| MSDS | : | 5452, GLID-GUARD EPOXY CHEMICAL RESISTANT (SUPDAT) | | CAS | : | 68002-19-7
25036-25-3
112945-52-5
1330-20-7
110-19-0
71-36-3
50-00-0
108-10-1
71-43-2
100-41-4 | | NAME | : | urea formaldehyde. ld50:(oral,rat) 1.90 gm/kg
phenol, 4,4'-(-methylethylidene)bis-, polymer with
ing 2: bis(oxirane); bisphenol a epoxy resin. ld50:(oral,rat) 2 gm/kg
silica, amorphous (fumed). ld50:(oral,rat) 10 gm/kg
xylene (sara 313) (cercla). ld50:(oral,rat) 4300 mg/kg
acetic acid, isobutyl ester; (isobutyl acetate) (cercla). ld50:(oral,rat)
n-butyl alcohol (sara 313) (cercla). ld50:(oral,rat) 2500 mg/kg
formaldehyde (sara 302/313) (cercla). % (wt): 0.01-0.1.
2-pentanone, 4-methyl-; (methyl isobutyl ketone) (sara 313) (cercla).
benzene (sara 313) (cercla). % (wt): 0.01-0.1
ethyl benzene (sara 313). ld50:(oral,rat) 3500 mg/kg
supdat: group 1. ntp 7th annual report on carcins, 1994: known to be
efts of overexp: uncoordination, naus, vomit, diarr, gi distrub, abdom
ing 13: depress, anesth eft/narcos, burns of mouth, throat, stom, loss of
ing 14: supp hlth info: cntns chem that is mod tox by ingest. other efts
ing 15: kidney, cns, blood. may be absorbed thru skin. notice-rpts have
ing 16: solvs w/perm brain & nerv sys dmg. intentional misuse by
ing 17: or fatal. for more specific information contact nehc (fp n).
first aid proc: especially under lids for @ lst 15 mins. if irrit/other
ing 19: if swallowed, obtain medical treatment immediately.
spill proc: must be used during cleanup. lg spills - shut off leak if
ing 21: to storage/salvage vess. use absorb to pick up excess residue.
ing 22: of sewers & water courses. sm spills - use absorbent to pick
other prec: surfs. if such cndtns cannot be avoided, use approp niosh
ing 24: prot info. empty cntnrs may cntn haz residues. ground equip when
|
| |
|
|
ICI PAINTS -- 5452, GLID-GUARD EPOXY CHEMICAL RESISTANT (SU
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CGRWM
MSDS NAME: 5452, GLID-GUARD EPOXY CHEMICAL RESISTANT (SUPDAT)
Responsible Party
Name: ICI PAINTS
Address: 925 EUCLID AVE
City: CLEVELAND OH 44115
Info Phone: 800-545-2643
Emergency Phone Number: 800-545-2643
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: GLIDDEN PAINT, ICI PAINTS NORTH AMERICA
Address: 925 EUCLID AVE
City: CLEVELAND OH 44115
Phone: 800-545-2643/216-344-8207
Name: ICI PAINTS
Address: 925 EUCLID AVE
City: CLEVELAND OH 44115
Phone: 800-545-2643
=======================================================
Ingredients
=======================================================
Cas: 68002-19-7
Name: UREA FORMALDEHYDE. LD50:(ORAL,RAT) 1.90 GM/KG
% Wt: 1-5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 25036-25-3
Name: PHENOL, 4,4'-(-METHYLETHYLIDENE)BIS-, POLYMER WITH
2,2'-((1-METHYLETHYLIDENE)BIS(4-1-PHENYLENE -OXYMETHYLENE))
% Wt: 40-50
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Name: ING 2: BIS(OXIRANE); BISPHENOL A EPOXY RESIN. LD50:(ORAL,RAT) 2 GM/KG
-----------------------------
Cas: 112945-52-5
RTECS #: VV7310000
Name: SILICA, AMORPHOUS (FUMED). LD50:(ORAL,RAT) 10 GM/KG
% Wt: 1-5
OSHA PEL: 6 MG/M3
ACGIH TLV: 10 MG/M3
------------------------------
Cas: 1330-20-7
RTECS #: ZE2100000
Name: XYLENE (SARA 313) (CERCLA). LD50:(ORAL,RAT) 4300 MG/KG
% Wt: 10-20
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM/150 STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 110-19-0
RTECS #: AI4025000
Name: ACETIC ACID, ISOBUTYL ESTER; (ISOBUTYL ACETATE) (CERCLA). LD50:(ORAL,RAT)
15.40 GM/KG
% Wt: 10-20
OSHA PEL: 150 PPM
ACGIH TLV: 150 PPM
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 71-36-3
RTECS #: EO1400000
Name: N-BUTYL ALCOHOL (SARA 313) (CERCLA). LD50:(ORAL,RAT) 2500 MG/KG
% Wt: 1-5
OSHA PEL: 100 PPM
ACGIH TLV: S, C 50 PPM
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 50-00-0
RTECS #: LP8925000
Name: FORMALDEHYDE (SARA 302/313) (CERCLA). % (WT): 0.01-0.1.
