HOSE MART INC -- SULFURIC ACID
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Material Safety Data Sheet
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MSDS Num: CGSCS
MSDS NAME: SULFURIC ACID
Responsible Party
Name: HOSE MART INC
Address: 24756 REDLANDS BLVD
City: SAN BERNADINO CA 92408
Info Phone: 800-222-0342
Emergency Phone Number: 800-222-0342
Preparer's Name: M.J. WURTH
Published: Y
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Contractor Summary
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Name: HOSE MART INC
Address: 24756 REDLANDS BLVD
City: SAN BERNADINO CA 92408
Phone: 800-222-0342
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Ingredients
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Cas: 7664-93-9
RTECS #: WS5600000
Name: SULFURIC ACID (SARA 302/313) (CERCLA). LD50:(ORAL,RAT) 2140 MG/KG.
% Wt: >95
OSHA PEL: 1 MG/M3
ACGIH TLV: 1 MG/M3;3 STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Name: FIRE FIGHT PROC:SPRAY ONLY TO KEEP FIRE-EXPOS CNTNRS COOL. STRUCTURAL
FIREFIGHTER'S PROT CLTHG IS NOT EFTIVE.
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Name: ING 2:STAY AWAY FROM ENDS OF TANKS. DO NOT RELEASE RUNOFF FROM FIRE
CONTROL METHODS TO SEWERS OR WATERWAYS.
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Name: EFTS OF OVEREXP:WEAK & RAPID PULSE, SHALLOW RESPS & SCANTY URINE
MAY FOLLOW INGEST/SKIN CONT. CIRCULATORY SHOCK
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Name: ING 4:IS OFTEN IMMED CAUSE OF DEATH. EYE CONT PRDCES DEEP CORNEAL
ULCERATION, KEROTO-CONJ, PALPEBRAL LESIONS &
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Name: ING 5:POSS BLINDNESS. CHRONIC:EFTS MAY INCL DENTAL EROSION, CONJ,
TRACHEOBRONCH, EMPHYSEMA, STOMATITIS(INFLAMM OF
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Name: ING 6:MOUTH MUC MEMBS), GASTRITIS (INFLAMM OF STOM MUC MEMBS) & DERM.
TARGET ORGANS:RESP SYS, EYES, SKIN & TEETH.
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Name: FIRST AID PROC:& WATER. FOR REDDENED/BLISTERED SKIN, CONSULT MD.
INHAL:REMOVE EXPOS PERS TO FRESH AIR & SUPPORT
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Name: ING 8:BRTHG AS NEEDED. INGEST:NEVER GIVE ANYTHING BY MOUTH TO
UNCON/CONVULSING PERS. CONT POIS CTL CTR. UNLESS
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Name: ING 9:POIS CTL CTR ADVISED OTHERWISE, HAVE THAT CONSCIOUS & ALERT
PERS DRINK 1-2 GLASSES OF WATER/MILK TO
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Name: ING 10:DILUTE. DO NOT INDUCE VOMIT! DO NOT ATTEMPT TO NEUT ACID W/SODIUM
BICARBONATE. AFTER 1ST AID, GET APPROP
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Name: ING 11:IN-PLANT, PARAMEDIC/COMMUNITY MED SUPPORT. NOTE TO MDS:MONITOR
ARTERIAL BLOOD GASES, CHEST X-RAY & PULM
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Name: ING 12:FUNCTION TEST IF RESP TRACT IRRIT/RESP DEPRESS IS EVID. TREAT
DERMAL IRRIT/BURNS W/STD TOPICAL THERAPY.
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Name: SPILL PROC:CTL LEAK IF W/OUT UNDUE RISK. NEUT SM SPILLS W/SODIUM
BICARBONATE/MIXT OF SODA ASH/SLAKED LIME(50/50)(SUPDAT)
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Name: ING 14:& PLACE INTO SEALED CNTNRS FOR DISP. IF NEUT AGENT IS NOT
AVAIL, ABSORB SPILLED PROD W/VERMICULITE, DRY
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Name: ING 15:SAND/EARTH. NEVER USE ORG MATL (E.G., SAWDUST) TO ABSORB SPILL.
