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MSDS 
:
 Phloroglucinol
CAS 
:
 108-73-6
SYNONYMS 
:
 1,3,5-Benzenetriol
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 108-73-6 |Phloroglucinol | 100 % | 203-611-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/22

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed.

Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
Ingestion of large amounts may cause gastrointestinal irritation.
Inhalation:
May cause respiratory tract irritation.
Chronic:
No information found.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Flush skin with plenty of soap and water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician:

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with skin and eyes. Keep container tightly closed. Avoid
ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134 or European Standard EN 149. Always use a
NIOSH or European Standard EN 149 approved respirator
when necessary.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Solid
Appearance: white to off-white
Odor: Odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Decomposes
Freezing/Melting Point: 421-432 F
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Slightly soluble in water
Specific Gravity/Density: 1.46
Molecular Formula: C6H3(OH)3
Molecular Weight: 126.0402

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, moisture.
Incompatibilities with Other Materials:
Strong oxidizing agents
Hazardous Decomposition Products:
No data available.
Hazardous Polymerization: Has not been reported.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 108-73-6: SY1050000
LD50/LC50:
CAS# 108-73-6: Oral, mouse: LD50 = 4550 mg/kg; Oral, rat: LD50 = 4
gm/kg.
Carcinogenicity:
Phloroglucinol -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****



**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 108-73-6: No information available.
United Kingdom Occupational Exposure Limits

Canada
CAS# 108-73-6 is listed on Canada's DSL List.
CAS# 108-73-6 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 108-73-6 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 12/12/1997 Revision #1 Date: 8/02/2000

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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NAMECAS
Phloroglucinol 108-73-6
Tetrapropylammonium bromide, 98% 1941-30-6
Octacosanoic acid, 99+% 506-48-9
n-Hexyl Sulfide, 95% 6294-31-1
cis-2-Amino-1-cyclopentanecarboxylic acid, 98+% 37910-65-9
Dimethyl 5-Sulfoisophthalate, Sodium Salt, Hydrate, 98% 3965-55-7
Phosphoric acid, 85% 7664-38-2
Phosphorus Pentoxide 1314-56-3
P-Tolyl Disulfide, 98% 103-19-5
1-Bromo-2-Propanol, Tech., 70%, Remainder 2-Bromo-1-Propanol 19686-73-8
1,2-Difluorobenzene, 98% 367-11-3
Glyoxal di(sodium bisulfite) 517-21-5
Phosphorus Oxychloride 10025-87-3
Potassium Osmate(VI) Dihydrate 19718-36-6
Tetrabutylammonium Chloride (50% in Water) 1112-67-0
3,3'-Diethylthiatricarbocyanine perchlorate, laser grade 22268-66-2
3-Aminopyrazole, 98% 1820-80-0
Undecanoic Acid, 99% 112-37-8
Glycine Hydrochloride, 99% (Titr.) 6000-43-7
Phosphotungstic acid 12067-99-1
Phthalaldehyde 643-79-8
Benzophenone hydrazone, 98+% 5350-57-2
4-Hexadecyloxybenzoic acid, 98% 15872-48-7
Boron trifluoride etherate, ca. 48% bf3 109-63-7
1,7-Heptanediol, 95% 629-30-1
Picric acid, wetted with at least 30% water, by mass 88-89-1
5-Methylindole, 99% 614-96-0
n-Isopropylbenzylamine, 97% 102-97-6
p-Bromoanisole, 95% (gc) 104-92-7
3,3'-(4,4'-Biphenylene)bis(2,5-diphenyl-2H-tetrazolium chloride), 95% 298-95-3
2-(P-Toluenesulfonyl)Acetamide 52345-47-8
4-Methylsulphonyl Benzonitrile, 95+% 22821-76-7
Piperidine 110-89-4
2,4-Dimethylbenzenesulfonic acid sodium salt, 95% (uv-vis) 827-21-4
Propyl Sulfone 598-03-8
Cis-2-Amino-4-Cyclohexene-1-Carboxylic Acid, 98+% 54162-90-2
Methyl Hexanoate, 98% (GC) 106-70-7
4-Methyl-2H-Imidazole-1-Oxide-2-Spirocyclo Hexane, 99.5+% 0-01-1
2-Ethylhexylamine 99% 104-75-6
Naphthalene-Bis(Hexachlorocyclopentadiene) Adduct, 99% 5696-92-4
4-Amino-3-Nitrobenzoic Acid, 98% (UV-Vis) 1588-83-6
Isoeugenol, 99%, Cis/Trans Mixture 97-54-1
2,4-Dichloro-3-ethylphenol 121518-45-
Platinium (IV) potassium chloride 16921-30-5
Ethyl 4,4,4-Trifluoroacetoacetate, 97% 372-31-6
2-Methyl-1-(3-sulfopropyl)naphtho(1,2-d) thiazolium inner salt, 95% 3176-77-0
P-Bromophenethyl Alcohol, 99% 4654-39-1
Ethyl 3,3-diethoxypropanoate, 98% 10601-80-6
4'-(Benzyloxy)-2-bromopropiophenone, 97% 0-00-1
Tryptamine hydrochloride, 98% 343-94-2

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