**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 119-26-6 |2,4-Dinitrophenylhydrazine | 65-70 | 204-309-3 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 30-35 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN F
Risk Phrases: 1 11 22 40
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Explosive when dry. Highly flammable. Harmful if swallowed. Limited
evidence of a carcinogenic effect.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
No information regarding skin irritation and other potential effects
was found.
Ingestion:
The toxicological properties of this substance have not been fully
investigated. May be harmful if swallowed.
Inhalation:
The toxicological properties of this substance have not been fully
investigated. Inhalation of dust may cause respiratory tract
irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Flammable solid. May be ignited by friction, heat,
sparks, or flame. May decompose explosively when heated or involved
in a fire. Severe explosion and fire risk if not kept moist.
Extinguishing Media:
Cool containers with flooding quantities of water until well after
fire is out. Use water spray, dry chemical, carbon dioxide, or
appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions. Remove all sources of
ignition. If the material is dry, explosives experts may be necessary
to dispose of the spill. Wet area to prevent drying out. Provide
ventilation. Use only non-sparking tools and equipment.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Ground and bond containers when transferring material.
Use spark-proof tools and explosion proof equipment. Avoid contact
with eyes, skin, and clothing. Keep container tightly closed. Do not
use if the material has evaporated to dryness. Do not pressurize,
cut, weld, braze, solder, drill, grind, or expose empty containers
to heat, sparks or open flames. Use only with adequate ventilation.
Keep away from heat, sparks and flame. Avoid breathing dust. Do not
allow to dry on clothing. Drying on clothing or other combustible
materials may cause fire. Keep wet with water.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Material can ignite
if dry. Do not allow material to completely dry. Store in a cool,
dry, well-ventilated area away from incompatible substances. Keep
moist. Keep wet with water.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use adequate ventilation to keep airborne
concentrations low.
Exposure Limits
CAS# 119-26-6:
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: red
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 198-201 deg C
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >160 deg C
Solubility in water: slightly soluble
Specific Gravity/Density:
Molecular Formula: C6H6N4O4
Molecular Weight: 198.14
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Unstable if heated. Do not allow water to evaporate from product.
Dry product is explosive.
Conditions to Avoid:
Ignition sources, dust generation, temperatures above 160C,
evaporating to near dryness.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 119-26-6: MV3325000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 119-26-6: Draize test, rabbit, eye: 500 mg/24H Mild.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Oral-rat LD50: 654 mg/kg.
mg/kg.
Carcinogenicity:
2,4-Dinitrophenylhydrazine -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE SOLID, ORGANIC, N.O.S.*
Hazard Class: 4.1
UN Number: 1325
Packing Group: II
IMO
Shipping Name: FLAMMABLE SOLID, ORGANIC, N.O.S.
Hazard Class: 4.1
UN Number: 1325
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE SOLID, ORGANIC, N.O.S.
Hazard Class: 4.1
UN Number: 1325
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 1 Explosive when dry.
R 11 Highly flammable.
R 22 Harmful if swallowed.
R 40 Limited evidence of a carcinogenic effect.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 48A Keep wet with water.
WGK (Water Danger/Protection)
CAS# 119-26-6: 2
CAS# 7732-18-5: No information available.
