PPG INDUSTRIES INC -- CHLORINATING TABLETS, 0407A
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Material Safety Data Sheet
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MSDS Num: CJPQV
MSDS NAME: CHLORINATING TABLETS, 0407A
Responsible Party
Name: PPG INDUSTRIES INC
Address: 4325 ROSANNA DR
Box: 9
City: ALLISON PARK PA 15101
Info Phone: 412-492-5555
Emergency Phone Number: 304-843-1300
Preparer's Name: R KENNETH LEE
Review Ind: Y
Published: Y
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Contractor Summary
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Name: PPG INDUSTRIES INC
Address: ONE PPG PLACE
City: PITTSBURGH PA 15272
Phone: 1-800-245-2974 (CAL HYPO)
Name: PPG INDUSTRIES INC.
Address: 19699 PROGRESS DR
City: STRONGVILLE OH 44136
Phone: 800-245-2590
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Item Description Information
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Ingredients
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Cas: 7778-54-3
RTECS #: NH3485000
Name: CALCIUM HYPOCHLORITE (NOTE: 65% AVAILABLE CHLORINE. 35% INERT INGREDIENTS
(INCLUDES 5.5 - 10% MOISTURE)).
> Wt: 65.
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
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Health Hazards Data
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LD50 LC50 Mixture: LD50: (ORAL, RAT) 850 MG/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: INHAL: INHAL OF CALCIUM HYPOCHLORITE DUST &
DEPOSITION OF PARTICLES IN RESP TRACT CAN LEAD TO IRRIT OF TISS & CAUSE
VARIETY OF EFTS. THESE EFTS DEPENDENT ON CONC & INCL: UPPER RESP TRACT
IRRIT, NASAL CONGESTION, COUGH, SORE THROAT, LARYNGITIS & SHORTNESS OF
BREATH. IN OPERATIONS WHERE THERE ARE NO HIGH CONCS OF RESPIRABLE
PARTICULATES, PULM EDEMA (FLUID IN LUNG) MAY BE PRDCED. IF NOT TREATE D
IMMED, PULM EDEMA CAN BE LIFE THREATENING. SINCE PROD IS IN GRANULAR FORM,
PARTICLES OF RESPIRABLE SIZE ARE NOT GENERALLY ENCOUNTERED. EYE/SKIN: CALCIUM
HYPOCHLORITE IS CORR TO EYES. CONTACT OF CALC IUM HYPOCHLORITE DUST (EFTS OF
OVEREXP)
Signs And Symptions Of Overexposure: HLTH HAZS: W/EYES, EVEN MINUTE AMT FOR
SHORT DURATION, CAN CAUSE SEV IRRIT & EVEN BLINDNESS. CNTCT W/SKIN MAY
CAUSE SEV IRRIT, BURNS OR TISS DESTRUCTION. IN STUDIES UTILIZING RABBITS,
SKIN IRRIT SCORE WAS 8/8 & EYE IRRIT SCORE WAS 98.5/110. INGEST: CALCIUM
HYPOCHLORITE, IF SWALLOWED, CAUSES SEV BURNS TO DIGESTIVE TRACT & CAN BE
FATAL. CHRONIC: GENOTOXICITY: CALCIUM HYPOCHLORITE PRDCED POS RESPONSE S IN
IN-VITRO ASSAYS USING BACTERIAL SYSTEMS (AMES TEST) & CHROMOSOMAL
ABERRATIONS IN CHINESE HAMSTER FIBROBLASTS. IN WHOLE ANIMAL EXPERIMENT (MOUSE
MICRONUCLEUS TEST), EXPOSURES RANGING FROM 20-160 M G/KG (SUPDAT)
Medical Cond Aggravated By Exposure: NONE KNOWN.
