ITW DEVCON -- UNDERWATER REPAIR PUTTY-UW RESIN, 11800
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Material Safety Data Sheet
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MSDS Num: CJPNL
MSDS NAME: UNDERWATER REPAIR PUTTY-UW RESIN, 11800
Kit Part: Y
Responsible Party
Name: ITW DEVCON
Address: 30 ENDICOTT ST
City: DANVERS MA 01923
Info Phone: 978-777-1100
Emergency Phone Number: 800-424-9300 (CHEMTREC)
Resp. Party Other MSDS No.: 0618; PART # 0111
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
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Contractor Summary
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Name: DEVCON CORP
Address: 30 ENDICOTT ST
City: DANVERS MA 01923-3753
Phone: 1-508-777-1100
Name: ITW DEVCON CORP
Address: 30 ENDICOTT ST
City: DANVERS MA 01923
Phone: 508-777-1100
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Ingredients
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Cas: 1333-86-4
RTECS #: FF5800000
Name: CARBON BLACK
< Wt: 1.
Other REC Limits: N/K (FP N)
OSHA PEL: 3.5 MG/M3
OSHA STEL: N/K (FP N)
ACGIH TLV: 3.5 MG/M3
ACGIH STEL: N/K (FP N)
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Cas: 25068-38-6
RTECS #: CE6880000
Name: BISPHENOL A EPOXY RESIN; (BISPHENOL A DIGLYCIDYL ETHER RESIN) (DGEBPA)
% low Wt: 30.
% high Wt: 60.
Other REC Limits: N/K (FP N)
OSHA PEL: N/K (FP N)
OSHA STEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
ACGIH STEL: N/K (FP N)
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Health Hazards Data
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LD50 LC50 Mixture: SEE OTHER INFORMATION.
Route Of Entry Inds - Inhalation: NO
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: SKIN: MODERATE IRRITANT. CONTACT AT ELEVATED
TEMPERATURES CAN CAUSE THERMAL BURNS. MAY CAUSE SKIN SENSITIZATION (RASHES,
HIVES). EYES: MODERATE IRRITANT. CONTACT AT ELEVATED TEMPERATURES CAN CA USE
THERMAL BURNS. INHALATION: THE LOW VAPOR PRESSURE OF THE RESIN MAKES
INHALATION UNLIKELY IN NORMAL USE. INGESTION: ACUTE ORAL TOXICITY IS LOW. MAY
CAUSE GASTRIC DISTRESS. CHRONIC: PROLONGED OR REP EATED SKIN CONTACT MAY
CAUSE SENSITIZATION, WITH ITCHING, SWELLING, OR RASHES ON LATER EXPOSURE.
Explanation Of Carcinogenicity: CARBON BLACK: IARC MONOGRAPHS, VOLUME 65, PAGE
149, 1998: GROUP 2B. ANIMAL: LUNG.
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: PREEXISTING EYE AND SKIN DISORDERS.
DEVELOPMENT OF PREEXISTING SKIN OR LUNG ALLERGY SYMPTOMS MAY INCREASE.
First Aid: EYES: FLUSH W/CLEAN WATER FOR AT LEAST 15 MINUTES, WHILE HOLDING
EYELIDS OPEN. GET IMMEDIATE MEDICAL ATTENTION. SKIN: IMMEDIATELY REMOVE
CONTAMINATED CLOTHING & EXCESS CONTAMINANT. FLUSH SKIN W/WATER. WASH
THOROUGHLY W/SOAP & WARM WATER. CONSULT MD IF IRRITATION DEVELOPS. INHAL:
REMOVE PATIENT TO FRESH AIR. ADMINISTER OXYGEN IF BREATHING IS DIFFICULT. GET
MEDICAL ATTENTION IF SYMPTOMS PERSIST. ING ESTION: DO NOT INDUCE VOMITING.
