**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 107263-95-6 |N-Fluoropyridinium Triflate | 95 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause systemic effects.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract. Aspiration may lead to
pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Do NOT get water inside containers. Use water spray, dry chemical,
carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation. Do
not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use only in a well-ventilated area. Minimize dust generation and
accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in
eyes, on skin, or on clothing. Keep container tightly closed. Do not
ingest or inhale. Do not allow contact with water. Discard
contaminated shoes. Keep from contact with moist air and steam.
Storage:
Keep container closed when not in use. Corrosives area. Keep
refrigerated. (Store below 4C/39F.) Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 107263-95-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: off-white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 183.00 - 184.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: 226 deg C ( 438.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 226 deg C
Solubility in water: may decompose
Specific Gravity/Density:
Molecular Formula: C6H5F4NO3S
Molecular Weight: 247.16
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, moisture, excess heat.
Incompatibilities with Other Materials:
Moisture.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide,
hydrogen fluoride gas, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 107263-95-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
N-Fluoropyridinium Triflate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 107263-95-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 107263-95-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 107263-95-6 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Calcion
| 3810-39-7 |
|
(-)-1-(9-Fluorenyl)ethyl chloroformate, 0.5 w/v % solution in acetone
| 67-64-1 |
|
6-Chloro-7-Nitroquinoxaline, 99+%
| 109541-21-1 |
|
2-Methoxy-1-Naphthonitrile
| 16000-39-8 |
|
(S)-(+)-gamma-Toluenesulfonylmethyl-gamma-butyrolactone, 99+%
| 58879-34-8 |
|
3-Chloro-2-butanone, tech., 95%
| 4089-07-0 |
|
2,6,10,14-Tetramethylpentadecane,96%
| 1921-70-6 |
|
2-(Tert-Butyl)Anthracene, 98%
| 18801-00-8 |
|
2,3-Dichloroquinoxaline, 97%
| 2213-63-0 |
|
4-Chloroanisole, 99%
| 623-12-1 |
|
2,4-Dinitrophenylhydrazine, moist solid, contains minimum of 30%
| 119-26-6 |
|
Dl-tert-butylglycine, 99%
| 33105-81-6 |
|
4-(2-Aminoethyl)morpholine, 99% (GC)
| 2038-03-1 |
|
R,S-3-Butene-1,2-diol, 99+%
| 497-06-3 |
|
2-Chloroacetamide, 98.0%
| 79-07-2 |
|
Octadecane, 99% (gc)
| 593-45-3 |
|
Rubidium Atomic Absorption Standard Solution, 1 mg/ml Rb in 2% HCl
| 7440-17-7 |
|
1-(4-Chlorophenyl)piperazine, 98%(titr.)
| 38212-33-8 |
|
Bromotrimethylsilane, 98%
| 2857-97-8 |
|
Dichloroacetic anhydride, 98%
| 4124-30-5 |
|
2,6-Dichloro-p-benzoquinone
| 697-82-5 |
|
Ethoxyacetic acid, 98%
| 627-03-2 |
|
Pamoic Acid, Disodium Salt Monohydrate (Pract), 95% (UV-Vis)
| 6640-22-8 |
|
4-Chlorobenzhydrylchloride, 99+%
| 134-83-8 |
|
4-Amino-1-benzylpiperidine dihydrochloride hydrate
| 1205-72-7 |
|
1-Butanesulfonyl Chloride, 99% (Titr.)
| 2386-60-9 |
|
N-Fluoropyridinium Triflate, 95%
| 107263-95-6 |
|
6-Aminochrysene, 97%
| 2642-98-0 |
|
Potassium fluoride, p.a.
| 7789-23-3 |
|
Myrcene, tech., 90+%,stabilized with 400 p pm tenox gt-1
| 123-35-3 |
|
Bis(Phenylthio)Methane, 97% (GC)
| 3561-67-9 |
|
2',3'-O-Isopropylideneadenosine, 98%
| 362-75-4 |
|
3-Acetylpyridine, 98%
| 350-03-8 |
|
Ethyl 3-Bromopropionate, 99% (GC)
| 539-74-2 |
|
1-Bromo-3,3-diphenylpropane, 99%
| 20017-68-9 |
|
1,2-Dibenzoylbenzene, 97%
| 1159-86-0 |
|
Cibacron brilliant red 3b-a
| 17681-50-4 |
|
2-Ketoglutaric acid,disodium salt, dihydrate, 99%
| 305-72-6 |
|
Methyl octanoate, 99% (gc)
| 111-11-5 |
|
Tungsten Hexacarbonyl, 99%
| 14040-11-0 |
|
n-(Trimethylsilyl)-imidazole, 98%
| 18156-74-6 |
|
Fluoresceinamine, isomer II
| 51649-83-3 |
|
Ethyl-O-Mesitylsulfonylaceto-Hydroxamate, 99%
| 38202-27-6 |
|
Fast Red Al Salt
| 16048-40-1 |
|
Methyl 4-methoxysalicylate, 98%
| 5446-02-6 |
|
2-Methyl-1,4-naphthoquinone
| 58-27-5 |
|
18 Beta-Glycyrrhetinic Acid, 98+% (Titr., on the Anhydrous Basis)
| 471-53-4 |
|
5-Bromouracil, 98%
| 51-20-7 |
|
2,2-Bis(4-Hydroxy-3-Methylphenylpropane)
| 79-97-0 |
|
Chlorotriethylsilane, 99%
| 994-30-9 |
|
|