First Aid: INHAL: MOVE PERSON TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP, PREF
MOUTH-TO-MOUTH. IF BRTHG IS DFCLT, GIVE OXYG. CALL MD. EYE CNTCT: IMMED FLUSH
EYES W/PLENTY OF WATER FOR AT LST 15 MIN, WHILE REMOVI NG CONTAM CLTHG &
SHOES. GET IMMED MED ATTN. SKIN CNTCT: IMMED FLUSH SKIN W/PLENTY OF SOAP
& WATER FOR AT LST 15 MIN, WHILE REMOVING CONTAM CLTHG & SHOES. IF
SKIN IRRIT OCCURS, GET MED ATTN. INGEST: I F SWALLOWED, GIVE AT LST 3-4
GLASSES OF WATER, BUT DO NOT INDUCE VOMIT. DO NOT GIVE ANYTHING BY MOUTH TO
UNCON OR CONVULSING PERSON. GET MED ATTN. NOTES TO MD: TREAT SYMPTOMATICALLY.
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Handling and Disposal
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Spill Release Procedures: USE EXTREME CAUTION IN HNDLG SPILLED MATL. CONTAM
W/ORG/COMBUST MATL MAY CAUSE FIRE/VIOLENT DECOMP. IF FIRE/DECOMP OCCURS IN
AREA OF SPILL, IMMED DOUSE W/PLENTY OF WATER. OTHERWISE, SWEEP UP ALL VISIB
LE MATL USING CLEAN, DRY SHOVEL & BROOM & DISSOLVE MATL IN WATER.
SPILLED MATL THAT HAS BEEN SWEPT UP & DISSOLVED IN WATER SHOULD BE USED
IMMED IN NORMAL APPLICATN FOR WHICH PROD IS BEING CONSUMED.
Neutralizing Agent: ONE PINT OF 35% HYDROGEN PEROXIDE SOLN PER POUND OF CALCIUM
HYPOCHLORITE TO BE NEUTRALIZED.
Waste Disposal Methods: SPILLED MATL THAT HAS BEEN SWEPT UP & DISSOLVED IN
WATER SHOULD BE USED IMMED IN NORM APPLICATN FOR WHICH PROD IS BEING USED. IF
THIS IS NOT POSS, CAREFULLY NEUT DISSOLVED MATL BY ADDING HYDROGEN PERO XIDE
(1 PINT OF 35% HYDROGEN PEROXIDE SOLN PER POUND OF CALCIUM HYPOCHLORITE TO BE
NEUT) THEN DILUTE NEUT MATL W/PLENTY OF WATER & (TRANSPORT INFO)
Handling And Storage Precautions: STORE IN A COOL, DRY, WELL-VENTD PLACE. KEEP
IN ORIGINAL CNTNR. KEEP CNTNR CLSD WHEN NOT IN USE. KEEP AWAY FROM HEAT,
SPKS, FLAMES, DIRECT SUNLIGHT & OTHER SOURCES OF HEAT, INCL LIGHTED
TOBACCO PRODS. USE ONLY CLEAN, DRY SCOOP MADE OF METAL OR PLASTIC EACH TIME
PROD IS TAKEN FROM CNTNR.
Other Precautions: DO NOT ADD PROD TO ANY DISPENSING DEVICE CONTAINING REMNANTS
OF ANY OTHER PROD. SUCH USE MAY CAUSE VIOLENT RXN LEADING TO FIRE OR EXPLO.
ADD THIS PROD ONLY TO WATER. MAY CAUSE FIRE OR EXPLO IF MIXED W /OTHER CHEMS.
FIRE MAY RSLT IF CONTAM W/ACIDS OR EASILY COMBUST MATLS SUCH AS OIL,
KEROSENE, (STATE REG INFO)
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Fire and Explosion Hazard Information
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Flash Point Text: NONE
Extinguishing Media: WATER ONLY.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT
(FP N) FOR POSSIBLE EXPOSURE TO HAZARDOUS GASES.
