**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7791-25-5 |Sulfuryl Chloride | 99% | 232-245-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 14 34 37
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Reacts violently with water. Causes burns. Irritating to respiratory
system.Corrosive.Water-reactive.
Potential Health Effects
Eye:
Causes eye burns. When substance becomes wet or comes in contact
with moisture of the mucous membranes, it will cause irritation. May
cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. Contact with skin causes irritation and possible
burns, especially if the skin is wet or moist. May cause skin rash
(in milder cases), and cold and clammy skin with cyanosis or pale
color.
Ingestion:
May cause severe and permanent damage to the digestive tract. May
cause perforation of the digestive tract. The toxicological
properties of this substance have not been fully investigated. May
cause systemic effects.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract. The toxicological
properties of this substance have not been fully investigated.
Aspiration may lead to pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid. Do NOT allow victim to rub eyes or keep eyes
closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse. Destroy contaminated shoes. If
water-reactive products are embedded in the skin, no water should be
applied. The embedded products should be covered with a light oil.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Water
Reactive. Material will react with water and may release a flammable
and/or toxic gas. Use water spray to keep fire-exposed containers
cool. Will react with water to form toxic and corrosive fumes.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. May ignite or explode on contact
with steam or moist air. Contact with metals may evolve flammable
hydrogen gas. Containers may explode when heated.
Extinguishing Media:
Use dry sand or earth to smother fire. DO NOT USE WATER! Do NOT get
water inside containers. Contact professional fire-fighters
immediately. Cool containers with flooding quantities of water until
well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation. Do not expose spill to water.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Do
not allow water to get into the container because of violent
reaction. Avoid contact with eyes, skin, and clothing. Keep container
tightly closed. Avoid ingestion and inhalation. Do not allow contact
with water. Discard contaminated shoes. Keep from contact with moist
air and steam.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep away
from water.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use adequate ventilation to keep airborne
concentrations low.
Exposure Limits
CAS# 7791-25-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless or slight yellow
Odor: chlorine-like - sulfurous odor
pH: Not available.
Vapor Pressure: 133 mbar @ 20 C
Viscosity: 0.7 cP 24 C
Boiling Point: 69.1 deg C
Freezing/Melting Point: -54.1 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Reacts with water.
Specific Gravity/Density: 1.67
Molecular Formula: Cl2O2S
Molecular Weight: 134.9648
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Combines vigorously
or explosively with water.
Conditions to Avoid:
Incompatible materials, contact with water, acids, metals, alkaline
materials, strong oxidants, exposure to moist air or water, amines.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, oxides of sulfur, irritating and
toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7791-25-5: WT4870000
LD50/LC50:
CAS# 7791-25-5: Inhalation, rat: LC50 = 159 ppm/4H.
Carcinogenicity:
Sulfuryl Chloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 14 Reacts violently with water.
R 34 Causes burns.
R 37 Irritating to respiratory system.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7791-25-5: 1
Canada
CAS# 7791-25-5 is listed on Canada's DSL List.
CAS# 7791-25-5 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7791-25-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 10/24/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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| 10357-84-3 |
|
Diethyl dimethylmalonate, 97%
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|
D-(-)-Pantolactone, 99%
| 599-04-2 |
|
1-(4-Chlorophenyl)-1-Cyclohexane- Carboxylic Acid 95%
| 58880-37-8 |
|
1,1,3,3-Tetramethyldisiloxane, 97+%
| 3277-26-7 |
|
3,6-Dithia-1,8-Octanediol, 98%
| 5244-34-8 |
|
4-Biphenylcarboxaldehyde, 99%
| 3215-64-3 |
|
3-Indolebutyric Acid, 98%
| 133-32-4 |
|
2,4-Dihydro-5-Methyl-2-(4-Nitrophenyl)-3H-Pyrazol-3-One
| 6402-09-1 |
|
1-Cyclohexenylacetonitrile, 92%
| 6975-71-9 |
|
5-Chloro-2-Iodobenzotrifluoride, 99%
| 23399-77-1 |
|
Diisopropyl Cyanomethylphosphonate, 97%
| 58264-04-3 |
|
Sulfuryl Chloride, 99% (Titr.)
| 7791-25-5 |
|
4-(Dimethylamino)-Benzonitrile, 95%
| 1197-19-9 |
|
Antimony pentafluoride, 99.5+%
| 7783-70-2 |
|
1-Octanethiol, 97+%
| 111-88-6 |
|
2,4-Lutidine, 98+%
| 108-47-4 |
|
2-Methylimidazole, 99%
| 693-98-1 |
|
Butyl Isocyanate, 99% (GC)
| 111-36-4 |
|
Isosafrol, 95%,mixture of cis and trans
| 120-58-1 |
|
3,3',5- Triiodo-L-Thyronine, Sodium Salt, 95%
| 55-06-1 |
|
2,6-Dimethylbenzoquinone, 97%
| 527-61-7 |
|
5-Carbethoxy-2-Thiouracil, 99%
| 38026-46-9 |
|
Piperonylic acid, 99%
| 94-53-1 |
|
3-Thiopheneacetic acid, 98%
| 6964-21-2 |
|
Bis-(Triphenylphosphine)Palladium(II) Acetate, 99%
| 14588-08-0 |
|
2-Fluorobenzyl chloride, 98%
| 345-35-7 |
|
l-Histidine methyl ester dihydrochloride, 97%
| 7389-87-9 |
|
Phenolphthalein Diphosphate, Tetrasodium Salt Hydrate, 99%
| 68807-90-9 |
|
4-(Phenylazo)diphenylamine, 97%
| 101-75-7 |
|
2-(N-Ethyl-meta-toluidino)ethanol, 97%
| 91-88-3 |
|
Didecyl phthalate, 95% (GC)
| 84-77-5 |
|
Dl-phenylalanine, 99%
| 150-30-1 |
|
Citric Acid Anhydrous
| 77-92-9 |
|
Lithium Benzoate, 99%
| 553-54-8 |
|
P-Nitrophenyl Isocyanate, 97% (Titr.)
| 100-28-7 |
|
1-Chloro-2-methyl-2-phenylpropane 98%
| 515-40-2 |
|
Copper phthalocyanine, dye content ca 95%
| 147-14-8 |
|
Kartamine
| |
|
2,3,3-Trimethylindolenine, 98%
| 1640-39-7 |
|
Chloromethylated polystyrene: 1% divinylbenzene copolymer beads
| 70024-51-0 |
|
6-Methylquinoline, 95+% (gc)
| 91-62-3 |
|
3-Methylglutaric anhydride, 97%(titr.)
| 4166-53-4 |
|
5-Chloro-3-Ethyl-2-Methylbenzothiazolium P-Toluenesulfonate (Pract),
| 63149-16-6 |
|
Galvinoxyl, Free Radical, 98%
| 2370-18-5 |
|
Alpha-Methylcinnamaldehyde 98%
| 101-39-3 |
|
Propionic anhydride, p.a.
| 123-62-6 |
|
1,3-Dichlorobutane, 99%
| 1190-22-3 |
|
n-(2-Aminoethyl)-1,3-propanediamine, 97%
| 13531-52-7 |
|
Urocanic acid, 99%
| 104-98-3 |
|
|