**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 2142-69-0 |2'-Bromoacetophenone | 98+ | 218-398-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
May cause respiratory tract irritation. Can produce delayed
pulmonary edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Remove contaminated clothing and wash before reuse. Avoid contact
with eyes, skin, and clothing. Keep container tightly closed. Avoid
ingestion and inhalation. Use with adequate ventilation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 2142-69-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear pale yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: > 112 deg C (> 233.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density: 1.476
Molecular Formula: C8H7BrO
Molecular Weight: 199.05
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 2142-69-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2'-Bromoacetophenone -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: II
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: II
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 2142-69-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 2142-69-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2142-69-0 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
8-Anilino-1-naphthalenesulfonic acid magnesium salt, 95% (uv-vis)
| 18108-68-4 |
|
Nonadecanoic acid, 99%
| 646-30-0 |
|
Hydrocinnamic Acid, 99+% (GC)
| 501-52-0 |
|
N-Methyldioctylamine, 98%
| 4455-26-9 |
|
n-Pentadecanoic acid, 99%
| 1002-84-2 |
|
Cesium hydroxide
| 21351-79-1 |
|
Triphenylmethyl mercaptan
| 3695-77-0 |
|
2,3,3',4'-Tetramethoxybenzophenone, 98%
| 50625-53-1 |
|
2,3,4-Trimethoxybenzaldehyde, 99%
| 2103-57-3 |
|
Dichloromalononitrile, 97%
| 13063-43-9 |
|
n-(5-Anilino-2,4-pentadienylidene)aniline hydrochloride, 98% (hplc)
| 1497-49-0 |
|
2,6-Dichlorobenzoic Acid, 98+%
| 50-30-6 |
|
3-Benzyloxy-4-Methoxybenzaldehyde, 98%
| 6346-05-0 |
|
2-Chloro-6-Fluorophenylacetonitrile, 98%
| 75279-55-9 |
|
3-Pyridinealdoxime, 98%
| 1193-92-6 |
|
Dibenzoylmethane, 98%
| 120-46-7 |
|
Lead telluride, 99.99%
| 1314-91-6 |
|
Benzoxazole, 99+%
| 273-53-0 |
|
DL-Asparagine Monohydrate, 98%
| 3130-87-8 |
|
2-Aminoresorcinol Hydrochloride, 97% (Titr.)
| 634-60-6 |
|
Sesame Oil
| 8008-74-0 |
|
N-1-(6-Indazolyl)-Sulfanilamide
| 13734-41-3 |
|
3-(4-Methoxyphenyl)-propionic acid, 98%
| 1929-29-9 |
|
1-Phenylnonane, 97%
| 1081-77-2 |
|
3,5-Dichloroanthranilic Acid, 97%
| 2789-92-6 |
|
N-(Tert-Butyl)Benzylamine, 99%
| 3378-72-1 |
|
2'-Bromoacetophenone, 98+%
| 2142-69-0 |
|
Chlorotrimethylsilane, 98%
| 75-77-4 |
|
Linalyl acetate,synthetic, 95-97%(gc)
| 115-95-7 |
|
5,7-Dibromo-8-hydroxyquinoline, 96%
| 521-74-4 |
|
Molecular Sieves, 5A, 4 to 8 Mesh
| 0-00-1 |
|
4-Chloro-3-Nitrobenzaldehyde, 97%
| 16588-34-4 |
|
2-Amino-5-Chlorobenzotrifluoride, 97%
| 445-03-4 |
|
Phosphorus Trichloride, 99% (Titr.)
| 7719-12-2 |
|
2-Methyl-1,3-pentadiene (cis/trans mixture 30/70),99%
| 1118-58-7 |
|
4-Bromo-3-Methylaniline, 99%
| 6933-10-4 |
|
Adipic Acid Monoethyl Ester, 98%
| 626-86-8 |
|
2-Guanidinobenzimidazole, 95%
| 5418-95-1 |
|
Diisobutyl phthalate, 99+% (GC)
| 84-69-5 |
|
Vinylacetic Acid, Tech., 90% Unstabilized
| 625-38-7 |
|
4-Propylbenzoyl Chloride, 99+% (Titr.)
| 52710-27-7 |
|
Hexanoic anhydride, 99%
| 2051-49-2 |
|
2-Hydroxy-6-methylpyridine-3-carboxylic acid, 98%
| 38116-61-9 |
|
5-Benzyloxygramine 99+%
| 1453-97-0 |
|
Ethyl 2-Methylacetoacetate, 98%
| 609-14-3 |
|
2-Fluoro-4-iodotoluene, 99+%
| 39998-81-7 |
|
Tris-(2-Methylallyl)-Amine, 99%
| 6321-40-0 |
|
Hydroxypivalyl hydroxypivalate
| 1115-20-4 |
|
DL-alpha-pinene, 97%
| 2437-95-8 |
|
FMOC-Glycine, 98%
| 29022-11-5 |
|
|