Unusual Fire/Explosion Hazard: PRODUCT DECOMPOSES AT 180C RELEASING OXYGEN GAS.
CONTAINER MAY RUPTURE.
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Control Measures
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Respiratory Protection: IF DUSTY CNDTNS ENCOUNTERED, USE NIOSH APPRVD RESP
W/ACID GAS CARTRIDGE & DUST PREFILTER. RESP USE LIMITS MADE BY NIOSH/MFR
MUST BE OBSERVED. RESP PROT PROGRAMS MUST BE I/A/W 29CFR 1910.134. EXPOS LIM
S:8-HR TIME WEIGHTED AVERAGE (TWA); 15-MIN SHORT-TERM EXPOS LIM (STEL): NO
OCCUP EXPOS LIMS ESTABLISHED BY OSHA/ACGIH. PPG (PEL): 1 MG/CUM; TWA 2 MG/CUM
STEL.
Ventilation: NONE REQUIRED UNLESS DUSTY CONDITIONS ARE ENCOUNTERED.
Protective Gloves: NATURAL OR SYNTHETIC RUBBER GLOVES.
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES & FULL LENGTH FACESHIELD
(FP N).
Other Protective Equipment: ANSI APPROVED EYE WASH AND DELUGE SHOWER (FP N).
BOOTS, APRONS OR CHEMICAL SUITS SHOULD BE WORN WHEN NECESSARY TO PREVENT SKIN
CONTACT.
Work Hygienic Practices: PERSONAL PROTECTIVE CLOTHING AND USE OF EQUIPMENT MUST
BE IN ACCORDANCE WITH 29 CFR 1910.132 (GENERAL REQUIREMENTS), 133 (EYE AND
FACE PROTECTION) AND 138 (HAND PROTECTION).
Supplemental Safety and Health: EFTS OF OVEREXP: PRDCED NO CMPD RELATED
CHROMOSOMAL ABNORMS. CARCINOGENISIS: ALTHOUGH NO STUDY CONDUCTED W/CALCIUM
HYPOCHLORITE, CARCINOGENIC POTNTL OF SODIUM HYPOCHLORITE STUDIED IN F344
RATS. AFTER 104 WKS OF DRINKING WATER CONTAINING UP TO 2000 PPM SODIUM
HYPOCHLORITE, (OTHER INFO)
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Physical/Chemical Properties
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Boiling Point: =180.C, 356.F
B.P. Text: DECOMPOSES
Decomp Temp: =180.C, 356.F
PH: ALKALINE
Solubility in Water: 217 G/L @ 27C
Appearance and Odor: WHITE TABLETS WITH BLUE COLORANT; SLIGHT CHLORINE ODOR.
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Reactivity Data
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Stability Indicator: NO
Stability Condition To Avoid: CONTAMINATION. EXCESSIVE HEAT ABOVE 177C.
UNSTABLE ABOVE 177C.
Materials To Avoid: ACIDS. COMBUSTIBLE MATERIALS. ORGANICS. REDUCING AGENTS.
Hazardous Decomposition Products: ACID OR AMMONIA CONTAMINATION WILL RELEASE
TOXIC GASES. EXCESSIVE HEAT WILL CAUSE DECOMPOSITION RESULTING IN THE RELEASE
OF OXYGEN AND CHLORINE GAS.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Toxicological Information: ACUTE INHAL LC50: (RAT) NO MORTALITY AT 3.5 MG/L (1
HR). IRRITATING. ACUTE DERMAL LD50: (RABBIT) >1000 MG/KG. SLIGHT TO VERY
LOW TOX. SKIN IRRIT: CAUSES BURNS. EYE IRRIT: CAUSES BURNS. ACUTE ORAL LD50 :
(RAT) 850 MG/KG. SLIGHT TO VERY LOW TOX. CHRONIC EFTS/CARCINOGENICITY: PROD
IS NOT LISTED AS CARCIN OR SUSPECTED CARCIN BY NTP, IARC OS OSHA.