% Wt: <0.1
OSHA PEL: SEE 1910.1048
ACGIH TLV: C 0.3 PPM, A2
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Cas: 108-10-1
RTECS #: SA9275000
Name: 2-PENTANONE, 4-METHYL-; (METHYL ISOBUTYL KETONE) (SARA 313) (CERCLA).
LD50:(ORAL,RAT) 1600 MG/KG
% Wt: 10-20
OSHA PEL: 100 PPM
ACGIH TLV: 50 PPM/75 STEL
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 71-43-2
RTECS #: CY1400000
Name: BENZENE (SARA 313) (CERCLA). % (WT): 0.01-0.1
% Wt: <0.1
OSHA PEL: SEE 1910.1028
ACGIH TLV: 10 PPM; A2
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
------------------------------
Cas: 100-41-4
RTECS #: DA0700000
Name: ETHYL BENZENE (SARA 313). LD50:(ORAL,RAT) 3500 MG/KG
% Wt: 1-5
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM/125 STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Name: SUPDAT: GROUP 1. NTP 7TH ANNUAL REPORT ON CARCINS, 1994: KNOWN TO BE
CARCIN. OSHA REG 29 CFR 1910.1028.
-----------------------------
Name: EFTS OF OVEREXP: UNCOORDINATION, NAUS, VOMIT, DIARR, GI DISTRUB, ABDOM
PAIN, VISUAL DISTURB, APATHY, CNS
-----------------------------
Name: ING 13: DEPRESS, ANESTH EFT/NARCOS, BURNS OF MOUTH, THROAT, STOM, LOSS OF
CONSCIOUSNESS, RESP FAILURE, DEATH.
-----------------------------
Name: ING 14: SUPP HLTH INFO: CNTNS CHEM THAT IS MOD TOX BY INGEST. OTHER EFTS
OF OVEREXP MAY INCL TOX TO LIVER,
-----------------------------
Name: ING 15: KIDNEY, CNS, BLOOD. MAY BE ABSORBED THRU SKIN. NOTICE-RPTS HAVE
ASSOC RPTD & PRLNGD OCCUP OVEREXP TO
-----------------------------
Name: ING 16: SOLVS W/PERM BRAIN & NERV SYS DMG. INTENTIONAL MISUSE BY
DELIB CONC & INHALING CONTENTS MAY BE HARMFUL
-----------------------------
Name: ING 17: OR FATAL. FOR MORE SPECIFIC INFORMATION CONTACT NEHC (FP N).
-----------------------------
Name: FIRST AID PROC: ESPECIALLY UNDER LIDS FOR @ LST 15 MINS. IF IRRIT/OTHER
EFTS PERSIST, OBTAIN MED ATTN. INGEST:
-----------------------------
Name: ING 19: IF SWALLOWED, OBTAIN MEDICAL TREATMENT IMMEDIATELY.
-----------------------------
Name: SPILL PROC: MUST BE USED DURING CLEANUP. LG SPILLS - SHUT OFF LEAK IF
SAFE TO DO SO. DIKE AND CNTN SPILL. PUMP
-----------------------------
Name: ING 21: TO STORAGE/SALVAGE VESS. USE ABSORB TO PICK UP EXCESS RESIDUE.
KEEP SALVAGEABLE MATL & RINSE WATER OUT
-----------------------------
Name: ING 22: OF SEWERS & WATER COURSES. SM SPILLS - USE ABSORBENT TO PICK
UP RESIDUE AND DISPOSE OF PROPERLY.
