**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 83042-08-4 |Pyridinium fluorochromate | | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T O
Risk Phrases: 43 45 8
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
May cause sensitization by skin contact. May cause cancer. Contact
with combustible material may cause fire.The toxicological properties
of this material have not been fully investigated.Moisture sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
The toxicological properties of this substance have not been fully
investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated.
Chronic:
May cause cancer in humans.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower lids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
soap and water for at least 15 minutes while removing contaminated
clothing and shoes.
Ingestion:
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air
immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Oxidizer. Greatly increases the burning rate of
combustible materials.
Extinguishing Media:
In case of fire use water spray, dry chemical, carbon dioxide, or
chemical foam.
Autoignition Temperature: Not available.
Flash Point: Not available.
NFPA Rating: Not published.
Explosion Limits, Lower: Not available.
Upper: Not available.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood.
Storage:
Do not store near combustible materials. Store in a cool, dry place.
Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134. Always use a NIOSH-approved respirator when
necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Appearance: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 158 deg C dec
Decomposition Temperature: Not available.
Solubility: soluble
Specific Gravity/Density: Not available.
Molecular Formula: C5H6CrFNO3
Molecular Weight: 199.10
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, exposure to moist air or
water.
Incompatibilities with Other Materials:
Strong acids - strong reducing agents - alcohols.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 83042-08-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Pyridinium fluorochromate -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
For further information, contact Fisher Scientific.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
CDG/CPL
IMO
Shipping Name: OXIDIZING SOLID, N.O.S.
Hazard Class: 5.1
UN Number: 1479
Packing Group: II
IATA
Shipping Name: OXIDIZING SOLID, N.O.S.*
Hazard Class: 5.1
UN Number: 1479
Packing Group: II
RID/ADR
Shipping Name: OXIDIZING SOLID, N.O.S.
Dangerous Goods Code: 5.1(27B)
UN Number: 1479
Canadian TDG
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T O
Risk Phrases:
R 43 May cause sensitization by skin contact.
R 45 May cause cancer.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
S 24 Avoid contact with skin.
S 37 Wear suitable gloves.
S 45 In case of accident of if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 53 Avoid exposure - obtain special instructions
before use.
WGK (Water Danger/Protection)
CAS# 83042-08-4:
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
WHMIS: Not available.
CAS# 83042-08-4 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 83042-08-4 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 10/01/1996 Revision #0 Date: Original.
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,6-Di-tert.butyl-4-methylphenol,
| 128-37-0 |
|
Sodium Hydride, 60% Dispersion in Mineral Oil, DMF Soluble Bags
| 7646-69-7 |
|
1,1,1-Trichloroacetone
| 918-00-3 |
|
(m-methoxyphenyl)acetonitrile, 97%
| 19924-43-7 |
|
Tributylpropynylstannane
| 64099-82-7 |
|
Diethylenetriamine-n,n,n',n',n'',n''-penta acetic dianhydride
| 23911-26-4 |
|
N-boc-l-1,2,3,4-tetrahydro-beta-carboline- 3-carboxylic acid
| |
|
D-1,2,3,4-Tetrahydroisoquinoline-3-Carboxylic Acid Hydrochloride
| 41220-48-8 |
|
2-Tert-Butylcyclohexanone, 97%
| 1728-46-7 |
|
L-1,2,3,4-Tetrahydroisoquinoline-3-Carboxylic Acid Hydrochloride
| 77497-95-1 |
|
4-Chloro-3-Methylphenol, 99%
| 59-50-7 |
|
N-boc-l-1,2,3,4-tetrahydroisoquinoline-3-c arboxylic acid
| |
|
N-FMOC-l-1,2,3,4-Tetrahydroisoquinoline-3- Carboxylic Acid
| 136030-33-6 |
|
N,n,2-trimethylpropionamide, 99%
| 21678-37-5 |
|
5-Amino-3-Phenyl-1,2,4-Thiadiazole, 99%
| 17467-15-1 |
|
4,6-Dimethyldibenzothiophene, 95% (gc)
| |
|
[(2-Chloroethyl)thio]benzene
| 5535-49-9 |
|
2,2-Dichlorocyclopropyl phenyl sulfide
| 63289-85-0 |
|
2,2-Dichlorocyclopropyl phenyl sulfone
| 38435-04-0 |
|
1-TOSYL-4-PHENYL-4-CARBOXY PIPERIDINE
| 50-00-0 |
|
(+)-[(8,8-Dichlorocamphoryl)sulfonyl]oxazi ridine
| 127184-05-8 |
|
(-)-[(8,8-Dichlorocamphoryl)sulfonyl]oxazi ridine
| 139628-16-3 |
|
Dl-3-aminoisobutyric acid monohydrate, 99%
| |
|
4-Phenyl-1-Butanol, 97%
| 3360-41-6 |
|
Potassium deuteroxide, 30 wt% solution in D2O
| 7789-20-0 |
|
5-tert.-Butyl-4-hydroxy-2-methylphenyl sulfide
| 96-69-5 |
|
Pyridinium fluorochromate
| 83042-08-4 |
|
5-beta-Cholestan
| 481-20-9 |
|
Dibenzoyl-d-tartaric acid
| 17026-42-5 |
|
Doyle dirhodium catalyst - RH2(5R-MEPY)4
| 67-63-0 |
|
Doyle dirhodium catalyst - RH2(5S-MEPY)4
| 67-63-0 |
|
Doyle dirhodium catalyst - rh2(4s-meox)4
| 167693-36-9 |
|
Doyle dirhodium catalyst - RH2(4S-MPPIM)4
| 75-05-8 |
|
Doyle dirhodium catalyst - rh2(capy)4
| 138984-26-6 |
|
Dibromoacetonitrile, 97+%
| 3252-43-5 |
|
Octyl Sodium Sulfate, HPLC Grade, 94% (Titr.)
| 142-31-4 |
|
Isobutyl vinyl ether, 99.5% (gc), stabilized with 0.1% potassium
| 109-53-5 |
|
Potassium hydroxide, 50 wt% aqueous solution
| 1310-58-3 |
|
Potassium hydroxide, 10 wt% aqueous soluti on
| 1310-58-3 |
|
Potassium hydroxide, 30 wt% aqueous solution
| 1310-58-3 |
|
Dl-aspartic acid k-mg salt
| |
|
1-Chloro-N,N,2-trimethylpropenylamine, 98.5+% (GC)
| 26189-59-3 |
|
Isosorbide-2-mononitrate
| 16106-20-0 |
|
1,2-Dichloroethylene, 99%, mixture of isomers
| 540-59-0 |
|
cis-1,2-Dichloroethylene, 97%
| 156-59-2 |
|
2-Methylaminophenol, 97+%
| 611-24-5 |
|
Hydrogen Peroxide, 50 wt% Solution in Water
| 7722-84-1 |
|
Ammonium Hydroxide, 25% Solution in Water, C.P.
| 1336-21-6 |
|
N-(1-Naphthyl)ethylenediamine Dihydrochloride, P.A.
| 1465-25-4 |
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N-Ethyl-Beta-Alaninenitrile
| 21539-47-9 |
|
|