**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1465-25-4 |N-(1-Naphthyl)Ethylenediamine Dihydroc| ca 100 | 215-981-2 |
| |hloride | | |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Hygroscopic.Light
sensitive.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Expected to be a low ingestion hazard.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary
edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at
least 15 minutes while removing contaminated clothing and shoes. Wash
clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam. Do
NOT get water inside containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Wash area with soap and water. Clean up spills immediately,
observing precautions in the Protective Equipment section. Sweep up,
then place into a suitable container for disposal. Avoid generating
dusty conditions. Provide ventilation. Do not get water inside
containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Avoid ingestion and
inhalation. Store protected from light. Do not allow contact with
water. Keep from contact with moist air and steam.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Store protected from moisture. Store protected from light.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134 or European Standard EN 149. Always use a
NIOSH or European Standard EN 149 approved respirator
when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Appearance: off-white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 188-190C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 200 deg C
Solubility in water: Slightly soluble in cold water.
Specific Gravity/Density:
Molecular Formula: C12H14N2.2HCl
Molecular Weight: 259.0314
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Hygroscopic: absorbs
moisture or water from the air.
Conditions to Avoid:
Incompatible materials, light, dust generation, excess heat, exposure
to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, irritating and
toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1465-25-4: KV5330000
LD50/LC50:
Not available.
Carcinogenicity:
N-(1-Naphthyl)Ethylenediamine Dihydrochloride -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Shipping Name: Not regulated.
Dangerous Goods Code:
UN Number:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 1465-25-4: No information available.
United Kingdom Occupational Exposure Limits
Canada
CAS# 1465-25-4 is listed on Canada's DSL List.
CAS# 1465-25-4 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 1465-25-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/07/1998 Revision #2 Date: 3/26/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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2,6-Di-tert.butyl-4-methylphenol,
| 128-37-0 |
|
Sodium Hydride, 60% Dispersion in Mineral Oil, DMF Soluble Bags
| 7646-69-7 |
|
1,1,1-Trichloroacetone
| 918-00-3 |
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(m-methoxyphenyl)acetonitrile, 97%
| 19924-43-7 |
|
Tributylpropynylstannane
| 64099-82-7 |
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Diethylenetriamine-n,n,n',n',n'',n''-penta acetic dianhydride
| 23911-26-4 |
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N-boc-l-1,2,3,4-tetrahydro-beta-carboline- 3-carboxylic acid
| |
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D-1,2,3,4-Tetrahydroisoquinoline-3-Carboxylic Acid Hydrochloride
| 41220-48-8 |
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2-Tert-Butylcyclohexanone, 97%
| 1728-46-7 |
|
L-1,2,3,4-Tetrahydroisoquinoline-3-Carboxylic Acid Hydrochloride
| 77497-95-1 |
|
4-Chloro-3-Methylphenol, 99%
| 59-50-7 |
|
N-boc-l-1,2,3,4-tetrahydroisoquinoline-3-c arboxylic acid
| |
|
N-FMOC-l-1,2,3,4-Tetrahydroisoquinoline-3- Carboxylic Acid
| 136030-33-6 |
|
N,n,2-trimethylpropionamide, 99%
| 21678-37-5 |
|
5-Amino-3-Phenyl-1,2,4-Thiadiazole, 99%
| 17467-15-1 |
|
4,6-Dimethyldibenzothiophene, 95% (gc)
| |
|
[(2-Chloroethyl)thio]benzene
| 5535-49-9 |
|
2,2-Dichlorocyclopropyl phenyl sulfide
| 63289-85-0 |
|
2,2-Dichlorocyclopropyl phenyl sulfone
| 38435-04-0 |
|
1-TOSYL-4-PHENYL-4-CARBOXY PIPERIDINE
| 50-00-0 |
|
(+)-[(8,8-Dichlorocamphoryl)sulfonyl]oxazi ridine
| 127184-05-8 |
|
(-)-[(8,8-Dichlorocamphoryl)sulfonyl]oxazi ridine
| 139628-16-3 |
|
Dl-3-aminoisobutyric acid monohydrate, 99%
| |
|
4-Phenyl-1-Butanol, 97%
| 3360-41-6 |
|
Potassium deuteroxide, 30 wt% solution in D2O
| 7789-20-0 |
|
5-tert.-Butyl-4-hydroxy-2-methylphenyl sulfide
| 96-69-5 |
|
Pyridinium fluorochromate
| 83042-08-4 |
|
5-beta-Cholestan
| 481-20-9 |
|
Dibenzoyl-d-tartaric acid
| 17026-42-5 |
|
Doyle dirhodium catalyst - RH2(5R-MEPY)4
| 67-63-0 |
|
Doyle dirhodium catalyst - RH2(5S-MEPY)4
| 67-63-0 |
|
Doyle dirhodium catalyst - rh2(4s-meox)4
| 167693-36-9 |
|
Doyle dirhodium catalyst - RH2(4S-MPPIM)4
| 75-05-8 |
|
Doyle dirhodium catalyst - rh2(capy)4
| 138984-26-6 |
|
Dibromoacetonitrile, 97+%
| 3252-43-5 |
|
Octyl Sodium Sulfate, HPLC Grade, 94% (Titr.)
| 142-31-4 |
|
Isobutyl vinyl ether, 99.5% (gc), stabilized with 0.1% potassium
| 109-53-5 |
|
Potassium hydroxide, 50 wt% aqueous solution
| 1310-58-3 |
|
Potassium hydroxide, 10 wt% aqueous soluti on
| 1310-58-3 |
|
Potassium hydroxide, 30 wt% aqueous solution
| 1310-58-3 |
|
Dl-aspartic acid k-mg salt
| |
|
1-Chloro-N,N,2-trimethylpropenylamine, 98.5+% (GC)
| 26189-59-3 |
|
Isosorbide-2-mononitrate
| 16106-20-0 |
|
1,2-Dichloroethylene, 99%, mixture of isomers
| 540-59-0 |
|
cis-1,2-Dichloroethylene, 97%
| 156-59-2 |
|
2-Methylaminophenol, 97+%
| 611-24-5 |
|
Hydrogen Peroxide, 50 wt% Solution in Water
| 7722-84-1 |
|
Ammonium Hydroxide, 25% Solution in Water, C.P.
| 1336-21-6 |
|
N-(1-Naphthyl)ethylenediamine Dihydrochloride, P.A.
| 1465-25-4 |
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N-Ethyl-Beta-Alaninenitrile
| 21539-47-9 |
|
|