**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 579-66-8 |2,6-Diethylaniline | 98 | 209-445-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed.Light sensitive.Air sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. Methemoglobinemia is
characterized by dizziness, drowsiness, headache, shortness of
breath, cyanosis (bluish discoloration of skin due to deficient
oxygenation of the blood), rapid heart rate and chocolate-brown
colored blood. May be harmful if swallowed. Overexposure may cause
methemoglobinemia.
Inhalation:
May cause respiratory tract irritation. Methemoglobinemia is
characterized by dizziness, drowsiness, headache, shortness of
breath, cyanosis (bluish discoloration of skin due to deficient
oxygenation of the blood), rapid heart rate and chocolate-brown
blood. Inhalation of aniline causes anoxia due to the formation of
methemoglobin.
Chronic:
May cause methemoglobinemia, which is characterized by
chocolate-brown colored blood, headache, weakness, dizziness, breath
shortness, cyanosis (bluish skin due to deficient oxygenation of
blood), rapid heart rate, unconsciousness and possible death.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
For methemoglobinemia, administer oxygen alone or with Methylene
Blue depending on the methemoglobin concentration in the blood.
Antidote:
Methylene blue, alone or in combination with oxygen is indicated as
a treatment in nitrite induced methemoglobinemia.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Water may be ineffective.
Material is lighter than water and a fire may be spread by the use of
water. Vapors may be heavier than air. They can spread along the
ground and collect in low or confined areas. Containers may explode
when heated.
Extinguishing Media:
Water may be ineffective. Use agent most appropriate to extinguish
fire. Cool containers with flooding quantities of water until well
after fire is out. Use water spray, dry chemical, carbon dioxide, or
appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation. Place under an inert
atmosphere.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation. Store protected from light. Handle
under an inert atmosphere. Store protected from air.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Do not expose
to air. Store protected from light. Store under an inert atmosphere.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 579-66-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear red
Odor: None reported.
pH: Not available.
Vapor Pressure: 0.02 mmHg @ 20
Viscosity: Not available.
Boiling Point: 243 deg C @ 760.00mmHg
Freezing/Melting Point: 3.00 - 4.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: 123 deg C ( 253.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .9060g/cm3
Molecular Formula: C10H15N
Molecular Weight: 149.24
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light, ignition sources, exposure to air,
excess heat.
Incompatibilities with Other Materials:
Air, strong acids, strong bases, strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 579-66-8: BX3500000
LD50/LC50:
CAS# 579-66-8: Oral, rat: LD50 = 1800 mg/kg.
Carcinogenicity:
2,6-Diethylaniline -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 24 Avoid contact with skin.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 579-66-8: 2
Canada
CAS# 579-66-8 is listed on Canada's DSL List.
CAS# 579-66-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 579-66-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #6 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
bis(2-Ethylhexyl) hydrogen phosphate, 95% (titr.)
| 298-07-7 |
|
Acriflavine Neutral, 13.3-15.8% Chlorine (on Dried Substance)
| 7782-50-5 |
|
p-Phenetidine, 98%
| 156-43-4 |
|
Cryptocyanine, 99% (UV-VIS)
| 4727-50-8 |
|
Methyl anthranilate
| 134-20-3 |
|
Phenylmercuric Nitrate, 62.75-63.50% Mercury
| 8003-05-2 |
|
Formaldehyde, 37 wt% solution in water, stabilized with 10-15%
| 50-00-0 |
|
2,4-Dimethyl-3-pentanol, 99+%
| 600-36-2 |
|
4-Bromochlorobenzene, 99%
| 106-39-8 |
|
Beta-Alanine, 98%
| 107-95-9 |
|
Tin (IV) Oxide, 99.995%
| 18282-10-5 |
|
Ethanesulfonic Acid, 99%
| 594-45-6 |
|
5-Methyl-3-heptanone, 98.5+%
| 541-85-5 |
|
m-Phenetidine, 98%
| 621-33-0 |
|
4-Dimethylaminobenzaldehyde, 98%
| 100-10-7 |
|
4-Dimethylaminobenzaldehyde, reagent acs
| 100-10-7 |
|
1,1,2,2-Tetrachloroethane, 97%
| 79-34-5 |
|
p-Phenylenediamine, 99+%
| 106-50-3 |
|
Hemin, bovine, crystalline, 98%
| 16009-13-5 |
|
2,6-Dimethylphenol, P.A.
| 576-26-1 |
|
beta-Methylstyrene, 99% trans, stabilized with 0.01% BHT
| 128-37-0 |
|
Diethyl Sulfate, 99%
| 64-67-5 |
|
3,5-Diiodosalicylic Acid, 97% (HPLC)
| 133-91-5 |
|
2-Sulfobenzoic Acid Cyclic Anhydride, Tech
| 81-08-3 |
|
1,5-Pentanediol, 98%
| 111-29-5 |
|
Dibenzyl Phosphate, 99%
| 1623-08-1 |
|
2-Methyl-1-undecene, 99+%
| 18516-37-5 |
|
2-Nitrobenzoic acid, 85-90%,(gc)
| 552-16-9 |
|
Lithium acetylide, ethylenediamine complex 85-92%
| 6867-30-7 |
|
3,3',4,4'-Benzophenonetetracarboxylic dianhydride, 96%
| 2421-28-5 |
|
trans-Cinnamaldehyde, 99%
| 104-55-2 |
|
Fullerene C70, 99+% (HPLC)
| 115383-22-7 |
|
3-Bromo-1-propanol, 98%
| 627-18-9 |
|
3-Nitrobenzyl chloride, 97+% (gc)
| 619-23-8 |
|
2,6-Diethylaniline, 98%
| 579-66-8 |
|
1,1,1-Trichloroethane, 93.5%, stabilized with ca. 5% 1,4-dioxane
| 71-55-6 |
|
Trimethyl Phosphate, 97%
| 512-56-1 |
|
2-(5-Bromo-2-Pyridylazo)-5-(Diethylamino)- Phenol, 97%
| 14337-53-2 |
|
Beta-Cyclodextrin Hydrate, 99% (HPLC)
| 68168-23-0 |
|
3,3'-Diethylthiadicarbocyanine Iodide, 99% (UV-VIS)
| 514-73-8 |
|
4-Methyl-1-cyclohexene, 99%
| 591-47-9 |
|
Mesityl oxide, 99%, mixt.of alpha- and bet a isomers(ca.93% alpha)
| 141-79-7 |
|
Butyl acrylate, 99+%, stabilized with 20 ppm MEHQ
| 141-32-2 |
|
Methyl diphenylphosphine, 99%
| 1486-28-8 |
|
2,5-Di-tert-butylhydroquinone
| 88-58-4 |
|
Orcinol, Monohydrate (Pract), 95% (UV-Vis)
| 6153-39-5 |
|
1-Iodohexane, 98+%,stabilized over copper
| 638-45-9 |
|
Octadecane, 99+% (gc)
| 593-45-3 |
|
Pamoic Acid, Disodium Salt Monohydrate, 98% (UV-Vis)
| 6640-22-8 |
|
Potassium fluoride
| 7789-23-3 |
|
|