ICI PAINTS DIV GLIDDEN CO -- 5209, GLID-GUARD METAL SHOP PRIMER, (SUPDAT)
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Material Safety Data Sheet
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MSDS Num: CGRWL
MSDS NAME: 5209, GLID-GUARD METAL SHOP PRIMER, (SUPDAT)
Responsible Party
Name: ICI PAINTS DIV GLIDDEN CO
Address: 925 EUCLID AVE
City: CLEVELAND OH 44115
Info Phone: 800-545-2643
Emergency Phone Number: 800-545-2643
Published: Y
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Contractor Summary
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Name: ICI PAINTS DIV GLIDDEN
Address: 925 EUCLID AVE
City: CLEVELAND OH 44115
Phone: 800-545-2643
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Ingredients
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Cas: 1309-37-1
RTECS #: NO7400000
Name: IRON OXIDE
% Wt: 5-10
OSHA PEL: 10 MG/M3 (FE)
ACGIH TLV: 5 MG(FE)/M3 FUME, B2
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Cas: 64742-89-8
Name: VM & P NAPHTHA; (LIGHT ALIPHATIC SOLVENT NAPHTHA (PETROLEUM)).
LD50:(ORAL,RAT) >25 ML/KG
% Wt: 5-10
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
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Cas: 8052-41-3
RTECS #: WJ8925000
Name: STODDARD SOLVENT. LD50:(ORAL,RAT) 4.70 GM/KG
% Wt: 5-10
OSHA PEL: 500 PPM
ACGIH TLV: 100 PPM
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Cas: 64742-89-8
Name: VM & P NAPHTHA; (LIGHT ALIPHATIC SOLVENT NAPHTHA (PETROLEUM)).
LD50:(ORAL,RAT) 8 ML/KG
% Wt: 20-30
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
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Cas: 14808-60-7
RTECS #: VV7330000
Name: SILICA, CRYSTALLINE - QUARTZ; (QUARTZ)
% Wt: 0.1-1.0
OSHA PEL: SEE TABLE Z-3
ACGIH TLV: 0.1 MG/M3 RDUST
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Cas: 12135-86-3
Name: CALCIUM MAGNESIUM SILICATE PIGMENT; (ANTIGORITE)
% Wt: 1-5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
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Cas: 17068-78-9
Name: ANTHOPHYLLITE, NONASBESTIFORM
% Wt: 0.1-1.0
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
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Cas: 14807-96-6
RTECS #: WW2710000
Name: TALC (POWDER), CONTAINING NO ASBESTOS FIBERS
% Wt: 10-20
OSHA PEL: 2 MG/M3
ACGIH TLV: 2 MG/M3
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Cas: 14567-73-8
RTECS #: CI6560000
Name: TREMOLITE; (ASBESTOS, TREMOLITE)
% Wt: 10-20
OSHA PEL: 2 FIBERS/CC
ACGIH TLV: 2 FIBERS/CC, A1
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Cas: 108-88-3
RTECS #: XS5250000
Name: TOLUENE (SARA 313) (CERCLA). LD50:(ORAL,RAT) 5000 MG/KG
% Wt: 1-5
OSHA PEL: 200 PPM; Z-2
ACGIH TLV: S, 50 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 71-43-2
RTECS #: CY1400000
Name: BENZENE (SARA 313) (CERCLA). % (WT): 0.01-0.1
% Wt: <0.1
OSHA PEL: SEE 1910.1028
ACGIH TLV: 10 PPM; A2
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
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Cas: 78-83-1
RTECS #: NP9625000
Name: ISOBUTYL ALCOHOL (CERCLA). LD50:(ORAL,RAT) 2400 MG/KG
% Wt: 1-5
OSHA PEL: 100 PPM
ACGIH TLV: 50 PPM
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Health Hazards Data
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LD50 LC50 Mixture: SEE INGREDIENTS
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: YES
Effects of Exposure: TOLUENE APPEARS ON NAVY LISTING OF OCCUP CHEM REPROD
HAZARDS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST
HAZARD LIST INFO & SAFE HNDLG & EXPOS INFO (FP N). ACUTE: INHAL:
IRRIT OF RESP TRACT. PRLNGD INHAL MAY LEAD TO FATG, DROW, DIZZ AND/OR LT
HEAD, HDCH, UNCOORDINATION, NAUS, (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: SILICA, CRYSTALLINE-QUARTZ: IARC MONO, VOL 68,
1997: GROUP 1. NTP 7TH ANNUAL RPT ON CARCIN, 1994: ANTIC TO BE (SUPDAT)
Signs And Symptions Of Overexposure: HLTH HAZ: VOMIT, DIARR, COUGH, CNS
DEPRESS, RESP PROBLEMS, INTOXICATION, TIGHTNESS OF CHEST, METALLIC TASTE,
CONFUSN, ANESTH EFT/NARCOS, DFCLTY OF BRTHG, FEVER & CHILLS, DEHYDRATION,
LOSS OF CONSCIOUS NESS, RESP FAILURE, ASPHY, DEATH. SKIN:IRRIT. PRLNGD/RPTD
CONT CAN CAUSE DERM, DEFAT, BLISTERING. EYE: IRRIT.
Medical Cond Aggravated By Exposure: EYE, SKIN, RESP DISORDERS, LUNG DISORDERS,
ASTHMA-LIKE CONDITIONS, CARDIAC ABNORMALITIES, KIDNEY DISORDERS, LIVER
DISORDERS.
First Aid: INHAL: REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED BRTHG.
