**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 345-35-7 |2-Fluorobenzyl chloride | 98 | 206-460-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.Lachrymator (substance which increases the
flow of tears).Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears). May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause cyanosis of the extremities. May cause
skin rash (in milder cases), and cold and clammy skin with cyanosis
or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. Ingestion of large amounts may cause CNS depression. May
cause systemic effects.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract. Aspiration may lead to
pulmonary edema. Vapors may cause dizziness or suffocation. May
cause systemic effects.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas.
Extinguishing Media:
Do NOT use water directly on fire. Use water spray to cool
fire-exposed containers. Use foam, dry chemical, or carbon dioxide.
Water may be ineffective. Do NOT get water inside containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Do
not get water inside containers. A vapor suppressing foam may be
used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Do not breathe dust,
vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.
Empty containers retain product residue, (liquid and/or vapor), and
can be dangerous. Keep container tightly closed. Keep away from heat,
sparks and flame. Do not ingest or inhale. Do not allow contact with
water. Discard contaminated shoes. Do not pressurize, cut, weld,
braze, solder, drill, grind, or expose empty containers to heat,
sparks or open flames. Keep from contact with moist air and steam.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area. Store protected from moisture. Do not store in steel
container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 345-35-7:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 86 deg C @ 40 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 57 deg C ( 134.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Immiscible.
Specific Gravity/Density: 1.2160 g/cm3
Molecular Formula: C7H6ClF
Molecular Weight: 144.58
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, moisture, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents, bases, alcohols, amines, steel, moisture.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 345-35-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-Fluorobenzyl chloride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Corrosive Liquid, Flammable, N.O.S.
Hazard Class: 8
UN Number: 2920
Packing Group: II
IMO
Shipping Name: Corrosive Liquid, Flammable, N.O.S.
Hazard Class: 8
UN Number: 2920
Packing Group: II
RID/ADR
Shipping Name: Corrosive Liquid, Flammable, N.O.S.
Hazard Class: 8
UN Number: 2920
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 345-35-7: 2
Canada
CAS# 345-35-7 is listed on Canada's NDSL List.
CAS# 345-35-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 345-35-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #7 Date: 5/07/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,6-Dihydroxypyridine Hydrochloride, 97%
| 10357-84-3 |
|
Diethyl dimethylmalonate, 97%
| 1619-62-1 |
|
D-(-)-Pantolactone, 99%
| 599-04-2 |
|
1-(4-Chlorophenyl)-1-Cyclohexane- Carboxylic Acid 95%
| 58880-37-8 |
|
1,1,3,3-Tetramethyldisiloxane, 97+%
| 3277-26-7 |
|
3,6-Dithia-1,8-Octanediol, 98%
| 5244-34-8 |
|
4-Biphenylcarboxaldehyde, 99%
| 3215-64-3 |
|
3-Indolebutyric Acid, 98%
| 133-32-4 |
|
2,4-Dihydro-5-Methyl-2-(4-Nitrophenyl)-3H-Pyrazol-3-One
| 6402-09-1 |
|
1-Cyclohexenylacetonitrile, 92%
| 6975-71-9 |
|
5-Chloro-2-Iodobenzotrifluoride, 99%
| 23399-77-1 |
|
Diisopropyl Cyanomethylphosphonate, 97%
| 58264-04-3 |
|
Sulfuryl Chloride, 99% (Titr.)
| 7791-25-5 |
|
4-(Dimethylamino)-Benzonitrile, 95%
| 1197-19-9 |
|
Antimony pentafluoride, 99.5+%
| 7783-70-2 |
|
1-Octanethiol, 97+%
| 111-88-6 |
|
2,4-Lutidine, 98+%
| 108-47-4 |
|
2-Methylimidazole, 99%
| 693-98-1 |
|
Butyl Isocyanate, 99% (GC)
| 111-36-4 |
|
Isosafrol, 95%,mixture of cis and trans
| 120-58-1 |
|
3,3',5- Triiodo-L-Thyronine, Sodium Salt, 95%
| 55-06-1 |
|
2,6-Dimethylbenzoquinone, 97%
| 527-61-7 |
|
5-Carbethoxy-2-Thiouracil, 99%
| 38026-46-9 |
|
Piperonylic acid, 99%
| 94-53-1 |
|
3-Thiopheneacetic acid, 98%
| 6964-21-2 |
|
Bis-(Triphenylphosphine)Palladium(II) Acetate, 99%
| 14588-08-0 |
|
2-Fluorobenzyl chloride, 98%
| 345-35-7 |
|
l-Histidine methyl ester dihydrochloride, 97%
| 7389-87-9 |
|
Phenolphthalein Diphosphate, Tetrasodium Salt Hydrate, 99%
| 68807-90-9 |
|
4-(Phenylazo)diphenylamine, 97%
| 101-75-7 |
|
2-(N-Ethyl-meta-toluidino)ethanol, 97%
| 91-88-3 |
|
Didecyl phthalate, 95% (GC)
| 84-77-5 |
|
Dl-phenylalanine, 99%
| 150-30-1 |
|
Citric Acid Anhydrous
| 77-92-9 |
|
Lithium Benzoate, 99%
| 553-54-8 |
|
P-Nitrophenyl Isocyanate, 97% (Titr.)
| 100-28-7 |
|
1-Chloro-2-methyl-2-phenylpropane 98%
| 515-40-2 |
|
Copper phthalocyanine, dye content ca 95%
| 147-14-8 |
|
Kartamine
| |
|
2,3,3-Trimethylindolenine, 98%
| 1640-39-7 |
|
Chloromethylated polystyrene: 1% divinylbenzene copolymer beads
| 70024-51-0 |
|
6-Methylquinoline, 95+% (gc)
| 91-62-3 |
|
3-Methylglutaric anhydride, 97%(titr.)
| 4166-53-4 |
|
5-Chloro-3-Ethyl-2-Methylbenzothiazolium P-Toluenesulfonate (Pract),
| 63149-16-6 |
|
Galvinoxyl, Free Radical, 98%
| 2370-18-5 |
|
Alpha-Methylcinnamaldehyde 98%
| 101-39-3 |
|
Propionic anhydride, p.a.
| 123-62-6 |
|
1,3-Dichlorobutane, 99%
| 1190-22-3 |
|
n-(2-Aminoethyl)-1,3-propanediamine, 97%
| 13531-52-7 |
|
Urocanic acid, 99%
| 104-98-3 |
|
|