Canada
CAS# 119-26-6 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 119-26-6 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 119-26-6 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/02/1997 Revision #5 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Calcion
| 3810-39-7 |
|
(-)-1-(9-Fluorenyl)ethyl chloroformate, 0.5 w/v % solution in acetone
| 67-64-1 |
|
6-Chloro-7-Nitroquinoxaline, 99+%
| 109541-21-1 |
|
2-Methoxy-1-Naphthonitrile
| 16000-39-8 |
|
(S)-(+)-gamma-Toluenesulfonylmethyl-gamma-butyrolactone, 99+%
| 58879-34-8 |
|
3-Chloro-2-butanone, tech., 95%
| 4089-07-0 |
|
2,6,10,14-Tetramethylpentadecane,96%
| 1921-70-6 |
|
2-(Tert-Butyl)Anthracene, 98%
| 18801-00-8 |
|
2,3-Dichloroquinoxaline, 97%
| 2213-63-0 |
|
4-Chloroanisole, 99%
| 623-12-1 |
|
2,4-Dinitrophenylhydrazine, moist solid, contains minimum of 30%
| 119-26-6 |
|
Dl-tert-butylglycine, 99%
| 33105-81-6 |
|
4-(2-Aminoethyl)morpholine, 99% (GC)
| 2038-03-1 |
|
R,S-3-Butene-1,2-diol, 99+%
| 497-06-3 |
|
2-Chloroacetamide, 98.0%
| 79-07-2 |
|
Octadecane, 99% (gc)
| 593-45-3 |
|
Rubidium Atomic Absorption Standard Solution, 1 mg/ml Rb in 2% HCl
| 7440-17-7 |
|
1-(4-Chlorophenyl)piperazine, 98%(titr.)
| 38212-33-8 |
|
Bromotrimethylsilane, 98%
| 2857-97-8 |
|
Dichloroacetic anhydride, 98%
| 4124-30-5 |
|
2,6-Dichloro-p-benzoquinone
| 697-82-5 |
|
Ethoxyacetic acid, 98%
| 627-03-2 |
|
Pamoic Acid, Disodium Salt Monohydrate (Pract), 95% (UV-Vis)
| 6640-22-8 |
|
4-Chlorobenzhydrylchloride, 99+%
| 134-83-8 |
|
4-Amino-1-benzylpiperidine dihydrochloride hydrate
| 1205-72-7 |
|
1-Butanesulfonyl Chloride, 99% (Titr.)
| 2386-60-9 |
|
N-Fluoropyridinium Triflate, 95%
| 107263-95-6 |
|
6-Aminochrysene, 97%
| 2642-98-0 |
|
Potassium fluoride, p.a.
| 7789-23-3 |
|
Myrcene, tech., 90+%,stabilized with 400 p pm tenox gt-1
| 123-35-3 |
|
Bis(Phenylthio)Methane, 97% (GC)
| 3561-67-9 |
|
2',3'-O-Isopropylideneadenosine, 98%
| 362-75-4 |
|
3-Acetylpyridine, 98%
| 350-03-8 |
|
Ethyl 3-Bromopropionate, 99% (GC)
| 539-74-2 |
|
1-Bromo-3,3-diphenylpropane, 99%
| 20017-68-9 |
|
1,2-Dibenzoylbenzene, 97%
| 1159-86-0 |
|
Cibacron brilliant red 3b-a
| 17681-50-4 |
|
2-Ketoglutaric acid,disodium salt, dihydrate, 99%
| 305-72-6 |
|
Methyl octanoate, 99% (gc)
| 111-11-5 |
|
Tungsten Hexacarbonyl, 99%
| 14040-11-0 |
|
n-(Trimethylsilyl)-imidazole, 98%
| 18156-74-6 |
|
Fluoresceinamine, isomer II
| 51649-83-3 |
|
Ethyl-O-Mesitylsulfonylaceto-Hydroxamate, 99%
| 38202-27-6 |
|
Fast Red Al Salt
| 16048-40-1 |
|
Methyl 4-methoxysalicylate, 98%
| 5446-02-6 |
|
2-Methyl-1,4-naphthoquinone
| 58-27-5 |
|
18 Beta-Glycyrrhetinic Acid, 98+% (Titr., on the Anhydrous Basis)
| 471-53-4 |
|
5-Bromouracil, 98%
| 51-20-7 |
|
2,2-Bis(4-Hydroxy-3-Methylphenylpropane)
| 79-97-0 |
|
Chlorotriethylsilane, 99%
| 994-30-9 |
|
|