**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 625-38-7 |Vinylacetic Acid, Tech., Unstabilized | 90% | 210-892-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Light sensitive.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause cyanosis of the extremities. May cause
skin rash (in milder cases), and cold and clammy skin with cyanosis
or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause cardiac disturbances. May cause central nervous
system effects. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead
to pulmonary edema. May cause cardiac abnormalities. May cause
systemic effects. Central nervous system effects, which appear to
predominate in acute cases are characterized by abnormal fatigue,
memory difficulties and dizziness.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Contact with metals may evolve
flammable hydrogen gas. Containers may explode when heated. Runoff
from fire control or dilution water may cause pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Do NOT get water
inside containers. For small fires, use dry chemical, carbon
dioxide, or water spray. For large fires, use dry chemical, carbon
dioxide, alcohol-resistant foam, or water spray.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Do not ingest or
inhale. Store protected from light. Discard contaminated shoes. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Keep container closed when not
in use. Store in a tightly closed container. Keep refrigerated.
(Store below 4C/39F.) Store protected from light.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 625-38-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 163 deg C @ 760.00mmHg
Freezing/Melting Point: -39 deg C
Autoignition Temperature: Not applicable.
Flash Point: 65 deg C ( 149.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble
Specific Gravity/Density: 1.0130g/cm3
Molecular Formula: C4H6O2
Molecular Weight: 86.09
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Bases, oxidizing agents, reducing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 625-38-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Vinylacetic Acid, Tech., Unstabilized -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3265
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 625-38-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 625-38-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 625-38-7 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #6 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
8-Anilino-1-naphthalenesulfonic acid magnesium salt, 95% (uv-vis)
| 18108-68-4 |
|
Nonadecanoic acid, 99%
| 646-30-0 |
|
Hydrocinnamic Acid, 99+% (GC)
| 501-52-0 |
|
N-Methyldioctylamine, 98%
| 4455-26-9 |
|
n-Pentadecanoic acid, 99%
| 1002-84-2 |
|
Cesium hydroxide
| 21351-79-1 |
|
Triphenylmethyl mercaptan
| 3695-77-0 |
|
2,3,3',4'-Tetramethoxybenzophenone, 98%
| 50625-53-1 |
|
2,3,4-Trimethoxybenzaldehyde, 99%
| 2103-57-3 |
|
Dichloromalononitrile, 97%
| 13063-43-9 |
|
n-(5-Anilino-2,4-pentadienylidene)aniline hydrochloride, 98% (hplc)
| 1497-49-0 |
|
2,6-Dichlorobenzoic Acid, 98+%
| 50-30-6 |
|
3-Benzyloxy-4-Methoxybenzaldehyde, 98%
| 6346-05-0 |
|
2-Chloro-6-Fluorophenylacetonitrile, 98%
| 75279-55-9 |
|
3-Pyridinealdoxime, 98%
| 1193-92-6 |
|
Dibenzoylmethane, 98%
| 120-46-7 |
|
Lead telluride, 99.99%
| 1314-91-6 |
|
Benzoxazole, 99+%
| 273-53-0 |
|
DL-Asparagine Monohydrate, 98%
| 3130-87-8 |
|
2-Aminoresorcinol Hydrochloride, 97% (Titr.)
| 634-60-6 |
|
Sesame Oil
| 8008-74-0 |
|
N-1-(6-Indazolyl)-Sulfanilamide
| 13734-41-3 |
|
3-(4-Methoxyphenyl)-propionic acid, 98%
| 1929-29-9 |
|
1-Phenylnonane, 97%
| 1081-77-2 |
|
3,5-Dichloroanthranilic Acid, 97%
| 2789-92-6 |
|
N-(Tert-Butyl)Benzylamine, 99%
| 3378-72-1 |
|
2'-Bromoacetophenone, 98+%
| 2142-69-0 |
|
Chlorotrimethylsilane, 98%
| 75-77-4 |
|
Linalyl acetate,synthetic, 95-97%(gc)
| 115-95-7 |
|
5,7-Dibromo-8-hydroxyquinoline, 96%
| 521-74-4 |
|
Molecular Sieves, 5A, 4 to 8 Mesh
| 0-00-1 |
|
4-Chloro-3-Nitrobenzaldehyde, 97%
| 16588-34-4 |
|
2-Amino-5-Chlorobenzotrifluoride, 97%
| 445-03-4 |
|
Phosphorus Trichloride, 99% (Titr.)
| 7719-12-2 |
|
2-Methyl-1,3-pentadiene (cis/trans mixture 30/70),99%
| 1118-58-7 |
|
4-Bromo-3-Methylaniline, 99%
| 6933-10-4 |
|
Adipic Acid Monoethyl Ester, 98%
| 626-86-8 |
|
2-Guanidinobenzimidazole, 95%
| 5418-95-1 |
|
Diisobutyl phthalate, 99+% (GC)
| 84-69-5 |
|
Vinylacetic Acid, Tech., 90% Unstabilized
| 625-38-7 |
|
4-Propylbenzoyl Chloride, 99+% (Titr.)
| 52710-27-7 |
|
Hexanoic anhydride, 99%
| 2051-49-2 |
|
2-Hydroxy-6-methylpyridine-3-carboxylic acid, 98%
| 38116-61-9 |
|
5-Benzyloxygramine 99+%
| 1453-97-0 |
|
Ethyl 2-Methylacetoacetate, 98%
| 609-14-3 |
|
2-Fluoro-4-iodotoluene, 99+%
| 39998-81-7 |
|
Tris-(2-Methylallyl)-Amine, 99%
| 6321-40-0 |
|
Hydroxypivalyl hydroxypivalate
| 1115-20-4 |
|
DL-alpha-pinene, 97%
| 2437-95-8 |
|
FMOC-Glycine, 98%
| 29022-11-5 |
|
|