**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 156-43-4 |p-Phenetidine | 98.0 | 205-855-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/24/25 33
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed. Danger
of cumulative effects.Light sensitive.Air sensitive.
Potential Health Effects
Eye:
Causes moderate eye irritation.
Skin:
Causes mild skin irritation. May be absorbed through the skin.
Effects of contact may be delayed.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. Effects of inhalation may be
delayed.
Chronic:
There is a danger of cumulative effects.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
Do NOT get water inside containers. For small fires, use dry
chemical, carbon dioxide, or water spray. For large fires, use dry
chemical, carbon dioxide, alcohol-resistant foam, or water spray.
Cool containers with flooding quantities of water until well after
fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation. Use with adequate ventilation. Store protected from
light. Store protected from air.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Keep containers tightly closed. Store protected from
light and air.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 156-43-4:
Russia: 0.2 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: amber
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 250 deg C @ 760.00mmHg
Freezing/Melting Point: 4 deg C
Autoignition Temperature: Not available.
Flash Point: 240 deg F ( 115.56 deg C)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble in alcohol
Specific Gravity/Density: 1.0650g/cm3
Molecular Formula: C8H11NO
Molecular Weight: 137.18
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Air sensitive. Light
sensitive.
Conditions to Avoid:
Incompatible materials, exposure to air, excess light.
Incompatibilities with Other Materials:
Acids - acid chlorides - acid anhydrides - chloroformates - strong
oxidizing agents - light - air.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 156-43-4: SI6465500
LD50/LC50:
CAS# 156-43-4: Draize test, rabbit, eye: 100 mg Moderate; Draize
test, rabbit, skin: 500 mg Mild; Oral, mouse: LD50 = 530 mg/kg; Oral,
rabbit: LD50 = 7 gm/kg; Oral, rat: LD50 = 540 mg/kg; Skin, rabbit:
LD50 = 2353 mg/kg.
TDLo - Lowest published toxic dose(Oral, rat)=1120
Carcinogenicity:
p-Phenetidine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: PHENETIDINES
Hazard Class: 6.1
UN Number: 2311
Packing Group: III
IMO
Shipping Name: PHENETIDINES
Hazard Class: 6.1
UN Number: 2311
Packing Group: III
RID/ADR
Shipping Name: PHENETIDINES
Hazard Class: 6.1
UN Number: 2311
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 33 Danger of cumulative effects.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 156-43-4: 1
Canada
CAS# 156-43-4 is listed on Canada's DSL List.
CAS# 156-43-4 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 156-43-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/11/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
bis(2-Ethylhexyl) hydrogen phosphate, 95% (titr.)
| 298-07-7 |
|
Acriflavine Neutral, 13.3-15.8% Chlorine (on Dried Substance)
| 7782-50-5 |
|
p-Phenetidine, 98%
| 156-43-4 |
|
Cryptocyanine, 99% (UV-VIS)
| 4727-50-8 |
|
Methyl anthranilate
| 134-20-3 |
|
Phenylmercuric Nitrate, 62.75-63.50% Mercury
| 8003-05-2 |
|
Formaldehyde, 37 wt% solution in water, stabilized with 10-15%
| 50-00-0 |
|
2,4-Dimethyl-3-pentanol, 99+%
| 600-36-2 |
|
4-Bromochlorobenzene, 99%
| 106-39-8 |
|
Beta-Alanine, 98%
| 107-95-9 |
|
Tin (IV) Oxide, 99.995%
| 18282-10-5 |
|
Ethanesulfonic Acid, 99%
| 594-45-6 |
|
5-Methyl-3-heptanone, 98.5+%
| 541-85-5 |
|
m-Phenetidine, 98%
| 621-33-0 |
|
4-Dimethylaminobenzaldehyde, 98%
| 100-10-7 |
|
4-Dimethylaminobenzaldehyde, reagent acs
| 100-10-7 |
|
1,1,2,2-Tetrachloroethane, 97%
| 79-34-5 |
|
p-Phenylenediamine, 99+%
| 106-50-3 |
|
Hemin, bovine, crystalline, 98%
| 16009-13-5 |
|
2,6-Dimethylphenol, P.A.
| 576-26-1 |
|
beta-Methylstyrene, 99% trans, stabilized with 0.01% BHT
| 128-37-0 |
|
Diethyl Sulfate, 99%
| 64-67-5 |
|
3,5-Diiodosalicylic Acid, 97% (HPLC)
| 133-91-5 |
|
2-Sulfobenzoic Acid Cyclic Anhydride, Tech
| 81-08-3 |
|
1,5-Pentanediol, 98%
| 111-29-5 |
|
Dibenzyl Phosphate, 99%
| 1623-08-1 |
|
2-Methyl-1-undecene, 99+%
| 18516-37-5 |
|
2-Nitrobenzoic acid, 85-90%,(gc)
| 552-16-9 |
|
Lithium acetylide, ethylenediamine complex 85-92%
| 6867-30-7 |
|
3,3',4,4'-Benzophenonetetracarboxylic dianhydride, 96%
| 2421-28-5 |
|
trans-Cinnamaldehyde, 99%
| 104-55-2 |
|
Fullerene C70, 99+% (HPLC)
| 115383-22-7 |
|
3-Bromo-1-propanol, 98%
| 627-18-9 |
|
3-Nitrobenzyl chloride, 97+% (gc)
| 619-23-8 |
|
2,6-Diethylaniline, 98%
| 579-66-8 |
|
1,1,1-Trichloroethane, 93.5%, stabilized with ca. 5% 1,4-dioxane
| 71-55-6 |
|
Trimethyl Phosphate, 97%
| 512-56-1 |
|
2-(5-Bromo-2-Pyridylazo)-5-(Diethylamino)- Phenol, 97%
| 14337-53-2 |
|
Beta-Cyclodextrin Hydrate, 99% (HPLC)
| 68168-23-0 |
|
3,3'-Diethylthiadicarbocyanine Iodide, 99% (UV-VIS)
| 514-73-8 |
|
4-Methyl-1-cyclohexene, 99%
| 591-47-9 |
|
Mesityl oxide, 99%, mixt.of alpha- and bet a isomers(ca.93% alpha)
| 141-79-7 |
|
Butyl acrylate, 99+%, stabilized with 20 ppm MEHQ
| 141-32-2 |
|
Methyl diphenylphosphine, 99%
| 1486-28-8 |
|
2,5-Di-tert-butylhydroquinone
| 88-58-4 |
|
Orcinol, Monohydrate (Pract), 95% (UV-Vis)
| 6153-39-5 |
|
1-Iodohexane, 98+%,stabilized over copper
| 638-45-9 |
|
Octadecane, 99+% (gc)
| 593-45-3 |
|
Pamoic Acid, Disodium Salt Monohydrate, 98% (UV-Vis)
| 6640-22-8 |
|
Potassium fluoride
| 7789-23-3 |
|
|