isocyanic acid, methylenedi-p-phenylene ester; (4,4'diphenylmethane benzene, 1,1'-methylenebis(isocyanato-; (diphenylmethane diisocyanate polyisocyanate based on mdi
INTERNATIONAL PAINT INC -- INTERSHIELD PRORECO, PRA252
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Material Safety Data Sheet
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MSDS Num: CGRVZ
MSDS NAME: INTERSHIELD PRORECO, PRA252
Responsible Party
Name: INTERNATIONAL PAINT CO INC
Address: 2270 MORRIS AVE
City: UNION NJ 07083-0386
Info Phone: 908-964-2206
Emergency Phone Number: 800-854-6813;800-424-9300(CHEMTREC)
Published: Y
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Contractor Summary
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Name: INTERNATIONAL PAINT INC
Address: 6001 ANTOINE DR
City: HOUSTON TX 77091
Phone: 800-589-1267/800-854-6813
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Ingredients
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Cas: 101-68-8
RTECS #: NQ9350000
Name: ISOCYANIC ACID, METHYLENEDI-P-PHENYLENE ESTER; (4,4'DIPHENYLMETHANE
DIISOCYANATE (MDI)) (SARA 313)
% Wt: 25-50
OSHA PEL: C 0.02 PPM
ACGIH TLV: 0.005 PPM
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
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Cas: 26447-40-5
Name: BENZENE, 1,1'-METHYLENEBIS(ISOCYANATO-; (DIPHENYLMETHANE DIISOCYANATE
(2,2,2,4))
% Wt: 25-50
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
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Name: POLYISOCYANATE BASED ON MDI
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: INHALATION: CAUSES NOSE AND THROAT IRRITATION.
EYES: CAUSES IRRITATION. SKIN: CAUSES IRRITATION. INGESTION: HARMFUL IF
SWALLOWED. CHRONIC: NONE SPECIFIED BY MANUFACTURER.
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: IN ALL CASES OF DOUBT/WHEN SYMPS PERSIST, SEEK MED ATTN. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCON PERS. INHAL: REMOVE TO FRESH AIR. IF DISCOMFORT
IS PRESENT/BRTHG IS ABSENT, GET MED ATTN IMMED. EYES: FLUSH IMMED W/PLENTY
OF WATER FOR AT LEAST 15 MIN UNTIL IRRIT SUBSIDES. IF IRRIT PERSISTS, GET MED
ATTN. SKIN: FLUSH W/LGE AMTS OF WATER. USE SOAP IF AVAIL. REMOVE SEVERELY
CONTAM CLTHG (INCL SHOES) & WASH BEFORE REUSE. IF IRRIT PERSISTS, GET
MED ATTN. INGEST: DO NOT INDUCE VOMIT. KEEP AT REST. GET PROMPT MED ATTN.
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Handling and Disposal
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Spill Release Procedures: CONTAIN SPILLED LIQUID WITH SAND OR EARTH. DO NOT USE
COMBUSTIBLE MATERIALS SUCH AS SAWDUST. ABSORB SPILL WITH AN INERT MATERIAL
(E.G., DRY SAND OR EARTH), THEN PLACE IN A CHEMICAL WASTE CONTAINER.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS. DO NOT INCINERATE UNOPENED CONTAINERS.
Handling And Storage Precautions: KEEP CONTAINER CLOSED. LOOSEN CLOSURE
CAUTIOUSLY BEFORE OPENING. STORE IN A COOL, WELL-VENTILATED PLACE AWAY FROM
INCOMPATIBLE MATERIALS.
Other Precautions: KEEP AWAY FROM HEAT, SPARKS & FLAMES. PROTECT FROM
DIRECT SUNLIGHT. GROUND & BOND CONTAINERS WHEN TRANSFERRING MATERIALS.
EMPTY CONTAINERS MAY RETAIN HAZARDOUS PROPERTIES. FOLLOW ALL MSDS/LABEL
WARNIN GS, EVEN AFTER CONTAINER IS EMPTIED.
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Fire and Explosion Hazard Information
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Flash Point Text: 390F,199C
Extinguishing Media: FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). IN ABSENCE OF ELECTRICITY, A WATER SPRAY (FOG NOZZLE
PREFERRED) MAY BE USED TO COOL CONTAINERS.
Unusual Fire/Explosion Hazard: ISOLATE FROM HEAT, SPARKS, ELECTRICAL EQUIP
& OPEN FLAME. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.
DECOMP & COMBUSTION PRODUCTS MAY BE TOXIC.
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Control Measures
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Respiratory Protection: USE A RESPIRATOR APPROVED BY NIOSH AND IN ACCORDANCE
WITH 29CFR 1910.134 TO REMOVE PARTICULATES (AND VAPORS IF THERE IS
OVEREXPOSURE TO VAPORS GENERATED DURING THE PROCESSING OF THIS PRODUCT).
Ventilation: PROVIDE SUFFICIENT VENT, IN VOL & PATTERN, TO: A) KEEP TLV OF
HAZ INGS BELOW LIMS SPECIFIED; B) REMOVE VOLAT PRDCED DURING CURE &
DECOMP PRODS PRDCED (SUP DAT)
Protective Gloves: WEAR CHEMICAL RESISTANT GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA (FP N). USE BODY PROTECTION TO AVOID SKIN CONTACT.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: VENT: DURING WELDING/CUTTING ON SURFS COATED
W/THISPROD.
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Physical/Chemical Properties
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B.P. Text: 694F,368C
Vapor Density: HVR/AIR
Spec Gravity: 1.14
Evaporation Rate & Reference: SLOWER THAN ETHER
Appearance and Odor: NONE SPECIFIED BY MANUFACTURER
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: MAY PRODUCE HAZ FUMES WHEN HEATED TO
DECOMPOSITION AS IN WELDING. FUMES MAY PRODUCE CARBON DIOXIDE & CARBON
MONOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: INTERSHIELD PRORECO, PRA252
Company: INTERNATIONAL PAINT INC
Street: 6001 ANTOINE DR
City: HOUSTON TX
Zipcode: 77091
Health Emergency Phone: 800-854-6813;800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 03/23/1998
Status Code: C
Label Date: 03/23/1998
Origination Code: G
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: ACUTE: INHALATION: CAUSES NOSE AND THROAT IRRITATION.
EYES: CAUSES IRRITATION. SKIN: CAUSES IRRITATION. INGESTION: HARMFUL IF
SWALLOWED. CHRONIC: NONE SPECIFIED BY MANUFACTURER.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.