-Acetyl-4-Piperidinecarboxylic Acid, 99%
| 25503-90-6 |
|
Alpha, Alpha, Alpha-Trifluoro-O-Cresol 99%
| 444-30-4 |
|
Trans 2, cis 6-nonadienal diethylacetal, 80%
| 67674-36-6 |
|
Nitronium tetrafluoroborate,97%
| 13826-86-3 |
|
7-Methylindole, 99%
| 933-67-5 |
|
2,3,4,5,6-Pentafluoroaniline, 97%
| 771-60-8 |
|
9-Hydroxyxanthene, 99%
| 90-46-0 |
|
2'-Methoxyacetophenone, 99%
| 579-74-8 |
|
4-Methylindole, 99%
| 16096-32-5 |
|
Benzo[b]naphtho[2,3-d]furan, tech., 90+% (gc)
| 243-42-5 |
|
2-Methyl-3-nitrophenol, 98 %
| 5460-31-1 |
|
Diethylcarbamyl chloride, 99% (titr.)
| 88-10-8 |
|
2'-Chloroacetophenone, 97%
| 2142-68-9 |
|
Trifluoromethanesulfonic acid, 99%
| 1493-13-6 |
|
Acid Blue 45
| 2861-02-1 |
|
N-Alpha-Carbobenzyloxy-D-Arginine, 99+%
| 6382-93-0 |
|
1,2,7,8-Diepoxyoctane, 97%
| 2426-07-5 |
|
Tetrachlorophthalic anhydride, 98% (contains 0.5% Hexachlorobenzene)
| 117-08-8 |
|
4-Hydroxy-N-Methylpiperidine, 98%
| 106-52-5 |
|
Methyl 2,4-dihydroxybenzoate, 97%
| 2150-47-2 |
|
Calmagite, Indicator Grade
| 3147-14-6 |
|
Magnesium bromide hexahydrate, p.a.
| 13446-53-2 |
|
1,5-Naphthalenedisulfonic Acid Disodium Salt, Monohydrate, 95%
| 1655-29-4 |
|
(S)-(+)-2-Amino-2-Methylbutanedioic Acid, 99%
| 0-00-1 |
|
1-Hexanethiol, 99% (GC)
| 111-31-9 |
|
3-Fluorocinnamic Acid
| 458-46-8 |
|
1-Methyl-1-cyclohexanecarboxylic acid, 99%
| 1123-25-7 |
|
1,2-Ethanedisulfonic Acid Disodium Salt
| 5325-43-9 |
|
2-Aminopyrimidine (Pract)
| 109-12-6 |
|
Copper(II) trifluoromethanesulfonate
| 34946-82-2 |
|
4-Nitrobenzenediazonium tetrafluoroborate (pract), 95% (uv-vis)
| 456-27-9 |
|
D-(-)-Gulose, 93-95%, mixture of anomers
| 4205-23-6 |
|
3-Acetoxyacetophenone, 99%
| 2454-35-5 |
|
1-Hydroxy-2,2,5,5-tetramethyl-3-imidazoline 3-oxide, 99%
| 33455-68-4 |
|
(S)-(+)-Glycidyl nosylate, 98%
| 115314-14-2 |
|
2,5-Diaminobenzenesulfonic Acid, Tech. 90%
| 88-45-9 |
|
Selenium atomic absorption standard solution, 1 mg/ml se in 10% hcl
| 7647-01-0 |
|
6-Quinolinecarboxylic Acid, 98% (Titr.)
| 10349-57-2 |
|
2,2-Diphenylpropionic Acid, 97%
| 5558-66-7 |
|
4-Aminoantipyrine
| 83-07-8 |
|
Methyl 3,5-Dimethoxybenzoate, 99%
| 2150-37-0 |
|
N,2,3-Trimethyl-2-Isopropylbutamide
| 51115-67-4 |
|
|