**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7789-23-3 |Potassium fluoride | 99 | 232-151-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/24/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if
swallowed.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
Harmful if swallowed. Ingestion of large amounts of fluoride may
cause salivation, nausea, vomiting, abdominal pain, fever, labored
breathing. Inorganic fluorides can be harmful. Acute exposure to
fluorine compounds can lead to digestive tract burns, and abdominal
pain. Exposure to fluoride compounds can result in systemic toxic
effects on the heart, liver, and kidneys. It may also deplete
calcium levels in the body leading to hypocalcemia and death. Causes
gastrointestinal tract irritation. Contains fluoride. Fluoride can
reduce calcium levels leading to fatal hypocalcemia.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Chronic inhalation and ingestion may cause chronic fluoride
poisoning (fluorosis) characterized by weight loss, weakness,
anemia, brittle bones, and stiff joints. Chronic exposure to
fluoride compounds may cause systemic toxicity.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or alcohol-resistant
foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Avoid breathing dust.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Keep containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 7789-23-3:
United Kingdom, WEL - TWA: (listed as fluorides, inorganic): 2.5
mg/m3 TWA (as F)
United Kingdom, WEL - STEL: (listed as fluorides, inorganic): 6.2
mg/m3 STEL (as F)
United States OSHA: 2.5 mg/m3 TWA (as F) (listed under
Fluorides).2.5 mg/m3 TWA (as F) (listed under Fluorides).
Belgium - TWA: (listed as fluorides, inorganic): 2.5 mg/m3 VLE (a
France - VME: (listed as fluorides): 2.5 mg/m3 VME (as F)
Germany: (listed as fluorides): 2.5 mg/m3 VME (as F)
Malaysia: (listed as fluorides): 2.5 mg/m3 TWA (as F)
Netherlands: (listed as fluorides): 3.5 mg/m3 STEL (as F)
Russia: 1 mg/m3 TWA
Russia: 0.2 mg/m3 STEL
Spain: (listed as fluorides, inorganic): 2.5 mg/m3 VLA-ED (except
uranium hexafluoride, as F)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 1505 deg C @ 760 mm Hg
Freezing/Melting Point: 858 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: IN WATER: 92.3 G/100ML (18C)
Specific Gravity/Density: 2.4800 g/cm3
Molecular Formula: FK
Molecular Weight: 58.09
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Strong acids.
Hazardous Decomposition Products:
Hydrogen fluoride gas, oxides of potassium.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7789-23-3: TT0700000
LD50/LC50:
CAS# 7789-23-3: Oral, rat: LD50 = 245 mg/kg.
Carcinogenicity:
Potassium fluoride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: POTASSIUM FLUORIDE
Hazard Class: 6.1
UN Number: 1812
Packing Group: III
IMO
Shipping Name: POTASSIUM FLUORIDE, SOLID
Hazard Class: 6.1
UN Number: 1812
Packing Group: III
RID/ADR
Shipping Name: POTASSIUM FLUORIDE
Hazard Class: 6.1
UN Number: 1812
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7789-23-3: 1
Canada
CAS# 7789-23-3 is listed on Canada's DSL List.
CAS# 7789-23-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7789-23-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 9/22/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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bis(2-Ethylhexyl) hydrogen phosphate, 95% (titr.)
| 298-07-7 |
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Acriflavine Neutral, 13.3-15.8% Chlorine (on Dried Substance)
| 7782-50-5 |
|
p-Phenetidine, 98%
| 156-43-4 |
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Cryptocyanine, 99% (UV-VIS)
| 4727-50-8 |
|
Methyl anthranilate
| 134-20-3 |
|
Phenylmercuric Nitrate, 62.75-63.50% Mercury
| 8003-05-2 |
|
Formaldehyde, 37 wt% solution in water, stabilized with 10-15%
| 50-00-0 |
|
2,4-Dimethyl-3-pentanol, 99+%
| 600-36-2 |
|
4-Bromochlorobenzene, 99%
| 106-39-8 |
|
Beta-Alanine, 98%
| 107-95-9 |
|
Tin (IV) Oxide, 99.995%
| 18282-10-5 |
|
Ethanesulfonic Acid, 99%
| 594-45-6 |
|
5-Methyl-3-heptanone, 98.5+%
| 541-85-5 |
|
m-Phenetidine, 98%
| 621-33-0 |
|
4-Dimethylaminobenzaldehyde, 98%
| 100-10-7 |
|
4-Dimethylaminobenzaldehyde, reagent acs
| 100-10-7 |
|
1,1,2,2-Tetrachloroethane, 97%
| 79-34-5 |
|
p-Phenylenediamine, 99+%
| 106-50-3 |
|
Hemin, bovine, crystalline, 98%
| 16009-13-5 |
|
2,6-Dimethylphenol, P.A.
| 576-26-1 |
|
beta-Methylstyrene, 99% trans, stabilized with 0.01% BHT
| 128-37-0 |
|
Diethyl Sulfate, 99%
| 64-67-5 |
|
3,5-Diiodosalicylic Acid, 97% (HPLC)
| 133-91-5 |
|
2-Sulfobenzoic Acid Cyclic Anhydride, Tech
| 81-08-3 |
|
1,5-Pentanediol, 98%
| 111-29-5 |
|
Dibenzyl Phosphate, 99%
| 1623-08-1 |
|
2-Methyl-1-undecene, 99+%
| 18516-37-5 |
|
2-Nitrobenzoic acid, 85-90%,(gc)
| 552-16-9 |
|
Lithium acetylide, ethylenediamine complex 85-92%
| 6867-30-7 |
|
3,3',4,4'-Benzophenonetetracarboxylic dianhydride, 96%
| 2421-28-5 |
|
trans-Cinnamaldehyde, 99%
| 104-55-2 |
|
Fullerene C70, 99+% (HPLC)
| 115383-22-7 |
|
3-Bromo-1-propanol, 98%
| 627-18-9 |
|
3-Nitrobenzyl chloride, 97+% (gc)
| 619-23-8 |
|
2,6-Diethylaniline, 98%
| 579-66-8 |
|
1,1,1-Trichloroethane, 93.5%, stabilized with ca. 5% 1,4-dioxane
| 71-55-6 |
|
Trimethyl Phosphate, 97%
| 512-56-1 |
|
2-(5-Bromo-2-Pyridylazo)-5-(Diethylamino)- Phenol, 97%
| 14337-53-2 |
|
Beta-Cyclodextrin Hydrate, 99% (HPLC)
| 68168-23-0 |
|
3,3'-Diethylthiadicarbocyanine Iodide, 99% (UV-VIS)
| 514-73-8 |
|
4-Methyl-1-cyclohexene, 99%
| 591-47-9 |
|
Mesityl oxide, 99%, mixt.of alpha- and bet a isomers(ca.93% alpha)
| 141-79-7 |
|
Butyl acrylate, 99+%, stabilized with 20 ppm MEHQ
| 141-32-2 |
|
Methyl diphenylphosphine, 99%
| 1486-28-8 |
|
2,5-Di-tert-butylhydroquinone
| 88-58-4 |
|
Orcinol, Monohydrate (Pract), 95% (UV-Vis)
| 6153-39-5 |
|
1-Iodohexane, 98+%,stabilized over copper
| 638-45-9 |
|
Octadecane, 99+% (gc)
| 593-45-3 |
|
Pamoic Acid, Disodium Salt Monohydrate, 98% (UV-Vis)
| 6640-22-8 |
|
Potassium fluoride
| 7789-23-3 |
|
|