GIVE TWO GLASSES OF WATER TO DILUTE IF PATIENT IS CONSCIOUS. GET MEDICAL
ATTENTION. NOTE TO MD: IN GENERAL, EMESIS INDUCTION IS UNNECESSARY IN HIGH
VISCOSITY, LOW VOLAT ILITY PRODUCTS, E.G., NEAT EPOXY RESINS.
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Handling and Disposal
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Spill Release Procedures: AVOID PERSONAL CONTACT. ELIMINATE IGNITION SOURCES.
VENTILATE AREA. DIKE, CONTAIN & ABSORB W/CLAY, SAND/OTHER SUITABLE
MATERIAL. FOR LARGE SPILLS, PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP RESIDUE
W/AN ABSORBENT SUCH AS CLAY, SAND/OTHER SUITABLE MATERIAL & DISPOSE OF
PROPERLY. FLUSH AREA W/WATER TO REMOVE TRACE RESIDUE. PREVENT SPILL FROM
ENTERING DRAINAGE/SEWER SYSTEMS, WATERWAYS & SURFACE WATERS.
Waste Disposal Methods: IF THIS RESIN BECOMES A WASTE, IT WOULD NOT BE A
HAZARDOUS WASTE BY RCRA CRITERIA (40 CFR 261). DISPOSE OF ACCORDING TO
APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS.
Handling And Storage Precautions: STORE IN A COOL, DRY AREA AWAY FROM HIGH
TEMPERATURES AND FLAMES. AVOID CONTACT WITH SKIN, EYES, OR CLOTHING. HANDLE
MIXED RESINAND HARDENER IN ACCORDANCE WITH THE POTENTIAL HAZARD OF THE CURING
AGENT USED.
Other Precautions: PROVIDE APPROPRIATE VENTILATION/RESPIRATORY PROTECTION
AGAINST DECOMPOSITION PRODUCTS (SEE CONTROL MEASURES SECTION) DURING
WELDING/FLAME CUTTING OPERATIONS AND TO PROTECT AGAINST NUISANCE DUST DURING
SANDING/GRINDING OF CURED PRODUCT.
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Fire and Explosion Hazard Information
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Flash Point Method: PMCC
Flash Point: >204.4C, 400.F
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N). MATERIAL WILL NOT BURN UNLESS PREHEATED. DO NOT ENTER
CONFINED SPACE WITHOUT FULL BUNKER GEAR. COOL FIRE-EXPOSED CONTAINERS WITH
WATER.
Unusual Fire/Explosion Hazard: WHEN HEATED TO DECOMPOSITION IT EMITS FUMES OF
CL-, CARBON MONOXIDE, OTHER FUMES AND VAPORS VARYING IN COMPOSITION AND
TOXICITY.
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Control Measures
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Respiratory Protection: NONE REQUIRED AT NORMAL HANDLING TEMPERATURES AND
CONDITIONS. USE NIOSH APPROVED ORGANIC VAPOR CARTRIDGES FOR UNCURED RESIN AND
NIOSH APPROVED DUST/PARTICLE RESPIRATORS DURING GRINDING/SANDING OPERATI ONS
OF CURED RESIN, AS EXPOSURE LEVELS DICTATE.
Ventilation: LOC EXHAUST IS PREFERRED ALTHOUGH GOOD GEN MECH VENT IS USUALLY
ADEQ FOR MOST INDUSTRIAL APPLICATIONS. LOC EXHAUST IS RECOMMENDED FOR
CONFINED AREAS.
Protective Gloves: CHEMICAL RESISTANT GLOVES.
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPROVED EMERGENCY EYEWASH AND DELUGE SHOWER
(FP N). CHEMICAL-RESISTANT GEAR AS REQUIRED TO PREVENT SKIN CONTACT.
Work Hygienic Practices: WASH THORO W/SOAP & WATER AFTER USING & PARTICULARLY
BEFORE EATING, DRINKING, SMKNG, APPLYING COSMETICS/USING TOILET. LAUNDER
CONTAM CLTHG & PROT GEAR BEFORE REUSE. DISCARD CONTAM LEATHER ARTICLES.
