**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 2142-68-9 |2'-Chloroacetophenone | 97 | 218-397-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes, respiratory system and
skin.Harmful.Lachrymator (substance which increases the flow of
tears).
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears). May cause chemical conjunctivitis and corneal
damage.
Skin:
May cause irritation and dermatitis. May cause cyanosis of the
extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
Aspiration may lead to pulmonary edema. May cause burning sensation,
coughing, wheezing, laryngitis, shortness of breath, headache,
nausea, and vomiting. Inhalation at high concentrations may cause
CNS depression and asphixiation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Use water spray to keep fire-exposed containers
cool. Combustible liquid. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas.
Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. This material is lighter than water and insoluble in
water. The fire could easily be spread by the use of water in an
area where the water cannot be contained.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Cover with sand, dry lime or soda ash and place in a closed
container for disposal. Remove all sources of ignition. Use a
spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame. Do
not ingest or inhale. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 2142-68-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear amber
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 227.0 - 230.0 deg C @ 760.00m
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 88 deg C ( 190.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: 1.1880g/cm3
Molecular Formula: C8H7ClO
Molecular Weight: 154.60
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, chloride fumes.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 2142-68-9: AM6310000
LD50/LC50:
CAS# 2142-68-9: Oral, mouse: LD50 = 880 mg/kg; Oral, rat: LD50 =
1820 mg/kg.
Carcinogenicity:
2'-Chloroacetophenone -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CHLOROACETOPHENONE, LIQUID
Hazard Class: 6.1
UN Number: 1697
Packing Group: II
IMO
Shipping Name: CHLOROACETOPHENONE, LIQUID
Hazard Class: 6.1
UN Number: 1697
Packing Group: II
RID/ADR
Shipping Name: CHLOROACETOPHENONE
Hazard Class: 6.1
UN Number: 1697
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 2142-68-9: No information available.
Canada
CAS# 2142-68-9 is listed on Canada's NDSL List.
CAS# 2142-68-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2142-68-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #6 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
N,N-Dibutylaniline, 99% (GC)
| 613-29-6 |
|
1,1,1,3,3,3-Hexafluoroacetone sesquihydrate, 98% (gc)
| 684-16-2 |
|
2-Biphenylyl Glycidyl Ether, 95%
| 7144-65-2 |
|
2,4-Dichlorobenzamide, 98%
| 2447-79-2 |
|
Isobutyl methacrylate, 99% (gc), stabilized with 15-20 ppm MEHQ
| 97-86-9 |
|
Picolinic acid n-oxide, 97%
| 824-40-8 |
|
N,n'-dimethylpiperazine, 98%
| 106-58-1 |
|
1,4-Dichlorobutane
| 110-56-5 |
|
1-Acetyl-4-Piperidinecarboxylic Acid, 99%
| 25503-90-6 |
|
Alpha, Alpha, Alpha-Trifluoro-O-Cresol 99%
| 444-30-4 |
|
Trans 2, cis 6-nonadienal diethylacetal, 80%
| 67674-36-6 |
|
Nitronium tetrafluoroborate,97%
| 13826-86-3 |
|
7-Methylindole, 99%
| 933-67-5 |
|
2,3,4,5,6-Pentafluoroaniline, 97%
| 771-60-8 |
|
9-Hydroxyxanthene, 99%
| 90-46-0 |
|
2'-Methoxyacetophenone, 99%
| 579-74-8 |
|
4-Methylindole, 99%
| 16096-32-5 |
|
Benzo[b]naphtho[2,3-d]furan, tech., 90+% (gc)
| 243-42-5 |
|
2-Methyl-3-nitrophenol, 98 %
| 5460-31-1 |
|
Diethylcarbamyl chloride, 99% (titr.)
| 88-10-8 |
|
2'-Chloroacetophenone, 97%
| 2142-68-9 |
|
Trifluoromethanesulfonic acid, 99%
| 1493-13-6 |
|
Acid Blue 45
| 2861-02-1 |
|
N-Alpha-Carbobenzyloxy-D-Arginine, 99+%
| 6382-93-0 |
|
1,2,7,8-Diepoxyoctane, 97%
| 2426-07-5 |
|
Tetrachlorophthalic anhydride, 98% (contains 0.5% Hexachlorobenzene)
| 117-08-8 |
|
4-Hydroxy-N-Methylpiperidine, 98%
| 106-52-5 |
|
Methyl 2,4-dihydroxybenzoate, 97%
| 2150-47-2 |
|
Calmagite, Indicator Grade
| 3147-14-6 |
|
Magnesium bromide hexahydrate, p.a.
| 13446-53-2 |
|
1,5-Naphthalenedisulfonic Acid Disodium Salt, Monohydrate, 95%
| 1655-29-4 |
|
(S)-(+)-2-Amino-2-Methylbutanedioic Acid, 99%
| 0-00-1 |
|
1-Hexanethiol, 99% (GC)
| 111-31-9 |
|
3-Fluorocinnamic Acid
| 458-46-8 |
|
1-Methyl-1-cyclohexanecarboxylic acid, 99%
| 1123-25-7 |
|
1,2-Ethanedisulfonic Acid Disodium Salt
| 5325-43-9 |
|
2-Aminopyrimidine (Pract)
| 109-12-6 |
|
Copper(II) trifluoromethanesulfonate
| 34946-82-2 |
|
4-Nitrobenzenediazonium tetrafluoroborate (pract), 95% (uv-vis)
| 456-27-9 |
|
D-(-)-Gulose, 93-95%, mixture of anomers
| 4205-23-6 |
|
3-Acetoxyacetophenone, 99%
| 2454-35-5 |
|
1-Hydroxy-2,2,5,5-tetramethyl-3-imidazoline 3-oxide, 99%
| 33455-68-4 |
|
(S)-(+)-Glycidyl nosylate, 98%
| 115314-14-2 |
|
2,5-Diaminobenzenesulfonic Acid, Tech. 90%
| 88-45-9 |
|
Selenium atomic absorption standard solution, 1 mg/ml se in 10% hcl
| 7647-01-0 |
|
6-Quinolinecarboxylic Acid, 98% (Titr.)
| 10349-57-2 |
|
2,2-Diphenylpropionic Acid, 97%
| 5558-66-7 |
|
4-Aminoantipyrine
| 83-07-8 |
|
Methyl 3,5-Dimethoxybenzoate, 99%
| 2150-37-0 |
|
N,2,3-Trimethyl-2-Isopropylbutamide
| 51115-67-4 |
|
|