**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 88-89-1 |Picric acid | <70 | 201-865-9 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | >30 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: T F
Risk Phrases: 1 11 23/24/25 4 43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Explosive when dry. Highly flammable. Toxic by inhalation, in
contact with skin and if swallowed. Forms very sensitive explosive
metallic compounds. May cause sensitization by skin contact.
Potential Health Effects
Eye:
Causes eye irritation. May result in corneal injury.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea. May cause corrosion and permanent
tissue destruction of the esophagus and digestive tract. May cause
headache.
Inhalation:
May cause respiratory tract irritation. Material has a low vapor
pressure, so exposure to vapor is not likely.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. May cause
kidney injury. Prolonged or repeated exposure may cause yellow
staining of the skin and conjunctiva and "yellow vision".
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Evacuate area and fight fire from a safe distance. As in any fire,
wear a self-contained breathing apparatus in pressure-demand,
MSHA/NIOSH (approved or equivalent), and full protective gear.
Exposure to heat may promote violent decomposition. This material is
an explosion hazard when exposed to heat, mechanical shock, or
friction. This material poses an explosion hazard when dry. Approach
fire from upwind to avoid hazardous vapors and toxic decomposition
products.
Extinguishing Media:
Do NOT use carbon dioxide. Do NOT use halogenated agents. Use
flooding quantities of water as spray. Cool containers with flooding
quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Remove all sources of ignition. If the material is dry, explosives
experts may be necessary to dispose of the spill. Isolate area and
deny entry. Wet area to prevent drying out. Provide ventilation.
Evacuate unnecessary personnel.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Material is heat, shock
and/or friction sensitive. Use care in handling and storage. Loosen
closure cautiously before opening. Avoid breathing dust, vapor,
mist, or gas. Avoid contact with eyes, skin, and clothing. Keep away
from heat, sparks and flame. Container should be opened by a
technically qualified person. Avoid mechanical shock and friction.
Do not allow water to evaporate from product. Dry picric acid is
explosive. Dried crystals may be present within threads of screw top
containers and present a detonation hazard when opening. If a bottle
of picric acid is old and has a metal cap, care must be exercised as
highly shock sensitive metal picrates may have formed.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Keep container closed
to prevent drying out. Store in a cool, dry, well-ventilated area
away from incompatible substances. Keep away from metals. Material
can explode if dry. Do not store on concrete. Separate from organic
materials. Protect from freezing.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.
Exposure Limits
CAS# 88-89-1:
United Kingdom, WEL - TWA: 0.1 mg/m3 TWA
United Kingdom, WEL - STEL: 0.3 mg/m3 STEL
United States OSHA: 0.1 mg/m3 TWA
Belgium - TWA: 0.1 mg/m3 VLE
France - VME: 0.1 mg/m3 VME
Germany: 0.1 mg/m3 TWA (inhalable fraction)
Germany: Skin absorber
Malaysia: 0.1 mg/m3 TWA
Netherlands: 0.1 mg/m3 MAC
Spain: 0.1 mg/m3 VLA-ED
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Slurry
Color: yellow
Odor: odorless
pH: 1.3 (1.4% sat aq soln)
Vapor Pressure: Negligible
Viscosity: Not available.
Boiling Point: Not applicable.
Freezing/Melting Point: 121.8 deg C
Autoignition Temperature: 300 deg C ( 572.00 deg F)
Flash Point: 150 deg C ( 302.00 deg F)
Explosion Limits, lower: None reported.
Explosion Limits, upper: None reported.
Decomposition Temperature: 300 deg C
Solubility in water: 1.27 g/100ml
Specific Gravity/Density: 1.767
Molecular Formula: C6H2(NO2)3OH
Molecular Weight: 229.0369
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Do not allow water to evaporate from product. Dry picric acid is
explosive. Explodes above 572F (300C) with release of oxides of
nitrogen.
Conditions to Avoid:
High temperatures, mechanical shock, ignition sources, Do not allow
water to evaporate from product. Dry picric acid is explosive..
Incompatibilities with Other Materials:
Metals, reducing agents, bases, amines, ammonia, concrete (forms
friction sensitive calcium picrate).
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 88-89-1: TJ7875000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 88-89-1: Oral, rat: LD50 = 200 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Picric acid -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Rainbow trout (Salmo gairdneri), LC50=109.6 mg/L/96 hr; American
oysters (Crassotrea virginica), LC50=254.9 mg/L/14 hr; Bluegill
(Lepomis macrachirus), LC50=193 mg/L/24 hr
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Trinitrophenol
Hazard Class: 1.1
UN Number: 0154
Packing Group: II
IMO
Shipping Name: Trinitrophenol
Hazard Class: 1.1
UN Number: 0154
Packing Group: II
RID/ADR
Shipping Name: Trinitrophenol
Hazard Class: 1.1
UN Number: 0154
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 1 Explosive when dry.
R 11 Highly flammable.
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 4 Forms very sensitive explosive metallic
compounds.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 28 After contact with skin, wash immediately
with...
S 35 This material and its container must be
disposed of in a safe way.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 88-89-1: 2
CAS# 7732-18-5: No information available.
Canada
CAS# 88-89-1 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 88-89-1 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 88-89-1 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 5/13/1998 Revision #4 Date: 3/03/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
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| 0-01-1 |
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