**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 4124-30-5 |Acetic acid, dichloro-, anhydride | 98% | 223-924-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.Moisture sensitive.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns.
Skin:
May cause severe irritation and possible burns.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea,
vomiting and possible burns. Expected to be a low ingestion hazard.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Do NOT induce vomiting and seek IMMEDIATE MEDICAL ADVICE.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower.
Exposure Limits
CAS# 4124-30-5:
Personal Protective Equipment
Eyes:
Wear chemical goggles and a face shield if splashing
is possible.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Pungent odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 214 - 216 deg C @ 760.00mm Hg
Freezing/Melting Point: 29 deg C
Autoignition Temperature: Not available.
Flash Point: > 112 deg C (> 233.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: decomposes in water
Specific Gravity/Density: 1.5740g/cm3
Molecular Formula: C4H2Cl4O3
Molecular Weight: 239.87
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 4124-30-5: AG6300000
LD50/LC50:
CAS# 4124-30-5: Draize test, rabbit, skin: 2 mg/24H Severe; Oral,
rat: LD50 = 2820 mg/kg; Skin, rabbit: LD50 = 470 uL/kg.
Carcinogenicity:
Acetic acid, dichloro-, anhydride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3265
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 4124-30-5: No information available.
Canada
CAS# 4124-30-5 is listed on Canada's NDSL List.
CAS# 4124-30-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4124-30-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Calcion
| 3810-39-7 |
|
(-)-1-(9-Fluorenyl)ethyl chloroformate, 0.5 w/v % solution in acetone
| 67-64-1 |
|
6-Chloro-7-Nitroquinoxaline, 99+%
| 109541-21-1 |
|
2-Methoxy-1-Naphthonitrile
| 16000-39-8 |
|
(S)-(+)-gamma-Toluenesulfonylmethyl-gamma-butyrolactone, 99+%
| 58879-34-8 |
|
3-Chloro-2-butanone, tech., 95%
| 4089-07-0 |
|
2,6,10,14-Tetramethylpentadecane,96%
| 1921-70-6 |
|
2-(Tert-Butyl)Anthracene, 98%
| 18801-00-8 |
|
2,3-Dichloroquinoxaline, 97%
| 2213-63-0 |
|
4-Chloroanisole, 99%
| 623-12-1 |
|
2,4-Dinitrophenylhydrazine, moist solid, contains minimum of 30%
| 119-26-6 |
|
Dl-tert-butylglycine, 99%
| 33105-81-6 |
|
4-(2-Aminoethyl)morpholine, 99% (GC)
| 2038-03-1 |
|
R,S-3-Butene-1,2-diol, 99+%
| 497-06-3 |
|
2-Chloroacetamide, 98.0%
| 79-07-2 |
|
Octadecane, 99% (gc)
| 593-45-3 |
|
Rubidium Atomic Absorption Standard Solution, 1 mg/ml Rb in 2% HCl
| 7440-17-7 |
|
1-(4-Chlorophenyl)piperazine, 98%(titr.)
| 38212-33-8 |
|
Bromotrimethylsilane, 98%
| 2857-97-8 |
|
Dichloroacetic anhydride, 98%
| 4124-30-5 |
|
2,6-Dichloro-p-benzoquinone
| 697-82-5 |
|
Ethoxyacetic acid, 98%
| 627-03-2 |
|
Pamoic Acid, Disodium Salt Monohydrate (Pract), 95% (UV-Vis)
| 6640-22-8 |
|
4-Chlorobenzhydrylchloride, 99+%
| 134-83-8 |
|
4-Amino-1-benzylpiperidine dihydrochloride hydrate
| 1205-72-7 |
|
1-Butanesulfonyl Chloride, 99% (Titr.)
| 2386-60-9 |
|
N-Fluoropyridinium Triflate, 95%
| 107263-95-6 |
|
6-Aminochrysene, 97%
| 2642-98-0 |
|
Potassium fluoride, p.a.
| 7789-23-3 |
|
Myrcene, tech., 90+%,stabilized with 400 p pm tenox gt-1
| 123-35-3 |
|
Bis(Phenylthio)Methane, 97% (GC)
| 3561-67-9 |
|
2',3'-O-Isopropylideneadenosine, 98%
| 362-75-4 |
|
3-Acetylpyridine, 98%
| 350-03-8 |
|
Ethyl 3-Bromopropionate, 99% (GC)
| 539-74-2 |
|
1-Bromo-3,3-diphenylpropane, 99%
| 20017-68-9 |
|
1,2-Dibenzoylbenzene, 97%
| 1159-86-0 |
|
Cibacron brilliant red 3b-a
| 17681-50-4 |
|
2-Ketoglutaric acid,disodium salt, dihydrate, 99%
| 305-72-6 |
|
Methyl octanoate, 99% (gc)
| 111-11-5 |
|
Tungsten Hexacarbonyl, 99%
| 14040-11-0 |
|
n-(Trimethylsilyl)-imidazole, 98%
| 18156-74-6 |
|
Fluoresceinamine, isomer II
| 51649-83-3 |
|
Ethyl-O-Mesitylsulfonylaceto-Hydroxamate, 99%
| 38202-27-6 |
|
Fast Red Al Salt
| 16048-40-1 |
|
Methyl 4-methoxysalicylate, 98%
| 5446-02-6 |
|
2-Methyl-1,4-naphthoquinone
| 58-27-5 |
|
18 Beta-Glycyrrhetinic Acid, 98+% (Titr., on the Anhydrous Basis)
| 471-53-4 |
|
5-Bromouracil, 98%
| 51-20-7 |
|
2,2-Bis(4-Hydroxy-3-Methylphenylpropane)
| 79-97-0 |
|
Chlorotriethylsilane, 99%
| 994-30-9 |
|
|