FOR LG SPILLS, DIKE FAR AHEAD TO CNTN FOR
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Name: ING 16:LATER DISP. FOLLOW APPLIC OSHA REGS (29 CFR 1910.120). REPORT ANY
RELEASE IN EXCESS OF 1000 LBS.
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Name: OTHER PREC:PLACEMENT & PERIODIC PHYSICAL EXAMS W/EMPHASIS ON RESP
TRACT (PULM FUNC TESTS), SKIN, EYES & TEETH.
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Name: ING 18:PROD REACTS VIOLENTLY W/WATER W/EVOLUTION OF HEAT. ALWAYS ADD ACID
TO WATER/OTHER DILUENT, NOT WATER TO ACID!
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Name: OTHER PROT EQUIP:HAS A MINOR TO MODERATE EFFECT ON NEOPRENE OR RUBBER.
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Name: HYGIENT PRACT:NEVER EAT, DRINK/SMOKE IN WORK AREAS. PRACTICE GOOD
PERSONAL HYGIENE AFTER USING MATL, ESP BEFORE
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Name: ING 21:EATING, DRINKING, SMOKING, USING TOILET OR APPLYING COSMETICS.
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Name: RESP PROT:EFFICIENCY PARTICULATE FILTER. AT <50 MG/M3 USE ANY CHEM
CARTRIDGE RESP W/FULL FACEPIECE & ACID GAS
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Name: ING 23:CARTRIDGE(S) IN COMBINATION W/HIGH EFFICIENCY PARTICULATE FILTER.
FOR CONCS <80 MG/M3, USE ANY SUPPLIED
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Name: ING 24:AIR-RESP W/FULL FACEPIECE & OPERATED IN PRESS-DEMAND/OTHER
POS-PRESS MODE. FOR MORE INFO, CONTACT NEHC (FP N).
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Health Hazards Data
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LD50 LC50 Mixture: SEE INGREDIENT 1.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE:VAP/MIST INHAL CAUSES COUGH, SNEEZING, NOSE
IRRIT/BLEEDS, REFLEX BRONCHOSPASM, SHORTNESS OF BREATH, PULM EDEMA (FLUID IN
LUNGS), EMPHYSEMA & PERM CHANGES IN PULM FUNC. INGEST CAUSES CORR OF MUC
MEMBS OF MOUTH, THROAT & ESOPHAGUS & EPIGASTRIC PAIN W/NAUS &
VOMIT OF MUCOID & "COFFEE GROUND" MATL. (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: SULFURIC ACID:IARC MONOGRAPHS, VOL 54, PG 41,
1992:GROUP 1. ANIMAL:PULMONARY IRRITATION.
Signs And Symptions Of Overexposure: HLTH HAZ:SKIN CONT PRDCES SEV BURNS;
INITIALLY ZONE OF CONT IS BLEACHED & TURNS BROWN PRIOR TO FORM OF CLEARLY
DEFINED ULCER. THESE WOUNDS ARE SLOW IN HEALING & MAY CAUSE EXTENSIVE
SCARRING THAT RSLTS IN FUNCTIONAL INHIBITION IF BURNS ARE EXTENSIVE, OUTCOME
MAY PROVE FATAL. CIRCULATORY COLLAPSE W/CLAMMY SKIN,
Medical Cond Aggravated By Exposure: CHRONIC RESPIRATORY, GASTROINTESTINAL,
NERVOUS & SKIN OR EYE DISORDERS.