-----------------------------
Name: OTHER PREC: SURFS. IF SUCH CNDTNS CANNOT BE AVOIDED, USE APPROP NIOSH
APPRVD RESP PROT AS DIRECTED UNDER SPEC
-----------------------------
Name: ING 24: PROT INFO. EMPTY CNTNRS MAY CNTN HAZ RESIDUES. GROUND EQUIP WHEN
TRANSFERRING TO PVNT ACCUM OF STATIC CHARGE.
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: SEE INGREDIENTS
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: YES
Effects of Exposure: ACUTE: INHAL: IRRIT OF RESP TRACT. PRLNGD INHAL MAY LEAD
TO MUC MEMB IRRIT, FATG, DROW, DIZZ AND/OR LT HEAD, HDCH, UNCOORDINATION,
NAUS, VOMIT, ABDOM PAIN, CHEST PAIN, COUGH, APATHY, CNS DEPRESS, INTO
XICATION, TIGHTNESS OF CHEST, ANESTH EFT/NARCOS, DFCLTY OF BREATHING, LIVER
DMG, KIDNEY DMG, LOSS OF (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: FORMALDEHYDE: IARC MONO, SUPP, VOL 7, PG 211,
1987: GROUP 2A. NTP 7TH ANNUAL RPT ON CARCINS, 1994: ANTIC TO BE (SUPDAT)
Signs And Symptions Of Overexposure: HLTH HAZ: CONSIOUSNESS, RESP FAILURE,
ASPHY, DEATH. POSS SENSIT TO RESP TRACT. SKIN: IRRIT. PRLNGD/RPTD CONT CAN
CAUSE DERM, DEFAT, BLISTERING, ALLERGIC RESPONSE, SEV IRRIT. POSS SENSIT.
EYES: IRRIT. PRLNGD/RPTD CONT CAN CAUSE CONJ, BLURRED VISION, TEARING,
REDNESS, SEV IRRIT, CORNEAL INJURY. INGEST: MAY CAUSE
Medical Cond Aggravated By Exposure: EYE, SKIN, RESPIRATORY DISORDERS, KIDNEY
DISORDERS.
First Aid: INHAL: REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED BRTHG.
GET EMER MED ATTN. HAVE TRAINED PERSON GIVE OXYG IF NEC. GET MED HELP FOR ANY
BRTHG DFCLTY. SKIN: FLUSH W/WATER. THEN WASH THORO W/SOAP & WATER.
REMOVE CONTAMD CLTHG. WASH CONTAMD CLTHG BEFORE RE-USE. DISPOSE OF CONTAMD
LEATHER ITEMS, SUCH AS SHOES & BELTS. IF IRRIT OCCURS, CONSULT PHYS. EYE:
FLUSH IMMED W/LG AMTS OF WATER,
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: COMPLY W/ALL APPLIC HLTH & ENVIRONMENTAL REGS.
ELIM ALL SOURCES OF IGNIT. VENTILATE AREA. VENTILATE AREA W/EXPLO-PROOF
EQUIP. SPILLS MAY BE COLLECTED W/ABSORB MATLS. USE NON-SPK TOOLS. EVACUATE
ALL UN NEC PERS. COMPLETE PERSONAL PROT EQUIPMENT
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
AVOID DISCHARGE TO NATURAL WATERS.
Handling And Storage Precautions: STORE <80F(27C). STORE <100F(38C). KEEP
AWAY FROM HEAT, SPKS & OPEN FLAME. USE ONLY W/ADEQ VENT. DO NOT TAKE
INTERNALLY.
Other Precautions: KEEP OUT OF REACH OF CHILDREN. AVOID CONT W/SKIN & EYES,
& BRTHG OF VAPS. KEEP CNTNRS TIGHTLY CLSD & UPRIGHT WHEN NOT IN USE.
