| MSDS | : | G-G EPOXY HIGH BUILD CONVERTER, 5556 | | CAS | : | 121888-68-4
68410-23-1
1332-58-7
67-63-0
108-88-3
71-43-2
112-24-3 | | NAME | : | quaternary ammonium compounds, benzyl(hydrogenated tallow alkly)dimethyl,
ing 1: (rheological additive). ld50: (oral,rat) 5 gm/kg
polyamide resin; (fatty acids, c18-unsatd, dimers, reaction products with
ing 3: ld50:(oral,rat) 8 gm/kg
clay (kaolin); (kaolin)
isopropyl alcohol (sara 313). ld50:(oral,rat) 4720 mg/kg
toluene (sara 313) (cercla). ld50:(oral,rat) 5000 mg/kg
benzene (sara 313) (cercla). % (wt): 0.01-0.1
triethylenetetramine
supdat: component(s) of prod which may cause cns depress, liver dmg,
ing 10: can cause blurred vision, tearing, redness, sev irrit/burns,
ing 11:lung inflamm & dmg due to aspir of matl into lungs, drow,
ing 12:throat, stom, repro sys dmg, loss of consciousness. supp hlth
ing 13: triethylenetetramine has demonstrated weak mutagenic activity in
ing 14: -fetal tox & fetal malformations when fed to rats.
ing 15: life-time mouse skin painting studies. other efts of overexp may
ing 16: heart. may be absorbed thru skin. notice - rpts have assoc rptd
ing 17: brain & nerv sys dmg. delib conc & inhaling contents may
ing 18: health hazards cont nehc (fp n).
first aid proc: 15 mins. if irrit/other efts persist, obtain med
ing 20: obtain medical treatment immediately.
spill proc: must be used during cleanup. lg spills - shut off leak if
ing 22: storage or salvage vessels. for more information cont nehc (fp
other prec: avoided, use approp niosh apprvd resp prot as directed under
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ICI PAINTS DIV GLIDDEN CO -- G-G EPOXY HIGH BUILD CONVERTER, 5556
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Material Safety Data Sheet
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MSDS Num: CGRWQ
MSDS NAME: G-G EPOXY HIGH BUILD CONVERTER, 5556
Responsible Party
Name: ICI PAINTS DIV GLIDDEN CO
Address: 925 EUCLID AVE
City: CLEVELAND OH 44115
Info Phone: 800-545-2643
Emergency Phone Number: 800-545-2643
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: ICI PAINTS DIV GLIDDEN
Address: 925 EUCLID AVE
City: CLEVELAND OH 44115
Phone: 800-545-2643
=======================================================
Ingredients
=======================================================
Cas: 121888-68-4
Name: QUATERNARY AMMONIUM COMPOUNDS, BENZYL(HYDROGENATED TALLOW ALKLY)DIMETHYL,
STEARATES, SALTS WITH BENTONITE;
% Wt: 1-5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Name: ING 1: (RHEOLOGICAL ADDITIVE). LD50: (ORAL,RAT) 5 GM/KG
-----------------------------
Cas: 68410-23-1
Name: POLYAMIDE RESIN; (FATTY ACIDS, C18-UNSATD, DIMERS, REACTION PRODUCTS WITH
POLYETHYLENEPOLYAMINES
% Wt: 10-20
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Name: ING 3: LD50:(ORAL,RAT) 8 GM/KG
-----------------------------
Cas: 1332-58-7
RTECS #: GF1670500
