**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 109-63-7 |Boron trifluoride etherate, ca.48% BF3| 100 % | 203-689-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F C
Risk Phrases: 15 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Contact with water liberates extremely flammable gases. Causes
burns.Corrosive.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns. May cause irreversible eye injury.
Skin:
Causes skin burns.
Ingestion:
Harmful if swallowed. Causes digestive tract burns with immediate
pain, swelling of the throat, convulsions, and possible coma.
Inhalation:
Causes severe irritation of upper respiratory tract with coughing,
burns, breathing difficulty, and possible coma.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Can burn in a fire, releasing toxic vapors. Will burn if
involved in a fire.
Extinguishing Media:
Use carbon dioxide or dry chemical.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Use with adequate
ventilation. Do not breathe dust, vapor, mist, or gas. Do not get in
eyes, on skin, or on clothing. Take precautionary measures against
static discharges. Do not ingest or inhale.
Storage:
Keep away from heat and flame. Store in a cool, dry place. Store in
a tightly closed container. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits.
Exposure Limits
CAS# 109-63-7:
United States OSHA: 2.5 mg/m3 TWA (as F) (listed under Fluorides
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear straw colored
Odor: Not available.
pH: Not available.
Vapor Pressure: 60 mbar @ 20 C
Viscosity: 10.5 deg C
Boiling Point: 126 deg C @ 760.00mm Hg
Freezing/Melting Point: -60 deg C
Autoignition Temperature: 185 deg C ( 365.00 deg F)
Flash Point: 110 deg C ( 230.00 deg F)
Explosion Limits, lower: 5.10 vol %
Explosion Limits, upper: 18.20 vol %
Decomposition Temperature: 110 deg C
Solubility in water: reacts with water
Specific Gravity/Density: 1.1280g/cm3
Molecular Formula: C4H10BF3O
Molecular Weight: 141.93
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Mechanical shock, temperatures above recommended temperatures,
incompatible materials, ignition sources, temperatures above 50C
(122F), exposure to moist air or water.
Incompatibilities with Other Materials:
Acids, bases, alcohols, alkali metals, steel, water, and metals.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, boron trifluoride, diethyl ether,
hydrogen fluoride gas, oxides of boron.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 109-63-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Boron trifluoride etherate, ca.48% BF3 -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: BORON TRIFLUORIDE DIETHYL ETHERATE
Hazard Class: 8 (3)
UN Number: 2604
Packing Group: I
IMO
Shipping Name: BORON TRIFLUORIDE DIETHYL ETHERATE
Hazard Class: 8 (3)
UN Number: 2604
Packing Group: I
RID/ADR
Shipping Name: BORON TRIFLUORIDE DIETHYL ETHERATE
Hazard Class: 8 (3)
UN Number: 2604
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 15 Contact with water liberates extremely
flammable gases.
R 34 Causes burns.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 109-63-7: No information available.
Canada
CAS# 109-63-7 is listed on Canada's DSL List.
CAS# 109-63-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 109-63-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
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Tetrapropylammonium bromide, 98%
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n-Hexyl Sulfide, 95%
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cis-2-Amino-1-cyclopentanecarboxylic acid, 98+%
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Dimethyl 5-Sulfoisophthalate, Sodium Salt, Hydrate, 98%
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Phosphoric acid, 85%
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Phosphorus Pentoxide
| 1314-56-3 |
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P-Tolyl Disulfide, 98%
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1-Bromo-2-Propanol, Tech., 70%, Remainder 2-Bromo-1-Propanol
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1,2-Difluorobenzene, 98%
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3,3'-Diethylthiatricarbocyanine perchlorate, laser grade
| 22268-66-2 |
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3-Aminopyrazole, 98%
| 1820-80-0 |
|
Undecanoic Acid, 99%
| 112-37-8 |
|
Glycine Hydrochloride, 99% (Titr.)
| 6000-43-7 |
|
Phosphotungstic acid
| 12067-99-1 |
|
Phthalaldehyde
| 643-79-8 |
|
Benzophenone hydrazone, 98+%
| 5350-57-2 |
|
4-Hexadecyloxybenzoic acid, 98%
| 15872-48-7 |
|
Boron trifluoride etherate, ca. 48% bf3
| 109-63-7 |
|
1,7-Heptanediol, 95%
| 629-30-1 |
|
Picric acid, wetted with at least 30% water, by mass
| 88-89-1 |
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| 614-96-0 |
|
n-Isopropylbenzylamine, 97%
| 102-97-6 |
|
p-Bromoanisole, 95% (gc)
| 104-92-7 |
|
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| 298-95-3 |
|
2-(P-Toluenesulfonyl)Acetamide
| 52345-47-8 |
|
4-Methylsulphonyl Benzonitrile, 95+%
| 22821-76-7 |
|
Piperidine
| 110-89-4 |
|
2,4-Dimethylbenzenesulfonic acid sodium salt, 95% (uv-vis)
| 827-21-4 |
|
Propyl Sulfone
| 598-03-8 |
|
Cis-2-Amino-4-Cyclohexene-1-Carboxylic Acid, 98+%
| 54162-90-2 |
|
Methyl Hexanoate, 98% (GC)
| 106-70-7 |
|
4-Methyl-2H-Imidazole-1-Oxide-2-Spirocyclo Hexane, 99.5+%
| 0-01-1 |
|
2-Ethylhexylamine 99%
| 104-75-6 |
|
Naphthalene-Bis(Hexachlorocyclopentadiene) Adduct, 99%
| 5696-92-4 |
|
4-Amino-3-Nitrobenzoic Acid, 98% (UV-Vis)
| 1588-83-6 |
|
Isoeugenol, 99%, Cis/Trans Mixture
| 97-54-1 |
|
2,4-Dichloro-3-ethylphenol
| 121518-45- |
|
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| 16921-30-5 |
|
Ethyl 4,4,4-Trifluoroacetoacetate, 97%
| 372-31-6 |
|
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| 3176-77-0 |
|
P-Bromophenethyl Alcohol, 99%
| 4654-39-1 |
|
Ethyl 3,3-diethoxypropanoate, 98%
| 10601-80-6 |
|
4'-(Benzyloxy)-2-bromopropiophenone, 97%
| 0-00-1 |
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| 343-94-2 |
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|