**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 111-31-9 |1-Hexanethiol | 99 | 203-857-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN F
Risk Phrases: 11 21/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful in contact with skin and if swallowed.
Potential Health Effects
Eye:
May cause eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
May cause irritation and dermatitis. May cause cyanosis of the
extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed. Ingestion of large amounts
may cause CNS depression.
Inhalation:
May cause respiratory tract irritation. Aspiration may lead to
pulmonary edema. Vapors may cause dizziness or suffocation. May cause
burning sensation in the chest.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Water may be
ineffective. Material is lighter than water and a fire may be spread
by the use of water. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors may be heavier than air. They
can spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep away from heat,
sparks and flame. Avoid ingestion and inhalation. Do not pressurize,
cut, weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 111-31-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: None reported.
pH: 4.0
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 150 - 154 deg C @ 760.00mm Hg
Freezing/Melting Point: -81 deg C
Autoignition Temperature: Not available.
Flash Point: 20 deg C ( 68.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: immiscible with water
Specific Gravity/Density: .8380g/cm3
Molecular Formula: C6H14S
Molecular Weight: 118.24
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, irritating and toxic fumes and
gases, carbon dioxide, hydrogen sulfide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 111-31-9: MO4550000
LD50/LC50:
CAS# 111-31-9: Inhalation, mouse: LC50 = 528 ppm/4H; Inhalation,
rat: LC50 = 1080 ppm/4H; Oral, rat: LD50 = 1254 mg/kg.
Carcinogenicity:
1-Hexanethiol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S.*
Hazard Class: 3 (6.1)
UN Number: 1228
Packing Group: II
IMO
Shipping Name: MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S.
Hazard Class: 3.2 (6.1)
UN Number: 1228
Packing Group: II
RID/ADR
Shipping Name: MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S.
Hazard Class: 3
UN Number: 1228
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 11 Highly flammable.
R 21/22 Harmful in contact with skin and if
swallowed.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 33 Take precautionary measures against static
discharges.
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 111-31-9: No information available.
Canada
CAS# 111-31-9 is listed on Canada's DSL List.
CAS# 111-31-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 111-31-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/24/1997 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
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1,1,1,3,3,3-Hexafluoroacetone sesquihydrate, 98% (gc)
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2-Biphenylyl Glycidyl Ether, 95%
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2,4-Dichlorobenzamide, 98%
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Isobutyl methacrylate, 99% (gc), stabilized with 15-20 ppm MEHQ
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Picolinic acid n-oxide, 97%
| 824-40-8 |
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N,n'-dimethylpiperazine, 98%
| 106-58-1 |
|
1,4-Dichlorobutane
| 110-56-5 |
|
1-Acetyl-4-Piperidinecarboxylic Acid, 99%
| 25503-90-6 |
|
Alpha, Alpha, Alpha-Trifluoro-O-Cresol 99%
| 444-30-4 |
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Trans 2, cis 6-nonadienal diethylacetal, 80%
| 67674-36-6 |
|
Nitronium tetrafluoroborate,97%
| 13826-86-3 |
|
7-Methylindole, 99%
| 933-67-5 |
|
2,3,4,5,6-Pentafluoroaniline, 97%
| 771-60-8 |
|
9-Hydroxyxanthene, 99%
| 90-46-0 |
|
2'-Methoxyacetophenone, 99%
| 579-74-8 |
|
4-Methylindole, 99%
| 16096-32-5 |
|
Benzo[b]naphtho[2,3-d]furan, tech., 90+% (gc)
| 243-42-5 |
|
2-Methyl-3-nitrophenol, 98 %
| 5460-31-1 |
|
Diethylcarbamyl chloride, 99% (titr.)
| 88-10-8 |
|
2'-Chloroacetophenone, 97%
| 2142-68-9 |
|
Trifluoromethanesulfonic acid, 99%
| 1493-13-6 |
|
Acid Blue 45
| 2861-02-1 |
|
N-Alpha-Carbobenzyloxy-D-Arginine, 99+%
| 6382-93-0 |
|
1,2,7,8-Diepoxyoctane, 97%
| 2426-07-5 |
|
Tetrachlorophthalic anhydride, 98% (contains 0.5% Hexachlorobenzene)
| 117-08-8 |
|
4-Hydroxy-N-Methylpiperidine, 98%
| 106-52-5 |
|
Methyl 2,4-dihydroxybenzoate, 97%
| 2150-47-2 |
|
Calmagite, Indicator Grade
| 3147-14-6 |
|
Magnesium bromide hexahydrate, p.a.
| 13446-53-2 |
|
1,5-Naphthalenedisulfonic Acid Disodium Salt, Monohydrate, 95%
| 1655-29-4 |
|
(S)-(+)-2-Amino-2-Methylbutanedioic Acid, 99%
| 0-00-1 |
|
1-Hexanethiol, 99% (GC)
| 111-31-9 |
|
3-Fluorocinnamic Acid
| 458-46-8 |
|
1-Methyl-1-cyclohexanecarboxylic acid, 99%
| 1123-25-7 |
|
1,2-Ethanedisulfonic Acid Disodium Salt
| 5325-43-9 |
|
2-Aminopyrimidine (Pract)
| 109-12-6 |
|
Copper(II) trifluoromethanesulfonate
| 34946-82-2 |
|
4-Nitrobenzenediazonium tetrafluoroborate (pract), 95% (uv-vis)
| 456-27-9 |
|
D-(-)-Gulose, 93-95%, mixture of anomers
| 4205-23-6 |
|
3-Acetoxyacetophenone, 99%
| 2454-35-5 |
|
1-Hydroxy-2,2,5,5-tetramethyl-3-imidazoline 3-oxide, 99%
| 33455-68-4 |
|
(S)-(+)-Glycidyl nosylate, 98%
| 115314-14-2 |
|
2,5-Diaminobenzenesulfonic Acid, Tech. 90%
| 88-45-9 |
|
Selenium atomic absorption standard solution, 1 mg/ml se in 10% hcl
| 7647-01-0 |
|
6-Quinolinecarboxylic Acid, 98% (Titr.)
| 10349-57-2 |
|
2,2-Diphenylpropionic Acid, 97%
| 5558-66-7 |
|
4-Aminoantipyrine
| 83-07-8 |
|
Methyl 3,5-Dimethoxybenzoate, 99%
| 2150-37-0 |
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N,2,3-Trimethyl-2-Isopropylbutamide
| 51115-67-4 |
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|