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Ecological Information
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Ecological: HIGHLY TOXIC TO AQUATIC LIFE, 0.088 MG/L (BLUEGILL) 96-HR LC50.
--OTHER INFO: CHLORINE IN THEIR DRINKING WATER. NO DIFFERENCE IN FERTILITY,
GROWTH, BLOOD PARAMETERS OR SPECIFIC ORGAN TOXICITY OBSERVED BETWEEN CONTROL
& EXPOSED ANIMALS. TWO SEPARATE ANIMAL STUDIES CONDUCTED BY DIFFERENT
GOVERNMENT AGENCIES DETERMINED THAT CHLORINATION OF MUNICIPAL DRINKING WATER
DID NOT RSLT IN TOXICITY TO DEVELOPI NG MOUSE FETUS. SAFE HNDLG OF MATL ON
LONG-TERM BASIS SHOULD EMPHASIZE MINIMIZING RPTD ACUTE EXPOS.
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MSDS Transport Information
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Transport Information: USA DOT DESCRIPTION - PROPER SHIPPING NAME: CALCIUM
HYPOCHLORITE, HYDRATED. HAZARD CLASS: 5.1 (OXIDIZER). IDENTIFICATION NUMBER:
UN2880. PACKING GROUP: II. REPORTABLE QUANTITY: 10 LBS/4.5 KG. --WASTE DISP
METH: FLUSH TO SEWER. NOTE: ONLY PROPERLY NEUTRALIZED MATL SHOULD BE FLUSHED
TO SEWER. UNNEUT MATL CAN CAUSE ENVIRONMENTAL DMG TO RECEIVING WATER OR CAN
INTERFERE W/TREATMENT PLANT OPERATION. FOR ON-SITE NEUTRALIZATION, CAREFULLY
& SLOWLY POUR APPROP QTY OF 35% HYDROGEN PEROXIDE SOLN OVER ALL SPILLED
MATL THEN FLUSH AREA W/PLENTY OF WATER. CARE MUST BE TAKEN WHEN USING OR
DISPOSING OF CHEM (S ARA REG INFO)
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Regulatory Information
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Sara Title III Information: SARA TITLE III: SARA (311,312) HAZ CLASS: ACUTE
HEALTH HAZ, REACTIVE HAZ, FIRE HAZ. SARA (313) CHEMS: NOT LISTED. SARA
SECTION 302: NOT LISTED AS AN EXTREMELY HAZ SUBSTANCE. --TRANSPORT INFO:
MATLS &/ OR THEIR CNTNRS TO PVNT ENVIRONMENTAL CONTAM. IT IS YOUR DUTY TO
DISPOSE OF CHEM MATLS &/OR THEIR CNTNRS I/A/W CLEAN AIR ACT, CLEAN WATER
ACT, RESOURCE CONSERVATION & RECOVERY ACT (RCRA), AS WELL AS A NY OTHER
RELEVANT FED, STATE OR LOCAL LAWS/REGS REGARDING DISPOSAL. RCRA: WASTE
CALCIUM HYPOCHLORITE & CONTAM SOLIDS/MATLS FROM SPILL CLEANUP ARE D001
HAZ WASTE AS PER 40 CFR 261.21(A)(4) & MUST BE DI SPOSED OF ACCORDINGLY
UNDER RCRA.
Federal Regulatory Information: USA TSCA: THIS PROD IS LISTED ON THE TSCA
INVENTORY. EUROPE EINECS: THIS PROD IS LISTED ON EINECS. CANADA DSL: THIS
PROD IS LISTED ON THE CANADIAN DSL. AUSTRALIA AICS: THIS PROD IS LISTED ON
AICS. KOR EA ECL: THIS PROD IS LISTED ON ECL. JAPAN MITI (ENCS): THIS PROD IS
LISTED ON MITI. CERCLA HAZARDOUS SUBSTANCE: LISTED IN TABLE 302.4 OF 40 CFR
PART 302 AS HAZARDOUS SUBSTANCE W/REPORTABLE QUANTITY OF 10 LBS. RELEASES TO
AIR, LAND OR WATER WHICH EXCEED RQ MUST BE REPORTED TO NRC, 800-424-8802.