Supplemental Safety and Health: PHYSICAL/CHEMICAL PROPERTIES: VOC: 0
GRAMS/LITER; PERCENT VOLATILE BY WEIGHT: 100; PH (5% SOLUTION OR SLURRY IN
WATER): NEUTRAL. CONDITIONS TO AVOID (POLYMERIZATION): GENERATING
UNIDENTIFIED FUMES AND VAPORS WHICH MAY BE TOXIC.
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Physical/Chemical Properties
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Boiling Point: >260.C, 500.F
Vapor Pres: 0.03 MM HG @ 171F
Vapor Density: >1 (AIR=1)
Spec Gravity: 1.5
PH: SUP DAT
Solubility in Water: NEGLIGIBLE
Appearance and Odor: BLACK PASTE WITH LITTLE ODOR.
Percent Volatiles by Volume: 0
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: OPEN FLAME AND EXTREME HEAT.
Materials To Avoid: STRONG LEWIS OR MINERAL ACIDS, STRONG OXIDIZING AGENTS,
STRONG MINERAL AND ORGANIC BASES (ESPECIALLY PRIMARY AND SECONDARY ALIPHATIC
AMINES).
Hazardous Decomposition Products: OXIDES OF CARBON; ALDEHYDES, ACIDS AND OTHER
ORGANIC SUBSTANCES MAY BE FORMED DURING COMBUSTION OR ELEVATED TEMPERATURE
(>500F) DEGRADATION.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: HEAT IS GENERATED WHEN RESIN IS MIXED WITH
CURING AGENTS; RUN-A-WAY CURE REACTIONS MAY CHAR & DECOMPOSE THE RESIN, (SUP
DAT)
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Toxicological Information
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Toxicological Information: EYE IRRIT: NOT AVAIL. SUBCHRONIC EFTS: NOT AVAIL.
CARCIN, TERATOGENICITY, & MUTAGENICITY: BOTH RESIN & DIGLYCIDYL ETHER
OF BISPHENOL A (A COMPONENT OF THIS PROD) HAVE PROVED TO BE INACTIVE WHEN
TESTED BY IN VIVO MUTAGENICITY ASSAYS. BOTH HAVE SHOWN ACTIVITY BY IN VITRO
MICROBIAL MUTAGENICITY SCREENING & HAVE PRDCED CHROMOSOMAL ABERRATIONS IN
CULTURED RAT LIVER CELLS. OTHER CHRONIC EFTS: 2-YR BIOAS SAYS IN MICE EXPOSED
BY DERMAL RTE TO EPON 828, DGEBPA/OTHER COMMERCIAL RESINS YIELDED LIMITED
EVIDENCE OF WEAK CARCIN. AUTHORS CONCLUCED THAT RENAL TUMOR EVIDENCE W/EPON
828 "WAS OF NO BIOLOGICAL SIG NIFICANCE" & THAT RESIN (OTHER INFO)
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Ecological Information
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Ecological: ECOTOXICITY: NO DATA AVAILABLE. MOBILITY AND PERSISTENCE: NO DATA
AVAILABLE. ENVIRONMENTAL FATE: NO DATA AVAILABLE.
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MSDS Transport Information
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Regulatory Information
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Sara Title III Information: APPROPRIATE REGULATIONS FOR EMERGENCY PLANNING AND
RELEASE REPORTING REQUIREMENTS FOR SUBSTANCES ON THE SARA SECTION 301
EXTREMELY HAZARDOUS SUBSTANCE LIST: NO HAZARDOUS CHEMICALS. NO CHEMICALS ARE
ON THE SARA SECTION 313 LIST OF TOXIC CHEMICALS, FOR WHICH RELEASE REPORTING
MAY BE REQUIRED. FOR SPECIFIC REQUIREMENTS, CONSULT THE APPROPRIATE
REGULATIONS. FOR PURPOSES OF SARA SECTION 312 HAZARDOUS M ATERIALS INVENTORY
REPORTING, THE FOLLOWING HAZARD CLASSES APPLY TO THIS MATERIAL: IMMEDIATE
HEALTH HAZARD; DELAYED HEALTH HAZARD.