Name: CLAY (KAOLIN); (KAOLIN)
% Wt: 40-50
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 2 MG/M3 TDUST
------------------------------
Cas: 67-63-0
RTECS #: NT8050000
Name: ISOPROPYL ALCOHOL (SARA 313). LD50:(ORAL,RAT) 4720 MG/KG
% Wt: 5-10
OSHA PEL: 400 PPM
ACGIH TLV: 400 PPM/500 STEL
------------------------------
Cas: 108-88-3
RTECS #: XS5250000
Name: TOLUENE (SARA 313) (CERCLA). LD50:(ORAL,RAT) 5000 MG/KG
% Wt: 20-30
OSHA PEL: 200 PPM; Z-2
ACGIH TLV: S, 50 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 71-43-2
RTECS #: CY1400000
Name: BENZENE (SARA 313) (CERCLA). % (WT): 0.01-0.1
% Wt: <0.1
OSHA PEL: SEE 1910.1028
ACGIH TLV: 10 PPM; A2
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
------------------------------
Cas: 112-24-3
RTECS #: YE6650000
Name: TRIETHYLENETETRAMINE
% Wt: 1-5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Name: SUPDAT: COMPONENT(S) OF PROD WHICH MAY CAUSE CNS DEPRESS, LIVER DMG,
KIDNEY DMG. EYE: IRRIT. PRLNGD/RPTD CONT
-----------------------------
Name: ING 10: CAN CAUSE BLURRED VISION, TEARING, REDNESS, SEV IRRIT/BURNS,
CORNEAL INJURY, BLNDNESS. INGEST: MAY CAUSE
-----------------------------
Name: ING 11:LUNG INFLAMM & DMG DUE TO ASPIR OF MATL INTO LUNGS, DROW,
NAUS, VOMIT, DIARR, GI DISTURB, BURNS OF MOUTH,
-----------------------------
Name: ING 12:THROAT, STOM, REPRO SYS DMG, LOSS OF CONSCIOUSNESS. SUPP HLTH
INFO:CNTNS CHEM THAT IS MOD TOX BY INGEST.
-----------------------------
Name: ING 13: TRIETHYLENETETRAMINE HAS DEMONSTRATED WEAK MUTAGENIC ACTIVITY IN
STD IN VITRO TESTS, & HAS CAUSED EMBRYO
-----------------------------
Name: ING 14: -FETAL TOX & FETAL MALFORMATIONS WHEN FED TO RATS.
TRIETHYLENETETRAMINE DID NOT EXHIBIT CARCIN POTNTL IN
-----------------------------
Name: ING 15: LIFE-TIME MOUSE SKIN PAINTING STUDIES. OTHER EFTS OF OVEREXP MAY
INCL TOX TO LIVER, KIDNEY, CNS, BLOOD,
-----------------------------
Name: ING 16: HEART. MAY BE ABSORBED THRU SKIN. NOTICE - RPTS HAVE ASSOC RPTD
& PRLNGD OCCUP OVEREXP TO SOLVS W/PERM
-----------------------------
Name: ING 17: BRAIN & NERV SYS DMG. DELIB CONC & INHALING CONTENTS MAY
BE HARMFUL/FATAL. FOR MORE SPECIFIC
-----------------------------
Name: ING 18: HEALTH HAZARDS CONT NEHC (FP N).
-----------------------------
Name: FIRST AID PROC: 15 MINS. IF IRRIT/OTHER EFTS PERSIST, OBTAIN MED
TREATMENT IMMEDIATELY. INGEST: IF SWALLOWED,
-----------------------------
Name: ING 20: OBTAIN MEDICAL TREATMENT IMMEDIATELY.
-----------------------------
Name: SPILL PROC: MUST BE USED DURING CLEANUP. LG SPILLS - SHUT OFF LEAK IF
SAFE TO DO SO. DIKE & CNTN SPILL. PUMP TO
-----------------------------
Name: ING 22: STORAGE OR SALVAGE VESSELS. FOR MORE INFORMATION CONT NEHC (FP
N).
-----------------------------
Name: OTHER PREC: AVOIDED, USE APPROP NIOSH APPRVD RESP PROT AS DIRECTED UNDER
SPEC PROT INFO. FOR MORE INFO CONT NEHC (FP N).
