ICI PAINTS DIV GLIDDEN CO -- GLID-GUARD VINYL-GUARD WHITE, 5516
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Material Safety Data Sheet
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MSDS Num: CGRWP
MSDS NAME: GLID-GUARD VINYL-GUARD WHITE, 5516
Responsible Party
Name: ICI PAINTS DIV GLIDDEN CO
Address: 925 EUCLID AVE
City: CLEVELAND OH 44115
Info Phone: 800-545-2643
Emergency Phone Number: 800-545-2643
Published: Y
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Contractor Summary
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Name: ICI PAINTS DIV GLIDDEN
Address: 925 EUCLID AVE
City: CLEVELAND OH 44115
Phone: 800-545-2643
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Ingredients
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Cas: 61788-76-9
Name: CHLORINATED PARAFFIN
% Wt: 1-5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
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Cas: 9003-22-9
RTECS #: AK0950000
Name: ACETIC ACID, VINYL ESTER, POLYMER WITH CHLOROETHYLENE; (VINYL
CHLORIDE/VINYL ACETATE COPOLYMER)
% Wt: 5-10
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
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Cas: 68611-44-9
Name: SILANE, DICHLORODIMETHYL-, REACTION PRODUCTS WITH SILICA. LD50:(ORAL,RAT)
>5000 MG/KG
% Wt: 1-5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
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Cas: 12001-26-2
RTECS #: VV8760000
Name: SILICATE, MICA; (MICA - GROUP MINERALS)
% Wt: 5-10
OSHA PEL: 20 MPPCF; Z-3
ACGIH TLV: 3 MG/M3 RDUST
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Cas: 108-88-3
RTECS #: XS5250000
Name: TOLUENE (SARA 313) (CERCLA). LD50:(ORAL,RAT) 5000 MG/KG
% Wt: 5-10
OSHA PEL: 200 PPM; Z-2
ACGIH TLV: S, 50 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 1330-20-7
RTECS #: ZE2100000
Name: XYLENE (SARA 313) (CERCLA). LD50:(ORAL,RAT) 4300 MG/KG
% Wt: 20-30
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM/150 STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 108-10-1
RTECS #: SA9275000
Name: 2-PENTANONE, 4-METHYL-; (METHYL ISOBUTYL KETONE) (SARA 313) (CERCLA).
LD50:(ORA,RAT) 1600 MG/KG
% Wt: 20-30
OSHA PEL: 100 PPM
ACGIH TLV: 50 PPM/75 STEL
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Cas: 110-43-0
RTECS #: MJ5075000
Name: 2-HEPTANONE; (METHYL N-AMYL KETONE). LD50:(ORAL,RAT) 1600 MG/KG
% Wt: 1-5
OSHA PEL: 100 PPM
ACGIH TLV: 50 PPM
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Cas: 108-05-4
RTECS #: AK0875000
Name: VINYL ACETATE (SARA 302/313) (CERCLA)
% Wt: 0.1-1.0
OSHA PEL: 10 PPM
ACGIH TLV: 10 PPM/15, A3 STEL
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Cas: 71-43-2
RTECS #: CY1400000
Name: BENZENE (SARA 313) (CERCLA). % (WT): 0.01-0.1
% Wt: <0.1
OSHA PEL: SEE 1910.1028
ACGIH TLV: 10 PPM; A2
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
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Cas: 100-41-4
RTECS #: DA0700000
Name: ETHYL BENZENE (SARA 313). LD50:(ORAL,RAT) 3500 MG/KG
% Wt: 1-5
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM/125 STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 13463-67-7
RTECS #: XR2275000
Name: TITANIUM OXIDE; (TITANIUM DIOXIDE)
% Wt: 10-20
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
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Cas: 9005-09-8
Name: VINYL CHLORIDE RESIN; (2-BUTENEDIOIC ACID(Z)-, POLYMER WITH CHLOROETHENE
AND ETHYENYL ACETATE)
% Wt: 5-10
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
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Name: SUPDAT: OF MATL INTO LUNGS, MOUTH & THROAT IRRIT, HDCH, NAUS, VOMIT,
DIARR, GI DISTURB, CNS DEPRESS, ANESTH EFT/
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Name: ING 14: NARCOS. CNTNS CHEM THAT IS MOD TOX BY INGEST. OTHER EFTS OF
OVEREXP MAY INCL TOX TO LIVER, KIDNEY, CNS,
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Name: ING 15: BLOOD, HEART. MAY BE ABSORBED THRU SKIN. NOTICE - RPTS HAVE ASSOC
RPTD & PRLNGD OCCUP OVEREXP TO SOLVS
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Name: ING 16: W/PERM BRAIN & NERV SYS DMG. INTENTIONAL MISUSE BY DELIB CONC
& INHALING CONTENTS MAY BE HARMFUL/FATAL.
