**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 693-98-1 |2-Methylimidazole | 100.0 | 211-765-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 22 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema.
Chronic:
None
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Dusts may
be an explosion hazard if mixed with air at critical proportions and
in the presence of an ignition source.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Do not
get in eyes, on skin, or on clothing. Keep container tightly closed.
Do not ingest or inhale. Use only in a chemical fume hood.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 693-98-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: white to light yellow
Odor: Not available.
pH: 10.5 (10% aq. solution)
Vapor Pressure: < 1 mbar @20C
Viscosity: Not available.
Boiling Point: 270 deg C
Freezing/Melting Point: 142-145 deg C
Autoignition Temperature: Not applicable.
Flash Point: 155 deg C ( 311.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: 780G/L WATER(20C)
Specific Gravity/Density: Not available.
Molecular Formula: C4H6N2
Molecular Weight: 82.10
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Acids, acid chlorides, acid anhydrides, strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 693-98-1: NI7175000
LD50/LC50:
CAS# 693-98-1: Oral, mouse: LD50 = 1400 mg/kg.
Carcinogenicity:
2-Methylimidazole -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish toxicity: LC50 Leuciscus idus: >100 <220 mg/l/96h
Daphnia
toxicity: EC/LC50 (48 h): 268 mg/l
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, BASIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3263
Packing Group: II
IMO
Shipping Name: CORROSIVE SOLID, BASIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3263
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE SOLID, BASIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3263
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 22 Harmful if swallowed.
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 693-98-1: 1
Canada
CAS# 693-98-1 is listed on Canada's DSL List.
CAS# 693-98-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 693-98-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #3 Date: 11/10/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,6-Dihydroxypyridine Hydrochloride, 97%
| 10357-84-3 |
|
Diethyl dimethylmalonate, 97%
| 1619-62-1 |
|
D-(-)-Pantolactone, 99%
| 599-04-2 |
|
1-(4-Chlorophenyl)-1-Cyclohexane- Carboxylic Acid 95%
| 58880-37-8 |
|
1,1,3,3-Tetramethyldisiloxane, 97+%
| 3277-26-7 |
|
3,6-Dithia-1,8-Octanediol, 98%
| 5244-34-8 |
|
4-Biphenylcarboxaldehyde, 99%
| 3215-64-3 |
|
3-Indolebutyric Acid, 98%
| 133-32-4 |
|
2,4-Dihydro-5-Methyl-2-(4-Nitrophenyl)-3H-Pyrazol-3-One
| 6402-09-1 |
|
1-Cyclohexenylacetonitrile, 92%
| 6975-71-9 |
|
5-Chloro-2-Iodobenzotrifluoride, 99%
| 23399-77-1 |
|
Diisopropyl Cyanomethylphosphonate, 97%
| 58264-04-3 |
|
Sulfuryl Chloride, 99% (Titr.)
| 7791-25-5 |
|
4-(Dimethylamino)-Benzonitrile, 95%
| 1197-19-9 |
|
Antimony pentafluoride, 99.5+%
| 7783-70-2 |
|
1-Octanethiol, 97+%
| 111-88-6 |
|
2,4-Lutidine, 98+%
| 108-47-4 |
|
2-Methylimidazole, 99%
| 693-98-1 |
|
Butyl Isocyanate, 99% (GC)
| 111-36-4 |
|
Isosafrol, 95%,mixture of cis and trans
| 120-58-1 |
|
3,3',5- Triiodo-L-Thyronine, Sodium Salt, 95%
| 55-06-1 |
|
2,6-Dimethylbenzoquinone, 97%
| 527-61-7 |
|
5-Carbethoxy-2-Thiouracil, 99%
| 38026-46-9 |
|
Piperonylic acid, 99%
| 94-53-1 |
|
3-Thiopheneacetic acid, 98%
| 6964-21-2 |
|
Bis-(Triphenylphosphine)Palladium(II) Acetate, 99%
| 14588-08-0 |
|
2-Fluorobenzyl chloride, 98%
| 345-35-7 |
|
l-Histidine methyl ester dihydrochloride, 97%
| 7389-87-9 |
|
Phenolphthalein Diphosphate, Tetrasodium Salt Hydrate, 99%
| 68807-90-9 |
|
4-(Phenylazo)diphenylamine, 97%
| 101-75-7 |
|
2-(N-Ethyl-meta-toluidino)ethanol, 97%
| 91-88-3 |
|
Didecyl phthalate, 95% (GC)
| 84-77-5 |
|
Dl-phenylalanine, 99%
| 150-30-1 |
|
Citric Acid Anhydrous
| 77-92-9 |
|
Lithium Benzoate, 99%
| 553-54-8 |
|
P-Nitrophenyl Isocyanate, 97% (Titr.)
| 100-28-7 |
|
1-Chloro-2-methyl-2-phenylpropane 98%
| 515-40-2 |
|
Copper phthalocyanine, dye content ca 95%
| 147-14-8 |
|
Kartamine
| |
|
2,3,3-Trimethylindolenine, 98%
| 1640-39-7 |
|
Chloromethylated polystyrene: 1% divinylbenzene copolymer beads
| 70024-51-0 |
|
6-Methylquinoline, 95+% (gc)
| 91-62-3 |
|
3-Methylglutaric anhydride, 97%(titr.)
| 4166-53-4 |
|
5-Chloro-3-Ethyl-2-Methylbenzothiazolium P-Toluenesulfonate (Pract),
| 63149-16-6 |
|
Galvinoxyl, Free Radical, 98%
| 2370-18-5 |
|
Alpha-Methylcinnamaldehyde 98%
| 101-39-3 |
|
Propionic anhydride, p.a.
| 123-62-6 |
|
1,3-Dichlorobutane, 99%
| 1190-22-3 |
|
n-(2-Aminoethyl)-1,3-propanediamine, 97%
| 13531-52-7 |
|
Urocanic acid, 99%
| 104-98-3 |
|
|