**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 106-70-7 |Methyl Hexanoate | 98 | 203-425-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F
Risk Phrases: 10
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Vapors may cause dizziness or suffocation. Contact with the liquid
or vapor may cause respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion. Will burn if involved in a fire.
Use water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. A vapor suppressing foam
may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Remove contaminated clothing and wash before reuse. Use only in a
well-ventilated area. Ground and bond containers when transferring
material. Use spark-proof tools and explosion proof equipment. Avoid
contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use process enclosure,
local exhaust ventilation, or other engineering controls to control
airborne levels.
Exposure Limits
CAS# 106-70-7:
Russia: 1 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear a chemical apron. Wear appropriate protective
clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use. Follow the OSHA
respirator regulations found in 29 CFR 1910.134 or
European Standard EN 149. Use a NIOSH/MSHA or
European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or
other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear almost colorless
Odor: acetic odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 151 deg C
Freezing/Melting Point: -71 deg C
Autoignition Temperature: Not available.
Flash Point: 42 deg C ( 107.60 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: .8840g/cm3
Molecular Formula: C7H14O2
Molecular Weight: 130.19
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong acids, strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 106-70-7: MO8401400
LD50/LC50:
CAS# 106-70-7: Dermal, guinea pig: LD50 = >5 gm/kg; Inhalation,
mouse: LC50 = 14 gm/m3/2H; Oral, rat: LD50 = >5 gm/kg.
Carcinogenicity:
Methyl Hexanoate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 10 Flammable.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 106-70-7: No information available.
Canada
CAS# 106-70-7 is listed on Canada's DSL List.
CAS# 106-70-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 106-70-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/24/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Phloroglucinol
| 108-73-6 |
|
Tetrapropylammonium bromide, 98%
| 1941-30-6 |
|
Octacosanoic acid, 99+%
| 506-48-9 |
|
n-Hexyl Sulfide, 95%
| 6294-31-1 |
|
cis-2-Amino-1-cyclopentanecarboxylic acid, 98+%
| 37910-65-9 |
|
Dimethyl 5-Sulfoisophthalate, Sodium Salt, Hydrate, 98%
| 3965-55-7 |
|
Phosphoric acid, 85%
| 7664-38-2 |
|
Phosphorus Pentoxide
| 1314-56-3 |
|
P-Tolyl Disulfide, 98%
| 103-19-5 |
|
1-Bromo-2-Propanol, Tech., 70%, Remainder 2-Bromo-1-Propanol
| 19686-73-8 |
|
1,2-Difluorobenzene, 98%
| 367-11-3 |
|
Glyoxal di(sodium bisulfite)
| 517-21-5 |
|
Phosphorus Oxychloride
| 10025-87-3 |
|
Potassium Osmate(VI) Dihydrate
| 19718-36-6 |
|
Tetrabutylammonium Chloride (50% in Water)
| 1112-67-0 |
|
3,3'-Diethylthiatricarbocyanine perchlorate, laser grade
| 22268-66-2 |
|
3-Aminopyrazole, 98%
| 1820-80-0 |
|
Undecanoic Acid, 99%
| 112-37-8 |
|
Glycine Hydrochloride, 99% (Titr.)
| 6000-43-7 |
|
Phosphotungstic acid
| 12067-99-1 |
|
Phthalaldehyde
| 643-79-8 |
|
Benzophenone hydrazone, 98+%
| 5350-57-2 |
|
4-Hexadecyloxybenzoic acid, 98%
| 15872-48-7 |
|
Boron trifluoride etherate, ca. 48% bf3
| 109-63-7 |
|
1,7-Heptanediol, 95%
| 629-30-1 |
|
Picric acid, wetted with at least 30% water, by mass
| 88-89-1 |
|
5-Methylindole, 99%
| 614-96-0 |
|
n-Isopropylbenzylamine, 97%
| 102-97-6 |
|
p-Bromoanisole, 95% (gc)
| 104-92-7 |
|
3,3'-(4,4'-Biphenylene)bis(2,5-diphenyl-2H-tetrazolium chloride), 95%
| 298-95-3 |
|
2-(P-Toluenesulfonyl)Acetamide
| 52345-47-8 |
|
4-Methylsulphonyl Benzonitrile, 95+%
| 22821-76-7 |
|
Piperidine
| 110-89-4 |
|
2,4-Dimethylbenzenesulfonic acid sodium salt, 95% (uv-vis)
| 827-21-4 |
|
Propyl Sulfone
| 598-03-8 |
|
Cis-2-Amino-4-Cyclohexene-1-Carboxylic Acid, 98+%
| 54162-90-2 |
|
Methyl Hexanoate, 98% (GC)
| 106-70-7 |
|
4-Methyl-2H-Imidazole-1-Oxide-2-Spirocyclo Hexane, 99.5+%
| 0-01-1 |
|
2-Ethylhexylamine 99%
| 104-75-6 |
|
Naphthalene-Bis(Hexachlorocyclopentadiene) Adduct, 99%
| 5696-92-4 |
|
4-Amino-3-Nitrobenzoic Acid, 98% (UV-Vis)
| 1588-83-6 |
|
Isoeugenol, 99%, Cis/Trans Mixture
| 97-54-1 |
|
2,4-Dichloro-3-ethylphenol
| 121518-45- |
|
Platinium (IV) potassium chloride
| 16921-30-5 |
|
Ethyl 4,4,4-Trifluoroacetoacetate, 97%
| 372-31-6 |
|
2-Methyl-1-(3-sulfopropyl)naphtho(1,2-d) thiazolium inner salt, 95%
| 3176-77-0 |
|
P-Bromophenethyl Alcohol, 99%
| 4654-39-1 |
|
Ethyl 3,3-diethoxypropanoate, 98%
| 10601-80-6 |
|
4'-(Benzyloxy)-2-bromopropiophenone, 97%
| 0-00-1 |
|
Tryptamine hydrochloride, 98%
| 343-94-2 |
|
|