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Name: ING 17: TREATMENT RELATED NASAL TUMORS WERE OBSERVED IN RATS & MICE
EXPOS TO VINYL ACETATE VIA INHAL @ 600 PPM
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Name: ING 18: FOR 2 YRS. DELIB INHAL OF TOLUENE HAS BEEN ASSOC W/NEONATAL EFTS
IN HUMANS. FOR MORE SPECIFIC HEALTH
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Name: ING 19: HAZARDS CONT NEHC (FP N).
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Name: FIRST AID PROC: IF IRRIT OCCURS, CONSULT PHYS. EYE: FLUSH IMMED W/LG AMTS
OF WATER, ESPECIALLY UNDER LIDS FOR @
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Name: ING 21: LST 15 MINS. IF IRRIT/OTHER EFTS PERSIST, OBTAIN MED TREATMENT.
INGEST:IF SWALLOWED, OBTAIN MED TREATMENT IMMED.
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Name: SPILL PROC: CNTNR. COMPLETE PERSONAL PROT EQUIP MUST BE USED DURING
CLEANUP. FOR MORE INFORMATION CONT NEHC (FP N).
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Name: OTHER PREC: PAINTED SURF. EMPTY CNTNRS MAY CNTN HAZ RESIDUES. GROUND
EQUIP WHEN TRANSFERRING TO PVNT ACCUM OF
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Name: ING 24: STATIC CHARGE. FOR MORE INFORMATION CONTACT NEHC (FP N).
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Health Hazards Data
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LD50 LC50 Mixture: SEE INGREDIENTS
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: YES
Effects of Exposure: TOLUENE APPEARS ON THE NAVY LISTING OF OCCUP CHEM REPROD
HAZARDS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST
HAZARD LIST INFO & SAFE HNDLG & EXPOS INFO (FP N). ACUTE: INHAL: IR
RIT OF RESP TRACT. PRLNGD INHAL MAY LEAD TO MUC MEMB IRRIT, FATG, DROW, DIZZ
AND/OR LT HEAD, HEADACHE, (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: BENZENE: IARC MONO, SUPP, VOL 7, PG 120, 1987:
GROUP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994: KNOWN TO BE CARCIN.(SUPDAT)
Signs And Symptions Of Overexposure: HLTH HAZ: UNCOORD, NAUS, VOMIT, COUGH, CNS
DEPRESS, RESP PROBLEMS, INTOXICATION, TIGHTNESS OF CHEST, CONFUSN, ANESTH
EFT/NARCOS, DFCLTY OF BRTHG, LIVER DMG, KIDNEY DMG, PNEUMOCONIOSIS, LOSS OF
CONSCIO USNESS, RESP FAILURE, ASPHY, DEATH. SKIN: IRRIT. PRLNGD/RPTD CONT CAN
CAUSE DERM, DEFAT, BLISTERING. EYE: IRRIT.(SUPDAT)
Medical Cond Aggravated By Exposure: EYE, SKIN, RESPIRATORY DISORDERS,
ASTHMA-LIKE CONDITIONS, CARDIAC ABNORMALITIES, KIDNEY DISORDERS, LIVER
DISORDERS.
First Aid: INHAL: REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED BRTHG.
GET EMER MED ATTN. HAVE TRAINED PERSON GIVE OXYG IF NEC. GET MED HELP FOR ANY
BRTHG DFCLTY. REMOVE TO FRESH AIR IF INHAL CAUSES EYE WATER ING, HDCHS,
DIZZ/OTHER DISCOMFORT. GET MED ATTN IF DISCOMFORT/IRRIT PERSISTS. SKIN: FLUSH
W/WATER. THEN WASH THORO W/SOAP & WATER. REMOVE CONTAMD CLTHG. WASH
CONTAMD CLTHG BEFORE RE-USE.
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Handling and Disposal
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Spill Release Procedures: COMPLY W/ALL APPLIC HLTH & ENVIRONMENTAL REGS.
ELIM ALL SOURCES OF IGNIT. VENTILATE AREA. VENTILATE AREA W/EXPLO-PROOF
EQUIP. SPILLS MAY BE COLLECTED W/ABSORB MATLS. USE NON-SPK TOOLS. EVACUATE
ALL UN NEC PERS. PLACE COLLECTED MATL IN PROPER
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL,
STATE AND LOCAL REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS.
Handling And Storage Precautions: STORE <80F(27C). KEEP AWAY FROM HEAT, SPKS
& OPEN FLAME. KEEP AWAY FROM DIRECT SUNLIGHT, HEAT & ALL SOURCES OF
IGNIT. USE ONLY W/ADEQ VENT.