HAZAR D RATING SYSTEM (/NFPA): HEALTH 3, FLAMMABILITY 0, REACTIVITY 1
(OXIDIZER). FIFRA: THIS PROD IS REGISTERED W/EPA AS A PESTICIDE.
State Regulatory Information: N/P. --OTHER PRECS: GASOLINE, PAINT PRODS &
MOST OTHER ORGANIC MATLS. DO NOT REUSE CNTNR. RESIDUAL MATL REMAINING IN
EMPTY DRUM CAN REACT TO CAUSE FIRE. THOROUGHLY FLUSH EMPTY CNTNR W/WATER THEN
DESTR OY BY PLACING IN TRASH COLLECTION. DO NOT CONTAMINATE WATER, FOOD OR
FEED BY STORAGE OR DISPOSAL. PHYSICAL DATA - BULK DENSITY: N/A. HEAT OF
SOLUTION: SLIGHTLY EXOTHERMIC.
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Other Information
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Other Information: THE FOLLOWING HAS BEEN REVISED SINCE THE LAST ISSUE OF THIS
MSDS: DATE; EDITION; SECTIONS 11, 12, 13 AND 15 HAVE BEEN UPDATED. PREVIOUS
REVISION DATE: 08/15/1997. PREVIOUS EDITION #: 003. --SUPDAT: TH ERE WAS NO
EVID THAT THIS CHEM PRDCED ANY CARCINOGENIC RESPONSE. IN ADDN, THIS EXPOS DID
NOT RSLT IN ANY ADVERSE EFTS IN BLOOD, CLINICAL CHEM OR OTHER TARGET ORGANS.
ONE OF MAJOR USES OF CALCIUM HYPOC HLORITE IS SOURCE OF CHLORINE FOR WATER
SANITIZATION IN DRINKING & RECREATIONAL WATER. STUDIES HAVE BEEN
CONDUCTED TO DETERM LONG-TERM EFTS OF CHLORINATED DRINKING WATER. SEVEN
GENERATIONS OF RATS WER E GIVEN 100 PPM (ECOLOGICAL INFO)
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HAZCOM Label
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MSDS NAME: CHLORINATING TABLETS, 0407A
Company: PPG INDUSTRIES INC
Street: ONE PPG PLACE
City: PITTSBURGH PA
Zipcode: 15272
Health Emergency Phone: 304-843-1300
Label Required IND: Y
Date Of Label Review: 10/13/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: INHAL: DUST & PARTICLES IN RESP TRACT CAN
LEAD TO IRRIT OF TISS & CAUSE UPPER RESP TRACT IRRIT, NASAL CONGESTION,
COUGH, SORE THROAT, LARYNGITIS & SHORTNESS OF BREATH. PULM EDEMA (FLUID
IN LUNG ) MAY BE PRDCED. IF NOT TREATED IMMED, PULM EDEMA CAN BE LIFE
THREATENING. SINCE PROD IS IN GRANULAR FORM, PARTICLES OF RESPIRABLE SIZE ARE
NOT GENERALLY ENCOUNTERED. EYE/SKIN: CALCIUM HYPOCHLORITE IS CORR TO EYES.
DUST CAN CAUSE SEV IRRIT & BLNDNESS. SKIN CONT MAY CAUSE SEV IRRIT,
BURNS/TISS DESTRUCTION. INGEST: CAUSES SEV BURNS TO DIGEST TRACT & CAN BE
FATAL. CHRONIC: HAS CAUSED BIRTH DEFECTS IN LAB ANIMALS.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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