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Health Hazards Data
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LD50 LC50 Mixture: SEE INGREDIENTS
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: YES
Effects of Exposure: TOLUENE APPEARS ON THE NAVY LISTING OF OCCUP CHEM REPROD
HAZARDS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST
HAZARD LIST INFO & SAFE HNDLG & EXPOS INFO (FP N). ACUTE: IRRIT OF
RESP TRACT. PRLNGD INHAL MAY LEAD TO MUC MEMB IRRIT, FATG, DROWSINESS, DIZZ
AND/OR LT HEAD, HEADACHE, (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: BENZENE: IARC MONO, SUPP, VOL 7, PG 120, 1987:
GROUP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994: KNOWN TO BE CARCIN.(SUPDAT)
Signs And Symptions Of Overexposure: HLTH HAZ: UNCOORDINATION, NAUS, VOMIT,
COUGH, CNS DEPRESS, RESP PROBLEMS, INTOXICATION, CONFUSN, ANESTH EFT/NARCOS,
DFCLTY OF BRTHG, SEV LUNG IRRIT/DMG, LOSS OF CONSCIOUSNESS, RESP FAILURE,
ASPHY, DEA TH. POSS SENSIT TO RESP TRACT. SKIN: IRRIT, PRLNGD/RPTD CONT CAN
CAUSE DERM, DEFAT, SEV SKIN IRRIT/BURNS. POSS (SUPDAT)
Medical Cond Aggravated By Exposure: EYE, SKIN, RESPIRATORY DISORDERS, LUNG
DISORDERS, ASTHMA-LIKE CONDITIONS, CARDIAC ABNORMALITIES, KIDNEY DISORDERS,
LIVER DISORDERS.
First Aid: INHAL: REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED BRTHG.
GET EMER MED ATTN. HAVE TRAINED PERSON GIVE OXYG IF NEC. GET MED HELP FOR ANY
BRTHG DFCLTY. SKIN: FLUSH W/WATER. THEN WASH THORO W/SOAP & WATER.
REMOVE CONTAMD CLTHG. WASH CONTAMD CLTHG BEFORE RE-USE. DISPOSE OF CONTAMD
LEATHER ITEMS, SUCH AS SHOES & BELTS. EYE: FLUSH IMMED W/LG AMTS OF
WATER, ESPECIALLY UNDER LIDS FOR @ LST
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Handling and Disposal
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Spill Release Procedures: COMPLY W/ALL APPLIC HLTH & ENVIRONMENTAL REGS.
ELIM ALL SOURCES OF IGNIT. VENTILATE AREA. VENTILATE AREA W/EXPLO-PROOF
EQUIP. SPILLS MAY BE COLLECTED W/ABSORB MATLS. USE NON-SPK TOOLS. EVACUATE
ALL UN NEC PERS. COMPLETE PERSONAL PROT EQUIP
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE I/A/W ALL APPLICABLE FEDERAL, STATE AND LOCAL
REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS.
Handling And Storage Precautions: STORE <80F(27C). KEEP AWAY FROM HEAT, SPKS
& OPEN FLAME. USE ONLY W/ADEQ VENT. DO NOT TAKE INTERNALLY. KEEP OUT OF
REACH OF CHILDREN.
Other Precautions: AVOID CONT W/SKIN & EYES, & BRTHG OF VAPS. KEEP
CNTNRS TIGHTLY CLSD & UPRIGHT WHEN NOT IN USE. AVOID CNDTNS WHICH RSLT IN
FORMATION OF INHALABLE PARTICLES SUCH AS SPRAYING/ABRADING (SANDING) PAINTED
S URFS. IF SUCH CNDTNS CANNOT BE
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Fire and Explosion Hazard Information
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Flash Point Method: SCC
Flash Point Text: 42.0F,5.6C
Lower Limits: 2.0%
Upper Limits: 12.0%
Extinguishing Media: DRY CHEMICAL OR FOAM, WATER FOG, CARBIN DIOXIDE.