First Aid: EYES:DO NOT ALLOW VICTIM TO RUB/KEEP EYES TIGHTLY SHUT. GENTLY LIFT
LIDS & FLUSH IMMED & CONTINUOUSLY W/FLOODING AMTS OF WATER(FOR AT LST
15 MINS) UNTIL TRANSPORTED TO EMER MED FACILITY. CONSULT OPHTH ALMOLOGIST
IMMED. SKIN:QUICKLY REMOVE CONTAM CLTHG. RINSE W/FLOODING AMTS OF WATER FOR
AT LST 15 MINS. USE 2% SODIUM BICARONATE SOLN TO FURTHER NEUT ANY H*2SO*4 ON
SKIN. WASH EXPOS AREA W/SOAP
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Handling and Disposal
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Spill Release Procedures: NOTIFY SFTY PERS OF SPILL, EVACUATE ALL UNNEC PERS,
REMOVE ALL IGNIT SOURCES & PROVIDE ADEQ VENT. CLEANUP PERS SHOULD WEAR
FULLY-ENCAPSULATING, VAP-PROT CLTHG TO PROT AGAINST INHAL & SKIN/EYE
CONT. KE EP WATER & COMBUSTS AWAY FROM RELS. STOP/
Neutralizing Agent: SODIUM BICARBONATE OR MIXTURE OF SODA ASH/SLAKED LIME
(50/50).
Waste Disposal Methods: CONTACT YOUR SUPPLIER OR A LICENSED CONTRACTORS FOR
DETAILED RECOMMENDATIONS. NEUTRIALIZE WASTE WATER PH BETWEEN 5.5 & 8.5.
FOLLOW APPLICABLE FEDERAL, STATE & LOCAL REGULATIONS.
Handling And Storage Precautions: CORR! STORE IN CLEARLY LABELED, STEEL CNTNRS
IN COOL (<50F(10C)), DRY, WELL-VENTED LOCATION ON ACID-RESIST CEMENT FLOOR
& AWAY FROM DIRECT (SUPP DATA)
Other Precautions: PROT STOR CNTNRS AGAINST DMG & WATER. USE NON-SPARKING
TOOLS NEAR PROD CARBOYS, DRUMS, TANK CARS/METAL STOR TANKS BECAUSE OF POSS
PRODUCTION OF HYDROGEN DURING STOR. USE HAND PUMPS FOR DECANTING & EMP
TYING OF CARBOYS. CONSIDER PRE-
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Fire and Explosion Hazard Information
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Flash Point Text: NOT COMBUSTIBLE
Lower Limits: NONE
Upper Limits: NONE
Extinguishing Media: USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE.
ONLY USE WATER IF ABSOLUTELY NECESSARY & USE W/GREAT CAUTION.
Fire Fighting Procedures: USE NIOSH APPRVD SCBA & FULL PROT EQUIP(FP N).
WATER APPLIED DIRECTLY TO SULFURIC ACID RSLTS IN VIOLENT HEAT LIBERATION
& SPLATTERING OF MATL. USE WATER
Unusual Fire/Explosion Hazard: SULFURIC ACID, A STRONG DEHYDRATING AGENT,
REACTS W/ORG MATLS & PRDCES ENOUGH HEAT IGNIT, CHARS WOOD & MAY CAUSE
IGNIT OF FINELY DIVIDED MATLS ON CONT. (SUPDAT)
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Control Measures
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Respiratory Protection: SEEK PROFESSIONAL ADVICE PRIOR TO RESP SELECTION &
USE. FOLLOW OSHA RESP REGS (29 CFR 1910.134) & WEAR NIOSH APPRVD RESP.
FOR CONCS <25 MG/M3 USE ANY POWERED, AIR-PURIFYING RESP W/ACID GAS
CARTRIDGE(S ) IN COMBINATION W/HIGH-
Ventilation: TOTAL ENCLOSURES OF PROCESSES & MECHANIZATION OF HNDLG PROCS
ARE MOST EFTIVE MEASURES TO PVNT CONT W/SULFURIC (SUPDAT)
Protective Gloves: CHEMICALLY PROTECTIVE GLOVES.
