**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 110-56-5 |1,4-Dichlorobutane | >97 | 203-778-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: 10
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable.The toxicological properties of this material have not
been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation and possible burns.
Skin:
May cause skin irritation and possible burns.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. Vapors may cause
dizziness or suffocation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Use water spray to keep fire-exposed containers cool. Flammable
liquid and vapor. Vapors may be heavier than air. They can spread
along the ground and collect in low or confined areas. Vapors may
form an explosive mixture with air. Containers may explode when
heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Do NOT use straight
streams of water. For small fires, use dry chemical, carbon dioxide,
water spray or regular foam. Cool containers with flooding
quantities of water until well after fire is out. For large fires,
use water spray, fog or regular foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition. A
vapor suppressing foam may be used to reduce vapors. Water spray may
reduce vapor but may not prevent ignition in closed spaces.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames. Avoid breathing vapor or
mist.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits.
Exposure Limits
CAS# 110-56-5:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: 5 hPa @ 20 C
Viscosity: 1.46 mPas 20 deg C
Boiling Point: 154 deg C
Freezing/Melting Point: -37 deg C
Autoignition Temperature: 220 deg C ( 428.00 deg F)
Flash Point: 40 deg C ( 104.00 deg F)
Explosion Limits, lower: 1.5 vol %
Explosion Limits, upper: 4.0 vol %
Decomposition Temperature: 120 deg C
Solubility in water: Insoluble.
Specific Gravity/Density: 1.1600g/cm3
Molecular Formula: C4H8Cl2
Molecular Weight: 127.01
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 110-56-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1,4-Dichlorobutane -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Rainbow trout: LC50 = 4.14 mg/L; 96 Hr.; UnspecifiedFish:
Fathead Minnow: LC50 = 5.10 mg/L; 96 Hr.; UnspecifiedWater flea
Daphnia: LC50 = 3.87 mg/L; 48 Hr.; Unspecified
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
R 10 Flammable.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
WGK (Water Danger/Protection)
CAS# 110-56-5: 2
Canada
CAS# 110-56-5 is listed on Canada's NDSL List.
CAS# 110-56-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 110-56-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/03/1999 Revision #4 Date: 5/06/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
N,N-Dibutylaniline, 99% (GC)
| 613-29-6 |
|
1,1,1,3,3,3-Hexafluoroacetone sesquihydrate, 98% (gc)
| 684-16-2 |
|
2-Biphenylyl Glycidyl Ether, 95%
| 7144-65-2 |
|
2,4-Dichlorobenzamide, 98%
| 2447-79-2 |
|
Isobutyl methacrylate, 99% (gc), stabilized with 15-20 ppm MEHQ
| 97-86-9 |
|
Picolinic acid n-oxide, 97%
| 824-40-8 |
|
N,n'-dimethylpiperazine, 98%
| 106-58-1 |
|
1,4-Dichlorobutane
| 110-56-5 |
|
1-Acetyl-4-Piperidinecarboxylic Acid, 99%
| 25503-90-6 |
|
Alpha, Alpha, Alpha-Trifluoro-O-Cresol 99%
| 444-30-4 |
|
Trans 2, cis 6-nonadienal diethylacetal, 80%
| 67674-36-6 |
|
Nitronium tetrafluoroborate,97%
| 13826-86-3 |
|
7-Methylindole, 99%
| 933-67-5 |
|
2,3,4,5,6-Pentafluoroaniline, 97%
| 771-60-8 |
|
9-Hydroxyxanthene, 99%
| 90-46-0 |
|
2'-Methoxyacetophenone, 99%
| 579-74-8 |
|
4-Methylindole, 99%
| 16096-32-5 |
|
Benzo[b]naphtho[2,3-d]furan, tech., 90+% (gc)
| 243-42-5 |
|
2-Methyl-3-nitrophenol, 98 %
| 5460-31-1 |
|
Diethylcarbamyl chloride, 99% (titr.)
| 88-10-8 |
|
2'-Chloroacetophenone, 97%
| 2142-68-9 |
|
Trifluoromethanesulfonic acid, 99%
| 1493-13-6 |
|
Acid Blue 45
| 2861-02-1 |
|
N-Alpha-Carbobenzyloxy-D-Arginine, 99+%
| 6382-93-0 |
|
1,2,7,8-Diepoxyoctane, 97%
| 2426-07-5 |
|
Tetrachlorophthalic anhydride, 98% (contains 0.5% Hexachlorobenzene)
| 117-08-8 |
|
4-Hydroxy-N-Methylpiperidine, 98%
| 106-52-5 |
|
Methyl 2,4-dihydroxybenzoate, 97%
| 2150-47-2 |
|
Calmagite, Indicator Grade
| 3147-14-6 |
|
Magnesium bromide hexahydrate, p.a.
| 13446-53-2 |
|
1,5-Naphthalenedisulfonic Acid Disodium Salt, Monohydrate, 95%
| 1655-29-4 |
|
(S)-(+)-2-Amino-2-Methylbutanedioic Acid, 99%
| 0-00-1 |
|
1-Hexanethiol, 99% (GC)
| 111-31-9 |
|
3-Fluorocinnamic Acid
| 458-46-8 |
|
1-Methyl-1-cyclohexanecarboxylic acid, 99%
| 1123-25-7 |
|
1,2-Ethanedisulfonic Acid Disodium Salt
| 5325-43-9 |
|
2-Aminopyrimidine (Pract)
| 109-12-6 |
|
Copper(II) trifluoromethanesulfonate
| 34946-82-2 |
|
4-Nitrobenzenediazonium tetrafluoroborate (pract), 95% (uv-vis)
| 456-27-9 |
|
D-(-)-Gulose, 93-95%, mixture of anomers
| 4205-23-6 |
|
3-Acetoxyacetophenone, 99%
| 2454-35-5 |
|
1-Hydroxy-2,2,5,5-tetramethyl-3-imidazoline 3-oxide, 99%
| 33455-68-4 |
|
(S)-(+)-Glycidyl nosylate, 98%
| 115314-14-2 |
|
2,5-Diaminobenzenesulfonic Acid, Tech. 90%
| 88-45-9 |
|
Selenium atomic absorption standard solution, 1 mg/ml se in 10% hcl
| 7647-01-0 |
|
6-Quinolinecarboxylic Acid, 98% (Titr.)
| 10349-57-2 |
|
2,2-Diphenylpropionic Acid, 97%
| 5558-66-7 |
|
4-Aminoantipyrine
| 83-07-8 |
|
Methyl 3,5-Dimethoxybenzoate, 99%
| 2150-37-0 |
|
N,2,3-Trimethyl-2-Isopropylbutamide
| 51115-67-4 |
|
|