**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 4455-26-9 |N-Methyldioctylamine | 98% | 224-703-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause methemoglobinemia, cyanosis (bluish
discoloration of skin due to deficient oxygenation of the blood),
convulsions, and death.
Inhalation:
Causes respiratory tract irritation. May cause methemoglobinemia,
cyanosis (bluish discoloration of skin due to deficient oxygenation
of the blood), convulsions, tachycardia, dyspnea (labored
breathing), and death. Can produce delayed pulmonary edema.
Chronic:
May cause methemoglobinemia, which is characterized by
chocolate-brown colored blood, headache, weakness, dizziness, breath
shortness, cyanosis (bluish skin due to deficient oxygenation of
blood), rapid heart rate, unconsciousness and possible death. Effects
may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively. For methemoglobinemia,
administer oxygen alone or with Methylene Blue depending on the
methemoglobin concentration in the blood.
Antidote:
Methylene blue, alone or in combination with oxygen is indicated as
a treatment in nitrite induced methemoglobinemia.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Will burn
if involved in a fire. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas. Runoff
from fire control or dilution water may cause pollution.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Avoid contact with eyes, skin, and clothing. Keep
container tightly closed. Avoid ingestion and inhalation. Use with
adequate ventilation.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use process enclosure,
local exhaust ventilation, or other engineering controls to control
airborne levels.
Exposure Limits
CAS# 4455-26-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear very slight yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 162 - 165 deg C @ 15.00mm Hg
Freezing/Melting Point: -30.1 deg C
Autoignition Temperature: Not available.
Flash Point: > 109 deg C (> 228.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C17H37N
Molecular Weight: 255.49
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents, acids, acid chlorides, acid anhydrides,
chloroformates.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 4455-26-9: RG8235000
LD50/LC50:
CAS# 4455-26-9: Draize test, rabbit, skin: 500 uL/24H Severe.
Carcinogenicity:
N-Methyldioctylamine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 4455-26-9: No information available.
Canada
CAS# 4455-26-9 is listed on Canada's DSL List.
CAS# 4455-26-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4455-26-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
8-Anilino-1-naphthalenesulfonic acid magnesium salt, 95% (uv-vis)
| 18108-68-4 |
|
Nonadecanoic acid, 99%
| 646-30-0 |
|
Hydrocinnamic Acid, 99+% (GC)
| 501-52-0 |
|
N-Methyldioctylamine, 98%
| 4455-26-9 |
|
n-Pentadecanoic acid, 99%
| 1002-84-2 |
|
Cesium hydroxide
| 21351-79-1 |
|
Triphenylmethyl mercaptan
| 3695-77-0 |
|
2,3,3',4'-Tetramethoxybenzophenone, 98%
| 50625-53-1 |
|
2,3,4-Trimethoxybenzaldehyde, 99%
| 2103-57-3 |
|
Dichloromalononitrile, 97%
| 13063-43-9 |
|
n-(5-Anilino-2,4-pentadienylidene)aniline hydrochloride, 98% (hplc)
| 1497-49-0 |
|
2,6-Dichlorobenzoic Acid, 98+%
| 50-30-6 |
|
3-Benzyloxy-4-Methoxybenzaldehyde, 98%
| 6346-05-0 |
|
2-Chloro-6-Fluorophenylacetonitrile, 98%
| 75279-55-9 |
|
3-Pyridinealdoxime, 98%
| 1193-92-6 |
|
Dibenzoylmethane, 98%
| 120-46-7 |
|
Lead telluride, 99.99%
| 1314-91-6 |
|
Benzoxazole, 99+%
| 273-53-0 |
|
DL-Asparagine Monohydrate, 98%
| 3130-87-8 |
|
2-Aminoresorcinol Hydrochloride, 97% (Titr.)
| 634-60-6 |
|
Sesame Oil
| 8008-74-0 |
|
N-1-(6-Indazolyl)-Sulfanilamide
| 13734-41-3 |
|
3-(4-Methoxyphenyl)-propionic acid, 98%
| 1929-29-9 |
|
1-Phenylnonane, 97%
| 1081-77-2 |
|
3,5-Dichloroanthranilic Acid, 97%
| 2789-92-6 |
|
N-(Tert-Butyl)Benzylamine, 99%
| 3378-72-1 |
|
2'-Bromoacetophenone, 98+%
| 2142-69-0 |
|
Chlorotrimethylsilane, 98%
| 75-77-4 |
|
Linalyl acetate,synthetic, 95-97%(gc)
| 115-95-7 |
|
5,7-Dibromo-8-hydroxyquinoline, 96%
| 521-74-4 |
|
Molecular Sieves, 5A, 4 to 8 Mesh
| 0-00-1 |
|
4-Chloro-3-Nitrobenzaldehyde, 97%
| 16588-34-4 |
|
2-Amino-5-Chlorobenzotrifluoride, 97%
| 445-03-4 |
|
Phosphorus Trichloride, 99% (Titr.)
| 7719-12-2 |
|
2-Methyl-1,3-pentadiene (cis/trans mixture 30/70),99%
| 1118-58-7 |
|
4-Bromo-3-Methylaniline, 99%
| 6933-10-4 |
|
Adipic Acid Monoethyl Ester, 98%
| 626-86-8 |
|
2-Guanidinobenzimidazole, 95%
| 5418-95-1 |
|
Diisobutyl phthalate, 99+% (GC)
| 84-69-5 |
|
Vinylacetic Acid, Tech., 90% Unstabilized
| 625-38-7 |
|
4-Propylbenzoyl Chloride, 99+% (Titr.)
| 52710-27-7 |
|
Hexanoic anhydride, 99%
| 2051-49-2 |
|
2-Hydroxy-6-methylpyridine-3-carboxylic acid, 98%
| 38116-61-9 |
|
5-Benzyloxygramine 99+%
| 1453-97-0 |
|
Ethyl 2-Methylacetoacetate, 98%
| 609-14-3 |
|
2-Fluoro-4-iodotoluene, 99+%
| 39998-81-7 |
|
Tris-(2-Methylallyl)-Amine, 99%
| 6321-40-0 |
|
Hydroxypivalyl hydroxypivalate
| 1115-20-4 |
|
DL-alpha-pinene, 97%
| 2437-95-8 |
|
FMOC-Glycine, 98%
| 29022-11-5 |
|
|