GET EMER MED ATTN. HAVE TRAINED PERSON GIVE OXYG IF NEC. GET MED HELP FOR ANY
BRTHG DFCLTY. SKIN: FLUSH W/WATER. THEN WASH THORO W/SOAP & WATER.
REMOVE CONTAMD CLTHG. WASH CONTAMD CLTHG BEFORE RE-USE. EYE: FLUSH IMMED W/LG
AMTS OF WATER, ESPECIALLY UNDER LIDS FOR @ LST 15 MINS. IF IRRIT/OTHER EFTS
PERSIST, OBTAIN MED TREATMENT.
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Handling and Disposal
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Spill Release Procedures: COMPLY W/ALL APPLIC HLTH & ENVIRONMENTAL REGS.
ELIM ALL SOURCES OF IGNITION, VENTILATE AREA. VENTILATE AREA W/EXPLO-PROOF
EQUIP. SPILLS MAY BE COLLECTED W/ABSORB MATLS. USE NON-SPK TOOLS. EVACUATE
ALL UNNEC PERS. PLACE COLLECTED MATERIAL IN
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
AVOID DISCHARGE TO NATURAL WATERS.
Handling And Storage Precautions: STORE BELOW 80F(27C). KEEP AWAY FROM HEAT,
SPKS & OPEN FLAME. USE ONLY W/ADEQ VENT. DO NOT TAKE INTERNALLY. KEEP OUT
OF REACH OF CHILDREN.
Other Precautions: AVOID CONT W/SKIN & EYES, & BRTHG OF VAPS. KEEP
CNTNRS TIGHTLY CLSD & UPRIGHT WHEN NOT IN USE. AVOID CNDTNS WHICH RSLT IN
FORMATION OF INHALABLE PARTICLES SUCH AS SPRAYING/ABRADING (SANDING) PAINTED
S URFS. IF SUCH CNTNS CANNOT BE
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Fire and Explosion Hazard Information
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Flash Point Text: 42.0F,5.6C
Lower Limits: FCC 1.3%
Upper Limits: 13.3%
Extinguishing Media: DRY CHEMICAL OR FOAM. WATER FOG. CARBON DIOXIDE.
Fire Fighting Procedures: NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N). WATER
MAY BE USED TO COOL & PROTECT EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard: CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME
HEAT/FIRE. VAPS MAY IGNITE EXPLO @ AMBIENT TEMPS. VAPS ARE HVR/AIR & MAY
TRAVEL LONG DIST TO SOURCE OF (SUPDA
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Control Measures
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Respiratory Protection: CONTROL ENVIRONMENTAL CONCS BELOW APPLIC STDS. WHERE
RESP PROT IS REQD, USE ONLY NIOSH APPRVD RESPIRATORS I/A/W OSHA STD 29 CFR
1910.134.
Ventilation: PROVIDE DILUTION VENT/LOC EXHAUST TO PVNT BUILD-UP OF VAPS. USE
EXPLOSION-PROOF EQUIP. USE NON-SPARKING EQUIPMENT.
Protective Gloves: IMPERVIOUS GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N).
IMPERVIOUS CLOTHING, APRON, BOOTS.
Work Hygienic Practices: WASH HANDS THORO AFTER HANDLG, ESPECIALLY BEFORE
EATING/SMOKING. ( ( /X
Supplemental Safety and Health: + &! [ (%[Y 6 =T M Y UP J E
8F@ Q Y A R 6Q D ) A L 4V * L S>
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Physical/Chemical Properties
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B.P. Text: >176F,
Spec Gravity: >80C 1.106
PH: 5.65 N
Evaporation Rate & Reference: NOT KNOWN
Solubility in Water: NOT KNOWN
Appearance and Odor: NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume: 7
Corrosion Rate: /K N/K
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Reactivity Data
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Stability Condition To Avoid: YESELEVATED TEMPS, CONT W/OXIDIZING AGENT,
SPARKS, OPEN FLAME. IGNITION SOURCES.
Materials To Avoid: OXIDIZERS, ACIDS, BASES, AMINES, VINYL POLYMERS.
Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE, ALDEHYDES,
TOXIC GASES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: 5209, GLID-GUARD METAL SHOP PRIMER, (SUPDAT)
Assigned IND: Y
Company: ICI PAINTS DIV GLIDDEN
Street: 925 EUCLID AVE
City: CLEVELAND OH
Zipcode: 44115
Health Emergency Phone: 800-545-2643
Label Required IND: Y
Date Of Label Review: 03/26/1998
Status Code: C
Label Date: 03/26/1998
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: ACUTE: INHAL: IRRIT OF RESP TRACT. PRLNGD INHAL MAY
LEAD TO FATG, DROW, DIZZ AND/OR LT HEAD, HDCH, UNCOORDINATION, NAUS, VOMIT,
UNCON, RESP FAILURE, ASPHYXIATION, DEATH. SKIN: IRRIT, DERM, BLISTERING,
DEFATTING. EYES: IRRITATION, BLURRED VISION, TEARING, REDNESS, CORNEAL
INJURY. INGEST: ASPIR HAZ-MAY CAUSE LUNG INFLAMMATION & DAMAGE. GI
IRRITATION, NAUS, VOMIT, DIARRHEA, CNS DEPRESS. CHRONIC: CANC ER HAZARD.
CONTAINS BENZENE WHICH IS LISTED AS A HUMAN BLOOD CARCIN AND CRYSTALLINE
SILICA QUARTZ WHICH IS LISTED AS A HUMAN LUNG CARCINOGEN (FP N). TOLUENE
APPEARS ON NAVY OCCUP CHEMICAL REPRODUCTIVE HAZARDS LIST (FP N).
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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