**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7789-23-3 |Potassium fluoride | | 232-151-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/24/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if
swallowed.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns. Exposure to particulates or solution may cause
conjunctivitis, ulceration, and corneal abnormalities.
Skin:
May cause severe irritation and possible burns. Toxic in contact
with skin.
Ingestion:
Poison by ingestion. May cause severe digestive tract irritation
with abdominal pain, nausea, vomiting and diarrhea.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. Inhalation may be fatal as a result of spasm,
inflammation, edema of the larynx and bronchi, chemical pneumonitis
and pulmonary edema. Toxic if inhaled.
Chronic:
Chronic inhalation and ingestion may cause chronic fluoride
poisoning (fluorosis) characterized by weight loss, weakness,
anemia, brittle bones, and stiff joints. Chronic inhalation may
cause nasal septum ulceration and perforation.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Substance is noncombustible.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower.
Exposure Limits
CAS# 7789-23-3:
United Kingdom, WEL - TWA: (listed as fluorides, inorganic): 2.5
mg/m3 TWA (as F)
United Kingdom, WEL - STEL: (listed as fluorides, inorganic): 6.2
mg/m3 STEL (as F)
United States OSHA: 2.5 mg/m3 TWA (as F) (listed under
Fluorides).2.5 mg/m3 TWA (as F) (listed under Fluorides).
Belgium - TWA: (listed as fluorides, inorganic): 2.5 mg/m3 VLE (a
France - VME: (listed as fluorides): 2.5 mg/m3 VME (as F)
Germany: (listed as fluorides): 2.5 mg/m3 VME (as F)
Malaysia: (listed as fluorides): 2.5 mg/m3 TWA (as F)
Netherlands: (listed as fluorides): 3.5 mg/m3 STEL (as F)
Russia: 1 mg/m3 TWA
Russia: 0.2 mg/m3 STEL
Spain: (listed as fluorides, inorganic): 2.5 mg/m3 VLA-ED (except
uranium hexafluoride, as F)
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear a chemical apron.
Respirators:
A NIOSH/MSHA approved air purifying dust or mist
respirator or European Standard EN 149.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: white - fine
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 1505 deg C @ 760.00mm Hg
Freezing/Melting Point: 858 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: IN WATER: 92.3 G/100ML (18C)
Specific Gravity/Density: 2.4800g/cm3
Molecular Formula: KF
Molecular Weight: 58.09
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong acids.
Hazardous Decomposition Products:
Hydrogen fluoride gas.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7789-23-3: TT0700000
LD50/LC50:
CAS# 7789-23-3: Oral, rat: LD50 = 245 mg/kg.
Carcinogenicity:
Potassium fluoride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: POTASSIUM FLUORIDE
Hazard Class: 6.1
UN Number: 1812
Packing Group: III
IMO
Shipping Name: POTASSIUM FLUORIDE, LIQUID
Hazard Class: 6.1
UN Number: 1812
Packing Group: III
RID/ADR
Shipping Name: POTASSIUM FLUORIDE
Hazard Class: 6.1
UN Number: 1812
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7789-23-3: 1
Canada
CAS# 7789-23-3 is listed on Canada's DSL List.
CAS# 7789-23-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7789-23-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/11/1997 Revision #4 Date: 10/08/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Calcion
| 3810-39-7 |
|
(-)-1-(9-Fluorenyl)ethyl chloroformate, 0.5 w/v % solution in acetone
| 67-64-1 |
|
6-Chloro-7-Nitroquinoxaline, 99+%
| 109541-21-1 |
|
2-Methoxy-1-Naphthonitrile
| 16000-39-8 |
|
(S)-(+)-gamma-Toluenesulfonylmethyl-gamma-butyrolactone, 99+%
| 58879-34-8 |
|
3-Chloro-2-butanone, tech., 95%
| 4089-07-0 |
|
2,6,10,14-Tetramethylpentadecane,96%
| 1921-70-6 |
|
2-(Tert-Butyl)Anthracene, 98%
| 18801-00-8 |
|
2,3-Dichloroquinoxaline, 97%
| 2213-63-0 |
|
4-Chloroanisole, 99%
| 623-12-1 |
|
2,4-Dinitrophenylhydrazine, moist solid, contains minimum of 30%
| 119-26-6 |
|
Dl-tert-butylglycine, 99%
| 33105-81-6 |
|
4-(2-Aminoethyl)morpholine, 99% (GC)
| 2038-03-1 |
|
R,S-3-Butene-1,2-diol, 99+%
| 497-06-3 |
|
2-Chloroacetamide, 98.0%
| 79-07-2 |
|
Octadecane, 99% (gc)
| 593-45-3 |
|
Rubidium Atomic Absorption Standard Solution, 1 mg/ml Rb in 2% HCl
| 7440-17-7 |
|
1-(4-Chlorophenyl)piperazine, 98%(titr.)
| 38212-33-8 |
|
Bromotrimethylsilane, 98%
| 2857-97-8 |
|
Dichloroacetic anhydride, 98%
| 4124-30-5 |
|
2,6-Dichloro-p-benzoquinone
| 697-82-5 |
|
Ethoxyacetic acid, 98%
| 627-03-2 |
|
Pamoic Acid, Disodium Salt Monohydrate (Pract), 95% (UV-Vis)
| 6640-22-8 |
|
4-Chlorobenzhydrylchloride, 99+%
| 134-83-8 |
|
4-Amino-1-benzylpiperidine dihydrochloride hydrate
| 1205-72-7 |
|
1-Butanesulfonyl Chloride, 99% (Titr.)
| 2386-60-9 |
|
N-Fluoropyridinium Triflate, 95%
| 107263-95-6 |
|
6-Aminochrysene, 97%
| 2642-98-0 |
|
Potassium fluoride, p.a.
| 7789-23-3 |
|
Myrcene, tech., 90+%,stabilized with 400 p pm tenox gt-1
| 123-35-3 |
|
Bis(Phenylthio)Methane, 97% (GC)
| 3561-67-9 |
|
2',3'-O-Isopropylideneadenosine, 98%
| 362-75-4 |
|
3-Acetylpyridine, 98%
| 350-03-8 |
|
Ethyl 3-Bromopropionate, 99% (GC)
| 539-74-2 |
|
1-Bromo-3,3-diphenylpropane, 99%
| 20017-68-9 |
|
1,2-Dibenzoylbenzene, 97%
| 1159-86-0 |
|
Cibacron brilliant red 3b-a
| 17681-50-4 |
|
2-Ketoglutaric acid,disodium salt, dihydrate, 99%
| 305-72-6 |
|
Methyl octanoate, 99% (gc)
| 111-11-5 |
|
Tungsten Hexacarbonyl, 99%
| 14040-11-0 |
|
n-(Trimethylsilyl)-imidazole, 98%
| 18156-74-6 |
|
Fluoresceinamine, isomer II
| 51649-83-3 |
|
Ethyl-O-Mesitylsulfonylaceto-Hydroxamate, 99%
| 38202-27-6 |
|
Fast Red Al Salt
| 16048-40-1 |
|
Methyl 4-methoxysalicylate, 98%
| 5446-02-6 |
|
2-Methyl-1,4-naphthoquinone
| 58-27-5 |
|
18 Beta-Glycyrrhetinic Acid, 98+% (Titr., on the Anhydrous Basis)
| 471-53-4 |
|
5-Bromouracil, 98%
| 51-20-7 |
|
2,2-Bis(4-Hydroxy-3-Methylphenylpropane)
| 79-97-0 |
|
Chlorotriethylsilane, 99%
| 994-30-9 |
|
|