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). WATER MAY BE USED TO COOL & PROTECT EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard: CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME
HEAT/FIRE. VAPS MAY IGNITE EXPLO @ AMBIENT TEMPS. VAPS ARE HVR/AIR & MAY
TRAVEL LONG DIST TO IGNIT SOURCE (SUPDAT)
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Control Measures
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Respiratory Protection: CTL ENVIRONMENTAL CONCS BELOW APPLIC STDS. WHERE RESP
PROT IS REQD, USE ONLY NIOSH APPROVED RESPIRATORS I/A/W OSHA STANDARD 29 CFR
1910.134.
Ventilation: PROVIDE DILUTION VENT OR LOCAL EXHAUST TO PREVENT BUILD-UP OF
VAPORS. USE EXPLO-PROOF EQUIP. USE NON-SPARKING EQUIP.
Protective Gloves: IMPERIVOUS GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N).
IMPERVIOUS CLOTHING.
Work Hygienic Practices: WASH HANDS THOROUGHLY AFTER HANDLING, ESPECIALLY
BEFORE EATING OR SMOKING.
Supplemental Safety and Health: EXPLO HAZ:& FLASH BACK. CLSD CNTNRS MAY
BURST IF EXPOS TO EXTREME HEAT/FIRE. MAY DECOMPOSE UNDER FIRE CNDTNS EMITTING
IRRITANT &/OR TOX GASES. IN CLSD TANKS, WATER/FOAM MAY CAUSE FROTHING/
ERUPTION. E XPLAN OF CARCIN:OSHA REG 29 CFR 1910.1028. EFTS OF OVEREXP:SENSIT
TO SKIN. SKIN CONT MAY RSLT IN DERM ABSORP OF
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Physical/Chemical Properties
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B.P. Text: >176F,>80C
Spec Gravity: 1.231
Evaporation Rate & Reference: NOT KNOWN
Solubility in Water: NOT KNOWN
Appearance and Odor: TAN LIQUID.
Percent Volatiles by Volume: 54.15
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: ELEVATED TEMPS, CONT W/OXIDIZING AGENT, SPARKS,
OPEN FLAME. IGNITION SOURCES.
Materials To Avoid: OXIDIZERS, ACIDS, ALDEHYDES, KETONES, AMINES, VINYL
POLYMERS, CAUSTICS.
Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF
NITROGEN, AMMONIA.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: G-G EPOXY HIGH BUILD CONVERTER, 5556
Assigned IND: Y
Company: ICI PAINTS DIV GLIDDEN
Street: 925 EUCLID AVE
City: CLEVELAND OH
Zipcode: 44115
Health Emergency Phone: 800-545-2643
Label Required IND: Y
Date Of Label Review: 03/13/1998
Status Code: C
Label Date: 03/13/1998
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE. ACUTE: INHAL: IRRITATION OF RESPIRATORY
TRACT. PROLONGED INHAL MAY LEAD TO FATIGUE, DROWSINESS, DIZZINESS AND/OR LT
LEAD, HEADACHE, UNCOORDINATION, NAUSEA, VOMITING, UNCON, RESPIRATORY FAIL
URE, ASPHYXIATION, DEATH. SKIN: IRRITATION, DERMATITIS, BLISTERING,
DEFATTING, EYES: IRRITATION, BLURRED VISION, TEARING, REDNESS, CORNEAL
INJURY. INGEST: ASPIRATION HAZARD - MAY CAUSE LUNG INFLAMMATI ON &
DAMAGE. GI IRRITATION, NAUSEA, VOMITING, DIARRHEA, CNS DEPRESSION. CHRONIC:
CANCER HAZARD. CONTAINS BENZENE WHICH IS LISTED AS A HUMAN BLOOD CARCIN (FP
N). TOLUENE APPEARS ON NAVY OCCUPATIONAL CH EMICAL REPRODUCTIVE HAZARDS LIST
(FP N).
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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