AVOID CNDTNS WHICH RSLT IN FORMATION OF INHALABLE PARTICLES SUCH AS SPRAYI
NG/ABRADING (SANDING) PAINTED
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: SCC
Flash Point Text: 40.0F,4.4C
Lower Limits: 7.0%
Upper Limits: 11.2%
Extinguishing Media: DRY CHEMICAL OR FOAM. WATER FOG. CARBON DIOXIDE.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard: CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME
HEAT/FIRE. VAPS MAY IGNITE EXPLO @ AMBIENT TEMPS. VAPS ARE HVR/AIR & MAY
TRAVEL LONG DIST TO SOURCE OF (SUPDAT)
=======================================================
Control Measures
=======================================================
Respiratory Protection: CONTROL ENVIRONMENTAL CONCS BELOW APPLIC STDS. WHERE
RESP PROT IS REQD, USE ONLY NIOSH APPRVD RESPIRATORS I/A/W OSHA STANDARD 29
CFR 1910.134.
Ventilation: PROVIDE DILUTION VENT/LOC EXHAUST TO PVNT BUILD-UP OF VAPS. USE
EXPLOSION-PROOF EQUIP. USE NON-SPK EQUIP.
Protective Gloves: IMPERVIOUS GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N).
IMPERVIOUS CLTHG, FACE SHIELD, APRON, BOOTS.
Work Hygienic Practices: WASH HANDS THORO AFTER HNDLG, ESPECIALLY BEFORE EATING
OR SMOKING.
Supplemental Safety and Health: MFR TRADE NAME/PART NO: FINISH DOUBLE BUILD
CURING AGENT. EXPLO HAZ: IGNIT & FLASH BACK. CLSD CNTNRS MAY BURST IF
EXPOS TO EXTREME HEAT/FIRE. MAY DECOMPOSE UNDER FIRE CNDTNS EMITTING IRRITANT
&/OR TOX IC GASES. EXPLAN OF CARCIN: CARCIN. OSHA REG: 29 CFR 1910.1048.
BENZENE: IARC MONO, SUPP, VOL 7, PG 120, 1987:
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >165F,>74C
Spec Gravity: 1.017
Evaporation Rate & Reference: NOT KNOWN
Solubility in Water: NOT KNOWN
Appearance and Odor: CLEAR LIQUID.
Percent Volatiles by Volume: 55.93
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: ELEVATED TEMPS, CONT W/OXIDIZING AGENT, STORAGE
NEAR ACIDS, SPARKS, OPEN FLAME. IGNITION SOURCES.
Materials To Avoid: OXIDIZERS, ACIDS, REDUCING AGENTS, BASES, ALDEHYDES,
AMINES, NITRIC ACID, MERCAPTANS, LEWIS ACIDS, MINERAL ACIDS.
Hazardous Decomposition Products: CO, CO*2, OXIDS OF NITROGEN, FORMALDEHYDE,
AMMONIA, ACIDIC CASES, ALDEHYDES, UNIDENTIFIED ORGANIC COMPOUNDS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: 5452, GLID-GUARD EPOXY CHEMICAL RESISTANT (SUPDAT)
Assigned IND: Y
Company: ICI PAINTS
Street: 925 EUCLID AVE
City: CLEVELAND OH
Zipcode: 44115
Health Emergency Phone: 800-545-2643
Label Required IND: Y
Date Of Label Review: 03/13/1998
Status Code: C
Label Date: 03/13/1998
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE. ACUTE: INHAL:RESP TRACT IRRIT. PRLNGD INHAL
MAY LEAD TO MUC MEMB IRRIT, FATG, DROW, DIZZ &/OR LT HEAD, HDCH, NAUS,
VOMIT, CHEST PAIN, COUGH, CNS DEPRESS, INTOXICATION, CHEST TIGHTNESS, ANES TH
EFT/NARCOS, BRTHG DFCLTY, ASPHY, DEATH. SKIN:IRRIT, DERM, DEFAT, BLISTERS,
ALLERGIC RESPONSE. EYES:IRRIT, CONJ, BLURRING, TEARING, REDNESS, CORNEAL
INJURY. INGEST:ASPIR HAZ-POSS LUNG INFLAM & DMG. GI IRRIT, NAUS, VOMIT,
CNS DEPRESS, UNCON, DEATH. CHRONIC:CANCER HAZ. CNTNS BENZENE WHICH IS LISTED
AS HUMAN BLOOD CARCIN & FORMALDEHYDE, AN ANIMAL NASAL CARCIN (FP N).
TOLUENE APPEARS ON NAVY OCCUP C HEM REPRO HAZ LIST (FP N). SKIN & RESP
SENSIT.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
|
|