**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 7440-17-7 |Rubidium | <1.0% | 231-126-6 |
|----------------|--------------------------------------|----------|-----------|
| 7647-01-0 |Hydrogen chloride | 2.0% | 231-595-7 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | Balance | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead
to pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use
extinguishing media appropriate to the surrounding fire. Substance is
noncombustible. Vapors may be heavier than air. They can spread
along the ground and collect in low or confined areas. Runoff from
fire control or dilution water may cause pollution.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use only in a well-ventilated area. Do not breathe dust, vapor,
mist, or gas. Do not get in eyes, on skin, or on clothing. Keep
container tightly closed. Do not ingest or inhale. Discard
contaminated shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7440-17-7:
CAS# 7647-01-0:
United Kingdom, WEL - TWA: 1 ppm TWA (aerosol mist and gas); 2 mg
TWA (aerosol mist and gas)
United Kingdom, WEL - STEL: 5 ppm STEL (aerosol mist and gas); 8
mg/m3 STEL (aerosol mist and gas)
United States OSHA: ; 5 ppm Ceiling; 7 mg/m3 Ceiling
Belgium - TWA: 5 ppm VLE; 8 mg/m3 VLE
Belgium - STEL: 10 ppm VLE; 15 mg/m3 VLE
France - VLE: 5 ppm VLE; 7.5 mg/m3 VLE
Germany: 8 mg/m3 TWA
Japan: 5 ppm Ceiling; 7.5 mg/m3 Ceiling
Malaysia: 5 ppm Ceiling; 7.5 mg/m3 Ceiling
Netherlands: 10 ppm STEL; 15 mg/m3 STEL
Netherlands: 5 ppm MAC; 8 mg/m3 MAC
Russia: 5 mg/m3 TWA
Spain: 5 ppm VLA-ED; 7.6 mg/m3 VLA-ED
Spain: 10 ppm VLA-EC; 15 mg/m3 VLA-EC
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: <1.0
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: miscible
Specific Gravity/Density: 1.0000g/cm3
Molecular Formula: Solution
Molecular Weight: 0
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7440-17-7: VL8500000
CAS# 7647-01-0: MW4025000 MW4031000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
Not available.
CAS# 7647-01-0: Inhalation, mouse: LC50 = 1108 ppm/1H; Inhalation,
mouse: LC50 = 20487 mg/m3/5M; Inhalation, mouse: LC50 = 3940
mg/m3/30M; Inhalation, mouse: LC50 = 8300 mg/m3/30M; Inhalation,
rat: LC50 = 3124 ppm/1H; Inhalation, rat: LC50 = 60938 mg/m3/5M;
Inhalation, rat: LC50 = 7004 mg/m3/30M; Inhalation, rat: LC50 =
45000 mg/m3/5M; Inhalation, rat: LC50 = 8300 mg/m3/30M; Oral,
rabbit: LD50 = 900 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Rubidium -
Not listed by ACGIH, IARC, or NTP.
Hydrogen chloride -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: HYDROCHLORIC ACID
Hazard Class: 8
UN Number: 1789
Packing Group: II
IMO
Shipping Name: HYDROCHLORIC ACID
Hazard Class: 8
UN Number: 1789
Packing Group: II
RID/ADR
Shipping Name: HYDROCHLORIC ACID
Hazard Class: 8
UN Number: 1789
Packing group: II
USA RQ: CAS# 7647-01-0: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 7440-17-7: No information available.
CAS# 7647-01-0: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 7440-17-7 is listed on Canada's NDSL List.
CAS# 7647-01-0 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 7440-17-7 is not listed on Canada's Ingredient Disclosure List.
CAS# 7647-01-0 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7440-17-7 is listed on the TSCA inventory.
CAS# 7647-01-0 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 36/37/38 Irritating to eyes, respiratory system and
skin.
