**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 21678-37-5 |N,N,2-Trimethylpropionamide | 99.0 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully
investigated.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated. May be
harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Will burn
if involved in a fire. Use water spray to keep fire-exposed
containers cool. Combustible liquid. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined
areas. Containers may explode when heated.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Cool containers with flooding quantities of water until well after
fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Sweep up
or absorb material, then place into a suitable clean, dry, closed
container for disposal. Remove all sources of ignition. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin,
and clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Avoid ingestion and inhalation. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Keep under a nitrogen
blanket. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 21678-37-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use. Follow the OSHA
respirator regulations found in 29 CFR 1910.134 or
European Standard EN 149. Use a NIOSH/MSHA or
European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or
other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 175 - 176 deg C @ 744.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 67 deg C ( 152.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .8920g/cm3
Molecular Formula: C6H13NO
Molecular Weight: 115.18
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, exposure to
moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 21678-37-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
N,N,2-Trimethylpropionamide -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 21678-37-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 21678-37-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 21678-37-5 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/02/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,6-Di-tert.butyl-4-methylphenol,
| 128-37-0 |
|
Sodium Hydride, 60% Dispersion in Mineral Oil, DMF Soluble Bags
| 7646-69-7 |
|
1,1,1-Trichloroacetone
| 918-00-3 |
|
(m-methoxyphenyl)acetonitrile, 97%
| 19924-43-7 |
|
Tributylpropynylstannane
| 64099-82-7 |
|
Diethylenetriamine-n,n,n',n',n'',n''-penta acetic dianhydride
| 23911-26-4 |
|
N-boc-l-1,2,3,4-tetrahydro-beta-carboline- 3-carboxylic acid
| |
|
D-1,2,3,4-Tetrahydroisoquinoline-3-Carboxylic Acid Hydrochloride
| 41220-48-8 |
|
2-Tert-Butylcyclohexanone, 97%
| 1728-46-7 |
|
L-1,2,3,4-Tetrahydroisoquinoline-3-Carboxylic Acid Hydrochloride
| 77497-95-1 |
|
4-Chloro-3-Methylphenol, 99%
| 59-50-7 |
|
N-boc-l-1,2,3,4-tetrahydroisoquinoline-3-c arboxylic acid
| |
|
N-FMOC-l-1,2,3,4-Tetrahydroisoquinoline-3- Carboxylic Acid
| 136030-33-6 |
|
N,n,2-trimethylpropionamide, 99%
| 21678-37-5 |
|
5-Amino-3-Phenyl-1,2,4-Thiadiazole, 99%
| 17467-15-1 |
|
4,6-Dimethyldibenzothiophene, 95% (gc)
| |
|
[(2-Chloroethyl)thio]benzene
| 5535-49-9 |
|
2,2-Dichlorocyclopropyl phenyl sulfide
| 63289-85-0 |
|
2,2-Dichlorocyclopropyl phenyl sulfone
| 38435-04-0 |
|
1-TOSYL-4-PHENYL-4-CARBOXY PIPERIDINE
| 50-00-0 |
|
(+)-[(8,8-Dichlorocamphoryl)sulfonyl]oxazi ridine
| 127184-05-8 |
|
(-)-[(8,8-Dichlorocamphoryl)sulfonyl]oxazi ridine
| 139628-16-3 |
|
Dl-3-aminoisobutyric acid monohydrate, 99%
| |
|
4-Phenyl-1-Butanol, 97%
| 3360-41-6 |
|
Potassium deuteroxide, 30 wt% solution in D2O
| 7789-20-0 |
|
5-tert.-Butyl-4-hydroxy-2-methylphenyl sulfide
| 96-69-5 |
|
Pyridinium fluorochromate
| 83042-08-4 |
|
5-beta-Cholestan
| 481-20-9 |
|
Dibenzoyl-d-tartaric acid
| 17026-42-5 |
|
Doyle dirhodium catalyst - RH2(5R-MEPY)4
| 67-63-0 |
|
Doyle dirhodium catalyst - RH2(5S-MEPY)4
| 67-63-0 |
|
Doyle dirhodium catalyst - rh2(4s-meox)4
| 167693-36-9 |
|
Doyle dirhodium catalyst - RH2(4S-MPPIM)4
| 75-05-8 |
|
Doyle dirhodium catalyst - rh2(capy)4
| 138984-26-6 |
|
Dibromoacetonitrile, 97+%
| 3252-43-5 |
|
Octyl Sodium Sulfate, HPLC Grade, 94% (Titr.)
| 142-31-4 |
|
Isobutyl vinyl ether, 99.5% (gc), stabilized with 0.1% potassium
| 109-53-5 |
|
Potassium hydroxide, 50 wt% aqueous solution
| 1310-58-3 |
|
Potassium hydroxide, 10 wt% aqueous soluti on
| 1310-58-3 |
|
Potassium hydroxide, 30 wt% aqueous solution
| 1310-58-3 |
|
Dl-aspartic acid k-mg salt
| |
|
1-Chloro-N,N,2-trimethylpropenylamine, 98.5+% (GC)
| 26189-59-3 |
|
Isosorbide-2-mononitrate
| 16106-20-0 |
|
1,2-Dichloroethylene, 99%, mixture of isomers
| 540-59-0 |
|
cis-1,2-Dichloroethylene, 97%
| 156-59-2 |
|
2-Methylaminophenol, 97+%
| 611-24-5 |
|
Hydrogen Peroxide, 50 wt% Solution in Water
| 7722-84-1 |
|
Ammonium Hydroxide, 25% Solution in Water, C.P.
| 1336-21-6 |
|
N-(1-Naphthyl)ethylenediamine Dihydrochloride, P.A.
| 1465-25-4 |
|
N-Ethyl-Beta-Alaninenitrile
| 21539-47-9 |
|
|