Sodium Hydride, 60% Dispersion in Mineral Oil, DMF Soluble Bags
CAS
:
7646-69-7
SYNONYMS
:
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 7646-69-7 |SODIUM HYDRIDE | 60% | 231-587-3 |
|----------------|--------------------------------------|----------|-----------|
| 8042-47-5 |MINERAL OIL | 40% | 232-455-8 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: F
Risk Phrases: 15
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Contact with water liberates extremely flammable
gases.Water-reactive.
Potential Health Effects
Eye:
May cause eye irritation and possible burns.
Skin:
May cause severe skin irritation with possible burns, especially if
skin is wet or moist.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea,
vomiting and possible burns.
Inhalation:
May cause severe irritation of the respiratory tract with possible
burns.
Chronic:
None
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water Reactive. Material will react with water and
may release a flammable and/or toxic gas. Containers may explode in
the heat of a fire. May re-ignite after fire is extinguished.
Extinguishing Media:
Do NOT get water inside containers. Cool containers with flooding
quantities of water until well after fire is out. DO NOT USE WATER
OR FOAM. For small fires, use dry chemical, soda ash, lime or sand.
For large fires, use dry sand, dry chemical, soda ash or lime or
withdraw from area and let fire burn.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Provide ventilation. Do not expose
spill to water. Do not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin
and eyes. Do not allow contact with water. Use only in a chemical
fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Water free area. Store totally
immersed in oil.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7646-69-7:
CAS# 8042-47-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid/Liquid Mixture
Color: white to gray
Odor: Practically odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 800 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature: >225 deg C
Solubility in water: Reacts.
Specific Gravity/Density: 1.2000g/cm3
Molecular Formula: HNa
Molecular Weight: 23.9968
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, exposure to air, contact with water,
temperatures above 220C.
Incompatibilities with Other Materials:
Acids - alcohols - carbon dioxide - hydrogenhalides.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen gas.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7646-69-7 unlisted.
CAS# 8042-47-5: PY8047000
LD50/LC50:
Not available.
Not available.
Carcinogenicity:
SODIUM HYDRIDE -
Not listed by ACGIH, IARC, or NTP.
MINERAL OIL -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: SODIUM HYDRIDE
Hazard Class: 4.3
UN Number: 1427
Packing Group: I
IMO
Shipping Name: SODIUM HYDRIDE
Hazard Class: 4.3
UN Number: 1427
Packing Group: I
RID/ADR
Shipping Name: SODIUM HYDRIDE
Hazard Class: 4.3
UN Number: 1427
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 15 Contact with water liberates extremely
flammable gases.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 24/25 Avoid contact with skin and eyes.
S 43A In case of fire, use dry chemical (never use
water).
WGK (Water Danger/Protection)
CAS# 7646-69-7: 1
CAS# 8042-47-5: No information available.
Canada
CAS# 7646-69-7 is listed on Canada's DSL List.
CAS# 8042-47-5 is listed on Canada's DSL List.
CAS# 7646-69-7 is not listed on Canada's Ingredient Disclosure List.
CAS# 8042-47-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7646-69-7 is listed on the TSCA inventory.
CAS# 8042-47-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 15 Contact with water liberates extremely flammable
gases.
MSDS Creation Date: 2/05/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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