Eye Protection: ANSI APPROVED CHEM WORKERS GOGGS(SUPDAT)
Other Protective Equipment: ANSI APPRVD EYE WASH FOUNTAIN & DELUGE SHOWER (FP
N). WEAR BOOTS, APRONS & GAUNTLETS TO PVNT SKIN CONT. H*2SO*4
Work Hygienic Practices: SEPARATE CONTAM WORK CLOTHES FROM STREET CLOTHES &
LAUNDER BEFORE REUSE. REMOVE MATL FROM SHOES & CLEAN PPE.
Supplemental Safety and Health: PH:1N SOLN=0.3, 0.1N SOLN=1.2, 0.01N SOLN=2.1.
APPEAR/ODOR:CMPD IS SOLID <51F(11C). EXPLO HAZ:RXN W/METALS MAY PRDCE
HIGHLY FLAMM, HYDROGEN GAS. HNDLG/STOR PREC:SUNLIGHT, COMBUSTS & OTHER
REACTIVE MAT LS. VENT:ACID. PROT ELEC INSTALLATIONS AGAINST CORR ACTION OF
ACID VAPS. EYE PROT:& FULL LENGTH FACESHIELD (FP N).
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Physical/Chemical Properties
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B.P. Text: 554F,290C
M.P/F.P Text: >50F,>10C
Decomp Text: 644F,340C
Vapor Pres: <0.001@20C
Vapor Density: 1.2
Spec Gravity: 1.841
PH: SUPDAT
Solubility in Water: SOLUBLE; REACTS.
Appearance and Odor: COLORLESS (PURE) TO DARK BROWN (IMPURE), DENSE, OILY LIQ;
ODORLESS. PURE(SUPDAT
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: WATER, COMBUSTIBLES, HEAT, IGNITION SOURCES &
OTHER INCOMPATIBLES.
Materials To Avoid: ACETIC ACID, ALLYL ALCOHOL, ALLYL CHLORIDE, CARBIDES,
WATER, ETC. FOR A COMPLETE LIST OF MATLS TO AVOID CONT NEHC(FP N).
Hazardous Decomposition Products: THERMAL OXIDATIVE DECOMPOSITION OF SULFURIC
ACID CAN PRODUCE SULFUR OXIDES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: SULFURIC ACID
Company: HOSE MART INC
Street: 24756 REDLANDS BLVD
City: SAN BERNADINO CA
Zipcode: 92408
Health Emergency Phone: 800-222-0342
Label Required IND: Y
Date Of Label Review: 03/18/1998
Status Code: C
Label Date: 03/18/1998
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE:INHAL:COUGH, SNEEZING, NOSE IRRIT/BLEEDS, REFLEX
BRONCHOSPASM, SHORTNESS OF BREATH, PULM EDEMA (FLUID IN LUNGS), EMPHYSEMA
& PERM CHANGES IN PULM FUNC. INGEST:CORR OF MUC MEMBS, EPIGASTRIC PAIN
W/NAUS & VOMIT OF MUCOID & "COFFEE GROUND" MATL. SKIN:SEV BURNS, IF
BURNS EXTENSIVE MAY BE FATAL. INGEST/SKIN CONT:CIRCULATORY COLLAPSE, CLAMMY
SKIN, WEAK, RAPID PULSE, SHALLOW RESP & SCANTY URINE, PO SS DEATH. EYE
CONT:CORNEAL ULCERATION, POSS BLINDNESS. CHRONIC:CANCER HAZARD. CONTAINS
SULFURIC ACID WHICH IS LISTED AS AN ANIMAL PULMONARY (LUNG) CARCIN (FP N).
DENTAL EROSION, CONJ, TRACHEOBRONCH, E MPHYSEMA, STOMATITIS, GASTRITIS &
DERMATITIS.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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