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Calcion
| 3810-39-7 |
|
(-)-1-(9-Fluorenyl)ethyl chloroformate, 0.5 w/v % solution in acetone
| 67-64-1 |
|
6-Chloro-7-Nitroquinoxaline, 99+%
| 109541-21-1 |
|
2-Methoxy-1-Naphthonitrile
| 16000-39-8 |
|
(S)-(+)-gamma-Toluenesulfonylmethyl-gamma-butyrolactone, 99+%
| 58879-34-8 |
|
3-Chloro-2-butanone, tech., 95%
| 4089-07-0 |
|
2,6,10,14-Tetramethylpentadecane,96%
| 1921-70-6 |
|
2-(Tert-Butyl)Anthracene, 98%
| 18801-00-8 |
|
2,3-Dichloroquinoxaline, 97%
| 2213-63-0 |
|
4-Chloroanisole, 99%
| 623-12-1 |
|
2,4-Dinitrophenylhydrazine, moist solid, contains minimum of 30%
| 119-26-6 |
|
Dl-tert-butylglycine, 99%
| 33105-81-6 |
|
4-(2-Aminoethyl)morpholine, 99% (GC)
| 2038-03-1 |
|
R,S-3-Butene-1,2-diol, 99+%
| 497-06-3 |
|
2-Chloroacetamide, 98.0%
| 79-07-2 |
|
Octadecane, 99% (gc)
| 593-45-3 |
|
Rubidium Atomic Absorption Standard Solution, 1 mg/ml Rb in 2% HCl
| 7440-17-7 |
|
1-(4-Chlorophenyl)piperazine, 98%(titr.)
| 38212-33-8 |
|
Bromotrimethylsilane, 98%
| 2857-97-8 |
|
Dichloroacetic anhydride, 98%
| 4124-30-5 |
|
2,6-Dichloro-p-benzoquinone
| 697-82-5 |
|
Ethoxyacetic acid, 98%
| 627-03-2 |
|
Pamoic Acid, Disodium Salt Monohydrate (Pract), 95% (UV-Vis)
| 6640-22-8 |
|
4-Chlorobenzhydrylchloride, 99+%
| 134-83-8 |
|
4-Amino-1-benzylpiperidine dihydrochloride hydrate
| 1205-72-7 |
|
1-Butanesulfonyl Chloride, 99% (Titr.)
| 2386-60-9 |
|
N-Fluoropyridinium Triflate, 95%
| 107263-95-6 |
|
6-Aminochrysene, 97%
| 2642-98-0 |
|
Potassium fluoride, p.a.
| 7789-23-3 |
|
Myrcene, tech., 90+%,stabilized with 400 p pm tenox gt-1
| 123-35-3 |
|
Bis(Phenylthio)Methane, 97% (GC)
| 3561-67-9 |
|
2',3'-O-Isopropylideneadenosine, 98%
| 362-75-4 |
|
3-Acetylpyridine, 98%
| 350-03-8 |
|
Ethyl 3-Bromopropionate, 99% (GC)
| 539-74-2 |
|
1-Bromo-3,3-diphenylpropane, 99%
| 20017-68-9 |
|
1,2-Dibenzoylbenzene, 97%
| 1159-86-0 |
|
Cibacron brilliant red 3b-a
| 17681-50-4 |
|
2-Ketoglutaric acid,disodium salt, dihydrate, 99%
| 305-72-6 |
|
Methyl octanoate, 99% (gc)
| 111-11-5 |
|
Tungsten Hexacarbonyl, 99%
| 14040-11-0 |
|
n-(Trimethylsilyl)-imidazole, 98%
| 18156-74-6 |
|
Fluoresceinamine, isomer II
| 51649-83-3 |
|
Ethyl-O-Mesitylsulfonylaceto-Hydroxamate, 99%
| 38202-27-6 |
|
Fast Red Al Salt
| 16048-40-1 |
|
Methyl 4-methoxysalicylate, 98%
| 5446-02-6 |
|
2-Methyl-1,4-naphthoquinone
| 58-27-5 |
|
18 Beta-Glycyrrhetinic Acid, 98+% (Titr., on the Anhydrous Basis)
| 471-53-4 |
|
5-Bromouracil, 98%
| 51-20-7 |
|
2,2-Bis(4-Hydroxy-3-Methylphenylpropane)
| 79-97-0 |
|
Chlorotriethylsilane, 99%
| 994-30-9 |
|
|