Federal Regulatory Information: ALL INGREDIENTS OF THIS PRODUCT ARE LISTED, OR
ARE EXEMPT FROM LISTING, ON THE ESCA INVENTORY. EXPORT NOTIFICATION IS
REQUIRED UNDER TSCA SECTION 12B: CARBON BLACK: NOT REQUIRED; BISPHENOL A
DIGLYCIDY L ETHER RESIN: REQUIRED. NO RCRA CODES APPLY TO THIS MATERIAL IF IT
BECOMES WASTE. CERCLA RQ: CARBON BLACK/BISPHENOL A DIGLYCIDYL ETHER RESIN:
0.00 LBS. CANADIAN REGULATIONS: W HAZARD CLASS(ES): D 2B; D2A. ALL COMPONENTS
OF THIS PRODUCT ARE ON THE DOMESTIC SUBSTANCES LIST.
State Regulatory Information: OTHER INFORMATION: CARBON BLACK: ORAL LD50 (RAT):
N/K; DERMAL LD50 (RABBIT): N/K; INHAL LC50 4 HR (RAT): N/K. BISPHENOL A
DIGLYCIDYL ETHER RESIN: ORAL LD50 (RAT): 30 G/KG; KERMAL LD50 (RABBIT):
>20 ML /KG; INHAL LC50 4 HR (RAT): NO DEATHS.
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Other Information
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Other Information: RATINGS: HLTH: 2; FLAMM: 1; REACTIVITY: 1. PROD IDENTIFIER:
EPOXY RESIN. GEN USE: THIS INFO APPLIES TO RESIN COMPONENT OF THE TWO-PART
KIT; HANDLE FRESHLY-MIXED RESIN & HARDENER AS REC FOR HARDEN ER. AFTER
CURING, PROD IS NOT HAZ. CHEM FAMILY: FILLED EPOXY RESIN. EMERGENCY OVERVIEW:
APPEARANCE, FORM, ODOR: BLACK PASTE WITH LITTLE ODOR. CAUTION! EYE & SKIN
IRRITANT (EVEID BY ITCH, REDNESS). POT NTL SKIN SENSITIZER. AVOID PRLNGD/RPTD
SKIN CONT. DO NOT TAKE INTERNALLY. WASH THORO AFTER HNDLG.-- TOX INFO: "IS
NOT A SYSTEMIC CARCIN WHEN APPLIED TO DORSAL SKIN OF CF1 MICE". TOX INFO ON
HAZ CHEM C ONSTITUENTS OF PROD: (STATE REGS)
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HAZCOM Label
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MSDS NAME: UNDERWATER REPAIR PUTTY-UW RESIN, 11800
Company: DEVCON CORP
Street: 30 ENDICOTT ST
City: DANVERS MA
Zipcode: 01923-3753
Health Emergency Phone: 800-424-9300 (CHEMTREC)
Label Required IND: Y
Date Of Label Review: 10/12/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Moderate
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: ACUTE: SKIN: MODERATE IRRITANT. CONTACT AT ELEVATED
TEMPERATURES CAN CAUSE THERMAL BURNS. MAY CAUSE SKIN SENSITIZATION (RASHES,
HIVES). EYES: MODERATE IRRITANT. CONTACT AT ELEVATED TEMPERATURES CAN CA USE
THERMAL BURNS. INHALATION: THE LOW VAPOR PRESSURE OF THE RESIN MAKES
INHALATION UNLIKELY IN NORMAL USE. INGESTION: ACUTE ORAL TOXICITY IS LOW. MAY
CAUSE GASTRIC DISTRESS. CHRONIC: CANCER HAZARD. C ONTAINS CARBON BLACK WHICH
IS LISTED AS AN ANIMAL LUNG CARCINOGEN (FP N). PROLONGED OR REPEATED SKIN
CONTACT MAY CAUSE SENSITIZATION, WITH ITCHING, SWELLING, OR RASHES ONLATER
EXPOSURE.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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