**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7783-70-2 |Antimony pentafluoride | 99.5+% | 232-021-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C N
Risk Phrases: 14 20/22 34 51/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Reacts violently with water. Harmful by inhalation and if swallowed.
Causes burns. Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.Water-reactive.Moisture
sensitive.Corrosive.
Potential Health Effects
Eye:
Contact with liquid is corrosive to the eyes and causes severe
burns.
Skin:
Contact with liquid is corrosive and causes severe burns and
ulceration.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns.
Inhalation:
Harmful if inhaled. Causes chemical burns to the respiratory tract.
Inhalation may be fatal as a result of spasm, inflammation, edema of
the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Chronic:
Chronic inhalation and ingestion may cause chronic fluoride
poisoning (fluorosis) characterized by weight loss, weakness,
anemia, brittle bones, and stiff joints.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. If water-reactive products are embedded in the skin, no
water should be applied. The embedded products should be covered
with a light oil.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Water
Reactive. Material will react with water and may release a flammable
and/or toxic gas. May ignite or explode on contact with steam or
moist air. May re-ignite after fire is extinguished.
Extinguishing Media:
Use dry sand or earth to smother fire. Substance is noncombustible;
use agent most appropriate to extinguish surrounding fire. DO NOT
USE WATER! Do NOT get water inside containers. Contact professional
fire-fighters immediately. Cool containers with flooding quantities
of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation. Do not expose spill to water.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Do not allow water to get into the
container because of violent reaction. Avoid contact with eyes, skin,
and clothing. Avoid ingestion and inhalation. Do not allow contact
with water. Use only in a chemical fume hood. Keep from contact with
moist air and steam.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Keep under a nitrogen blanket. Keep away from water.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use only under a chemical fume hood.
Exposure Limits
CAS# 7783-70-2:
United Kingdom, WEL - TWA: (listed as antimony compounds): 0.5 mg
TWA (except stibine, as Sb)
United Kingdom, WEL - STEL: (listed as antimony compounds): 1.5 m
STEL (except stibine, as Sb)
United States OSHA: 0.5 mg/m3 TWA (listed under Antimony).2.5 mg
TWA (as F) (listed under Fluorides).2.5 mg/m3 TWA (as F) (liste
under Fluorides).0.5 mg/m3 TWA (as Sb) (listed under Antimony
compounds).
Belgium - TWA: (listed as antimony compounds): 0.5 mg/m3 VLE (as
France - VME: (listed as antimony compounds): 0.5 mg/m3 VME (as S
Germany: (listed as antimony compounds): 0.5 mg/m3 VME (as Sb)
Japan: (listed as antimony compounds): 0.1 mg/m3 OEL (except stib
as Sb)
Malaysia: (listed as antimony compounds): 0.5 mg/m3 TWA (as Sb)
Netherlands: (listed as fluorides): 3.5 mg/m3 STEL (as F)
Netherlands: (listed as antimony compounds): 0.5 mg/m3 MAC (as Sb
Russia: 0.3 mg/m3 TWA
Russia: (listed as antimony): 0.2 mg/m3 STEL
Spain: (listed as antimony compounds): 0.5 mg/m3 VLA-ED (except
antimony hydride, as Sb)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: 753 mbar @ 142 deg
Viscosity: Not available.
Boiling Point: 149.4 deg C @ 760.00mm Hg
Freezing/Melting Point: 7 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: reacts with water
Specific Gravity/Density: 2.9930g/cm3
Molecular Formula: F5Sb
Molecular Weight: 216.74
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Reacts vigorously
with water to form toxic hydrogen fluoride (hydrofluoric acid). If
confined and wet, explosions can result.
Conditions to Avoid:
Incompatible materials, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Water, Slowly corrodes glass, copper and lead. When moisture is
present, causes severe corrosion of metals (except steel) and glass..
Hazardous Decomposition Products:
Hydrogen fluoride gas, antimony/antimony oxides.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7783-70-2: CC5800000
LD50/LC50:
CAS# 7783-70-2: Inhalation, mouse: LC50 = 270 mg/m3.
Carcinogenicity:
Antimony pentafluoride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ANTIMONY PENTAFLUORIDE
Hazard Class: 8 (6.1)
UN Number: 1732
Packing Group: II
IMO
Shipping Name: ANTIMONY PENTAFLUORIDE
Hazard Class: 8 (6.1)
UN Number: 1732
Packing Group: II
RID/ADR
Shipping Name: ANTIMONY PENTAFLUORIDE
Hazard Class: 8
UN Number: 1732
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C N
Risk Phrases:
R 14 Reacts violently with water.
R 20/22 Harmful by inhalation and if swallowed.
R 34 Causes burns.
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 7783-70-2: No information available.
Canada
CAS# 7783-70-2 is listed on Canada's DSL List.
CAS# 7783-70-2 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7783-70-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 7/07/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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| 77-92-9 |
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| 147-14-8 |
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