**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 123-62-6 |Propionic anhydride | 100.0 | 204-638-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.Combustible liquid.
Potential Health Effects
Eye:
Causes eye burns. Vapors may cause eye irritation.
Skin:
Causes skin burns.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea,
vomiting and possible burns. Aspiration of material into the lungs
may cause chemical pneumonitis, which may be fatal.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Use water spray to keep fire-exposed containers
cool. Combustible liquid. Contact with metals may evolve flammable
hydrogen gas. Containers may explode when heated or if contaminated
with water. Substance will react with water (some violently)
releasing flammable, toxic, or corrosive gases and runoff.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be
ineffective. Do NOT get water inside containers. For large fires,
use water spray, fog or alcohol-resistant foam. Do NOT use straight
streams of water. For small fires, use carbon dioxide, dry chemical,
dry sand, or alcohol-resistant foam. Cool containers with flooding
quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Use water spray to disperse the
gas/vapor. Remove all sources of ignition. A vapor suppressing foam
may be used to reduce vapors. Do not get water on spilled substances
or inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Do not get in eyes,
on skin, or on clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Do not ingest or
inhale. Do not allow contact with water. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Do not store near combustible materials. Store in a
tightly closed container. Store in a cool, dry, well-ventilated area
away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local explosion-proof ventilation to keep
airborne levels to acceptable levels.
Exposure Limits
CAS# 123-62-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: none reported
pH: Not available.
Vapor Pressure: 1 mm Hg @20C
Viscosity: 1.144cP@20c
Boiling Point: 167 deg C
Freezing/Melting Point: -45 deg C
Autoignition Temperature: 285 deg C ( 545.00 deg F)
Flash Point: 74 deg C ( 165.20 deg F)
Explosion Limits, lower: 1.3
Explosion Limits, upper: 11.9
Decomposition Temperature:
Solubility in water: Reacts with water.
Specific Gravity/Density: 1.01
Molecular Formula: (CH3CH2CO)2O
Molecular Weight: 130.0682
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, oxidizers.
Incompatibilities with Other Materials:
Oxidizing agents, alcohols, alkalies, water.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 123-62-6: UF9100000
LD50/LC50:
CAS# 123-62-6: Dermal, guinea pig: LD50 = 1 mL/kg; Oral, rat: LD50 =
2360 mg/kg; Skin, rabbit: LD50 = 10 mL/kg.
Carcinogenicity:
Propionic anhydride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: PROPIONIC ANHYDRIDE
Hazard Class: 8
UN Number: 2496
Packing Group: III
IMO
Shipping Name: PROPIONIC ANHYDRIDE
Hazard Class: 8
UN Number: 2496
Packing Group: III
RID/ADR
Shipping Name: PROPIONIC ANHYDRIDE
Hazard Class: 8
UN Number: 2496
Packing group: III
USA RQ: CAS# 123-62-6: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 123-62-6: 1
Canada
CAS# 123-62-6 is listed on Canada's DSL List.
CAS# 123-62-6 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 123-62-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/14/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,6-Dihydroxypyridine Hydrochloride, 97%
| 10357-84-3 |
|
Diethyl dimethylmalonate, 97%
| 1619-62-1 |
|
D-(-)-Pantolactone, 99%
| 599-04-2 |
|
1-(4-Chlorophenyl)-1-Cyclohexane- Carboxylic Acid 95%
| 58880-37-8 |
|
1,1,3,3-Tetramethyldisiloxane, 97+%
| 3277-26-7 |
|
3,6-Dithia-1,8-Octanediol, 98%
| 5244-34-8 |
|
4-Biphenylcarboxaldehyde, 99%
| 3215-64-3 |
|
3-Indolebutyric Acid, 98%
| 133-32-4 |
|
2,4-Dihydro-5-Methyl-2-(4-Nitrophenyl)-3H-Pyrazol-3-One
| 6402-09-1 |
|
1-Cyclohexenylacetonitrile, 92%
| 6975-71-9 |
|
5-Chloro-2-Iodobenzotrifluoride, 99%
| 23399-77-1 |
|
Diisopropyl Cyanomethylphosphonate, 97%
| 58264-04-3 |
|
Sulfuryl Chloride, 99% (Titr.)
| 7791-25-5 |
|
4-(Dimethylamino)-Benzonitrile, 95%
| 1197-19-9 |
|
Antimony pentafluoride, 99.5+%
| 7783-70-2 |
|
1-Octanethiol, 97+%
| 111-88-6 |
|
2,4-Lutidine, 98+%
| 108-47-4 |
|
2-Methylimidazole, 99%
| 693-98-1 |
|
Butyl Isocyanate, 99% (GC)
| 111-36-4 |
|
Isosafrol, 95%,mixture of cis and trans
| 120-58-1 |
|
3,3',5- Triiodo-L-Thyronine, Sodium Salt, 95%
| 55-06-1 |
|
2,6-Dimethylbenzoquinone, 97%
| 527-61-7 |
|
5-Carbethoxy-2-Thiouracil, 99%
| 38026-46-9 |
|
Piperonylic acid, 99%
| 94-53-1 |
|
3-Thiopheneacetic acid, 98%
| 6964-21-2 |
|
Bis-(Triphenylphosphine)Palladium(II) Acetate, 99%
| 14588-08-0 |
|
2-Fluorobenzyl chloride, 98%
| 345-35-7 |
|
l-Histidine methyl ester dihydrochloride, 97%
| 7389-87-9 |
|
Phenolphthalein Diphosphate, Tetrasodium Salt Hydrate, 99%
| 68807-90-9 |
|
4-(Phenylazo)diphenylamine, 97%
| 101-75-7 |
|
2-(N-Ethyl-meta-toluidino)ethanol, 97%
| 91-88-3 |
|
Didecyl phthalate, 95% (GC)
| 84-77-5 |
|
Dl-phenylalanine, 99%
| 150-30-1 |
|
Citric Acid Anhydrous
| 77-92-9 |
|
Lithium Benzoate, 99%
| 553-54-8 |
|
P-Nitrophenyl Isocyanate, 97% (Titr.)
| 100-28-7 |
|
1-Chloro-2-methyl-2-phenylpropane 98%
| 515-40-2 |
|
Copper phthalocyanine, dye content ca 95%
| 147-14-8 |
|
Kartamine
| |
|
2,3,3-Trimethylindolenine, 98%
| 1640-39-7 |
|
Chloromethylated polystyrene: 1% divinylbenzene copolymer beads
| 70024-51-0 |
|
6-Methylquinoline, 95+% (gc)
| 91-62-3 |
|
3-Methylglutaric anhydride, 97%(titr.)
| 4166-53-4 |
|
5-Chloro-3-Ethyl-2-Methylbenzothiazolium P-Toluenesulfonate (Pract),
| 63149-16-6 |
|
Galvinoxyl, Free Radical, 98%
| 2370-18-5 |
|
Alpha-Methylcinnamaldehyde 98%
| 101-39-3 |
|
Propionic anhydride, p.a.
| 123-62-6 |
|
1,3-Dichlorobutane, 99%
| 1190-22-3 |
|
n-(2-Aminoethyl)-1,3-propanediamine, 97%
| 13531-52-7 |
|
Urocanic acid, 99%
| 104-98-3 |
|
|