Other Precautions: DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. AVOID
CONT W/SKIN & EYES, & BRTHG OF VAPS. KEEP CNTNRS TIGHTLY CLSD &
UPRIGHT WHEN NOT IN USE. AVOID CNDTNS RSLTG IN FORM OF INHALABLE PARTICLES
IE, SPRAYING/ABRADING (SANDING)
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Fire and Explosion Hazard Information
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Flash Point Method: SCC
Flash Point Text: 40.0F,4.4C
Lower Limits: 1.3%
Upper Limits: 8.0%
Extinguishing Media: DRY CHEMICAL OR FOAM, WATER FOG, CARBON DIOXIDE.
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). WATER MAY BE USED TO COOL & PROTECT EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard: CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME
HEAT/FIRE. VAPS MAY IGNITE EXPLO @ AMBIENT TEMPS. VAPS ARE HVR/AIR & MAY
TRAVEL LONG DIST TO SOURCE (SUPDAT)
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Control Measures
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Respiratory Protection: CTL ENVIRONMENTAL CONCS BELOW APPLIC STDS. WHERE RESP
PROT IS REQD, USE ONLY NIOSH APPRVD RESPIRATORS IN ACCORDANCE WITH OSHA
STANDARD 29 CFR 1910.134.
Ventilation: PROVIDE DILUTION VENT/LOC EXHAUST TO PREVENT BUILD-UP OF VAPS. USE
EXPLO-PROOF EQUIP. USE NON-SPARKING EQUIPMENT.
Protective Gloves: IMPERVIOUS GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N).
IMPERVIOUS CLOTHING, APRON, BOOTS.
Work Hygienic Practices: WASH HANDS THORO AFTER HANDLING, ESPECIALLY BEFORE
EATING OR SMOKING.
Supplemental Safety and Health: EXPLO HAZ: TO IGNIT & FLASH BACK. MAY
DECOMPOSE UNDER FIRE CNDTNS EMITTING IRRITANT AND/OR TOXIC GASES. EXPLAN OF
CARCIN: OSHA REG 29 CFR 1910.1028. EFTS OF OVEREXP: PRLNGD/RPTD CONT CAN
CAUSE CONJ, B LURRED VISION, TEARING, REDNESS, SEV IRRIT, CORNEAL INJURY.
INGEST: MAY CAUSE LUNG INFLAMM & DMG DUE TO ASPIR
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Physical/Chemical Properties
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B.P. Text: >163F,>73C
Spec Gravity: 1.062
Evaporation Rate & Reference: NOT KNOWN
Solubility in Water: NOT KNOWN
Appearance and Odor: WHITE LIQUID.
Percent Volatiles by Volume: 78.26
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: ELEVATED TEMPS, CONT W/OXIDIZING AGENT, CONT
W/ALUMINUM OR ZINC, SPARKS, OPEN FLAME. IGNITION SOURCES.
Materials To Avoid: OXIDIZERS, ACIDS, REDUCING AGENTS, BASES, AMINES, ALUMINUM,
ZINC, VINYL POLYMERS, MAGNESIUM, SODIUM, POTASSIUM.
Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE, OXYGEN,
HYDROGEN CHLORIDE, UNIDENTIFIED ORGANIC COMPOUNDS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: GLID-GUARD VINYL-GUARD WHITE, 5516
Assigned IND: Y
Company: ICI PAINTS DIV GLIDDEN
Street: 925 EUCLID AVE
City: CLEVELAND OH
Zipcode: 44115
Health Emergency Phone: 800-545-2643
Label Required IND: Y
Date Of Label Review: 03/13/1998
Status Code: C
Label Date: 03/13/1998
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE. ACUTE: INHAL: IRRITATION OF RESPIRATORY
TRACT. PROLONGED INHAL MAY LEAD TO FATIGUE, DROWSINESS, DIZZINESS AND/OR LT
HEAD, HEADACHE, UNCOORDINATION, NAUSEA, VOMITING, UNCON, RESPIRATORY FAIL
URE, ASPHYXIATION, DEATH. SKIN: IRRITATION, DERMATITIS, BLISTERING,
DEFATTING, EYES: IRRITATION, BLURRED VISION, TEARING, REDNESS, CORNEAL
INJURY. INGEST: ASPIRATION HAZARD - MAY CAUSE LUNG INFLAMMATI ON &
DAMAGE. GI IRRITATION, NAUSEA, VOMITING, DIARRHEA, CNS DEPRESSION. CHRONIC:
CANCER HAZARD. CONTAINS BENZENE WHICH IS LISTED AS A HUMAN BLOOD CARCIN (FP
N). TOLUENE APPEARS ON NAVY OCCUPATIONAL CH EMICAL REPRODUCTIVE HAZARDS LIST
(FP N).
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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