**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 19686-73-8 |1-Bromo-2-Propanol | 70% | 243-225-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 10 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause lacrimation (tearing), blurred
vision, and photophobia. May cause chemical conjunctivitis and
corneal damage.
Skin:
May cause skin irritation and possible burns. May cause cyanosis of
the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Ingestion of large amounts may cause CNS depression. May
cause cardiac abnormalities.
Inhalation:
Causes respiratory tract irritation. Aspiration may lead to
pulmonary edema. Vapors may cause dizziness or suffocation. May
cause cardiac abnormalities. Olfactory fatigue may occur. May cause
burning sensation in the chest.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Vapors may form an explosive mixture with air. Vapors can travel to
a source of ignition and flash back. During a fire, irritating and
highly toxic gases may be generated by thermal decomposition or
combustion. Will burn if involved in a fire. Containers may explode
in the heat of a fire. Flammable liquid and vapor. Vapors may be
heavier than air. They can spread along the ground and collect in
low or confined areas. May burn rapidly with flare burning effect.
May re-ignite after fire is extinguished. Runoff from fire control
or dilution water may cause pollution.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Water may be ineffective. Do NOT use
straight streams of water. Contact professional fire-fighters
immediately. Cool containers with flooding quantities of water until
well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Use with adequate ventilation. Wash clothing before
reuse. Do not pressurize, cut, weld, braze, solder, drill, grind, or
expose empty containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use process enclosure,
local exhaust ventilation, or other engineering controls to control
airborne levels.
Exposure Limits
CAS# 19686-73-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear colorless to amber
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 145 - 148 deg C @ 760.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 54 deg C ( 129.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble in water
Specific Gravity/Density: 1.5300g/cm3
Molecular Formula: C3H7BrO
Molecular Weight: 138.99
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 19686-73-8: UA7388000
LD50/LC50:
Not available.
Carcinogenicity:
1-Bromo-2-Propanol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 10 Flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 33 Take precautionary measures against static
discharges.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 19686-73-8: No information available.
Canada
CAS# 19686-73-8 is listed on Canada's NDSL List.
CAS# 19686-73-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 19686-73-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #6 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
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Tetrapropylammonium bromide, 98%
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|
Octacosanoic acid, 99+%
| 506-48-9 |
|
n-Hexyl Sulfide, 95%
| 6294-31-1 |
|
cis-2-Amino-1-cyclopentanecarboxylic acid, 98+%
| 37910-65-9 |
|
Dimethyl 5-Sulfoisophthalate, Sodium Salt, Hydrate, 98%
| 3965-55-7 |
|
Phosphoric acid, 85%
| 7664-38-2 |
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Phosphorus Pentoxide
| 1314-56-3 |
|
P-Tolyl Disulfide, 98%
| 103-19-5 |
|
1-Bromo-2-Propanol, Tech., 70%, Remainder 2-Bromo-1-Propanol
| 19686-73-8 |
|
1,2-Difluorobenzene, 98%
| 367-11-3 |
|
Glyoxal di(sodium bisulfite)
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Potassium Osmate(VI) Dihydrate
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Tetrabutylammonium Chloride (50% in Water)
| 1112-67-0 |
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3,3'-Diethylthiatricarbocyanine perchlorate, laser grade
| 22268-66-2 |
|
3-Aminopyrazole, 98%
| 1820-80-0 |
|
Undecanoic Acid, 99%
| 112-37-8 |
|
Glycine Hydrochloride, 99% (Titr.)
| 6000-43-7 |
|
Phosphotungstic acid
| 12067-99-1 |
|
Phthalaldehyde
| 643-79-8 |
|
Benzophenone hydrazone, 98+%
| 5350-57-2 |
|
4-Hexadecyloxybenzoic acid, 98%
| 15872-48-7 |
|
Boron trifluoride etherate, ca. 48% bf3
| 109-63-7 |
|
1,7-Heptanediol, 95%
| 629-30-1 |
|
Picric acid, wetted with at least 30% water, by mass
| 88-89-1 |
|
5-Methylindole, 99%
| 614-96-0 |
|
n-Isopropylbenzylamine, 97%
| 102-97-6 |
|
p-Bromoanisole, 95% (gc)
| 104-92-7 |
|
3,3'-(4,4'-Biphenylene)bis(2,5-diphenyl-2H-tetrazolium chloride), 95%
| 298-95-3 |
|
2-(P-Toluenesulfonyl)Acetamide
| 52345-47-8 |
|
4-Methylsulphonyl Benzonitrile, 95+%
| 22821-76-7 |
|
Piperidine
| 110-89-4 |
|
2,4-Dimethylbenzenesulfonic acid sodium salt, 95% (uv-vis)
| 827-21-4 |
|
Propyl Sulfone
| 598-03-8 |
|
Cis-2-Amino-4-Cyclohexene-1-Carboxylic Acid, 98+%
| 54162-90-2 |
|
Methyl Hexanoate, 98% (GC)
| 106-70-7 |
|
4-Methyl-2H-Imidazole-1-Oxide-2-Spirocyclo Hexane, 99.5+%
| 0-01-1 |
|
2-Ethylhexylamine 99%
| 104-75-6 |
|
Naphthalene-Bis(Hexachlorocyclopentadiene) Adduct, 99%
| 5696-92-4 |
|
4-Amino-3-Nitrobenzoic Acid, 98% (UV-Vis)
| 1588-83-6 |
|
Isoeugenol, 99%, Cis/Trans Mixture
| 97-54-1 |
|
2,4-Dichloro-3-ethylphenol
| 121518-45- |
|
Platinium (IV) potassium chloride
| 16921-30-5 |
|
Ethyl 4,4,4-Trifluoroacetoacetate, 97%
| 372-31-6 |
|
2-Methyl-1-(3-sulfopropyl)naphtho(1,2-d) thiazolium inner salt, 95%
| 3176-77-0 |
|
P-Bromophenethyl Alcohol, 99%
| 4654-39-1 |
|
Ethyl 3,3-diethoxypropanoate, 98%
| 10601-80-6 |
|
4'-(Benzyloxy)-2-bromopropiophenone, 97%
| 0-00-1 |
|
Tryptamine hydrochloride, 98%
| 343-94-2 |
|
|