CLEARON CORP -- HALOBROM MSDT
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Material Safety Data Sheet
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MSDS Num: CJPNZ
MSDS NAME: HALOBROM MSDT
Responsible Party
Name: CLEARON CORP
Address: 95 MACCORKLE AVE SW
City: SOUTH CHARLESTON WV 25303
Info Phone: 304-746-3000
Emergency Phone Number: (800)424-9300
Chemtrec IND/Phone: (800)424-9300
Proprietary Ind: Y
Review Ind: Y
Published: Y
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Contractor Summary
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Name: CLEARON CORP
Address: 95 MACCORKLE AVE SW
City: SOUTH CHARLESTON WV 25303
Phone: 304-746-3000
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Item Description Information
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: LD50: (ORAL, RAT) 1500 MG/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: CAUSES BURNS. TOXIC BY INHALATION. MAY CAUSE SKIN
SENSITIZATION. EYES: SEVERE IRRITANT. MAY CAUSE TEMPORARY OR POSSIBLY
PERMANENT EYE INJURY. SKIN: EXPOSURE TO WET SKIN MAY CAUSE SEVERE BURNS. CAN
CAU SE SENSITIZATION IN SUSCEPTIBLE INDIVIDUALS AND PROLONGED SKIN CONTACT
MAY CAUSE SUPERFICIAL BURNS. INHALATION: IRRITANT TO UPPER RESPIRATORY TRACT,
NOSE, THROAT AND LUNGS. CAN CAUSE SHORTNESS OF BREA TH, HEADACHES AND NAUSEA.
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
First Aid: EYES: HOLDING EYELIDS APART, FLUSH EYES IMMED W/LG AMTS OF WATER FOR
AT LST 15 MIN. GET MED ATTN IMMED. SKIN: WASH AFFECTED AREAS THOROUGHLY
W/MILD SOAP & PLENTY OF WATER. REMOVE & WASH CONTAM CLTHG T HOROUGHLY
BEFORE REUSE. DO NOT TAKE CLTHG HOME TO BE LAUNDERED. CONSULT MD IF IRRIT IS
OBSERVED & PERSISTS. INGEST: IF SWALLOWED, WASH MOUTH THOROUGHLY W/PLENTY
OF WATER & GIVE TWO GLASSES OF WATER TO DRINK. GET MED ATTN IMMED. NEVER
GIVE UNCON PERSON ANYTHING TO DRINK. INHAL: IN CASE OF DUST INHAL/BRTHG FUMES
RELEASED FROM HEATED MATL, REMOVE PERSON TO FRESH AIR. KEEP QUIET & WARM.
APPLY ARTF RES P IF NEC & GET MED ATTN IMMED.
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Handling and Disposal
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Spill Release Procedures: FOR ALL TRANSPORTATION ACCIDENT, CALL CHEMTREC AT
800-424-9300. WEAR NIOSH APPRVD FULL-FACEPIECE AIR-PURIFYING RESP. EQUIP
W/CHEM CARTRIDGE FOR PROT AGAINST HALOGEN GASES & DUST/MIST FILTERS. WEAR
COM PAT, CHEM RESIST GLOVES. MATL IS SEV IRRITANT. IF EXPOSED TO MATL DURING
CLEAN-UP OPERATIONS, IMMED REMOVE ALL CONTAM CLTHG & WASH EXPOSED SKIN
AREAS W/SOAP & WATER. SEE FIRST AID MEASURES. (SUPDAT)
Waste Disposal Methods: FOR DISPOSAL, INCINERATE THIS MATERIAL AT A FACILITY
THAT COMPLIES WITH FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
Handling And Storage Precautions: AVOID CNTCT W/CLTHG & OTHER COMBUST
MATLS. KEEP CNTNRS TIGHTLY CLSD WHEN NOT IN USE. MATL IS SEV IRRITANT. SEE
EXPOS CTLS/PERSONAL PROT, PRIOR TO HNDLG. STORE IN DRY, COOL, DARK &
WELL-VENTD AREA AWAY FROM COMBUST MATLS. STORE AWAY FROM EXCESS HEAT (EG,
STEAMPIPES, RADIATORS) & FROM IGNIT SOURCES.
Other Precautions: CONTAINERS HAZARDOUS WHEN EMPTY. SINCE EMPTIED CONTAINERS
RETAIN PRODUCT RESIDUE (VAPORS AND/OR LIQUID) FOLLOW ALL MSDS AND LABEL
WARNINGS EVEN AFTER CONTAINER IS EMPTIED.
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Fire and Explosion Hazard Information
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Extinguishing Media: DRY POWDER, CARBON DIOXIDE OR WATER SPRAY.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT
(FP N). USE WATER SPRAY TO COOL CONTAINERS EXPOSED TO FIRE. MINIMIZE
EXPOSURE. DO NOT BREATHE FUMES. CONTAIN RUN-OFF.
Unusual Fire/Explosion Hazard: STRONG OXIDIZING AGENT. FORMS EXPLOSIVE MIXTURES
W/COMBUSTIBLE, ORGANIC OR OTHER EASILY OXIDIZABLE MATERIALS. WHEN HEATED TO
DECOMPOSITION, MAY RELEASE POISONOUS & CORROSIVE FUMES OF HYDROGEN
BROMIDE, BROMINE GAS, NITROGEN OXIDES & HYDROGEN CHLORIDE.
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Control Measures
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Respiratory Protection: RESP PROT PROGRAM MEETING OSHA 1910.134 & ANSI
Z88.2 REQS MUST BE FOLLOWED WHENEVER WORKPLACE CNDTNS WARRANT RESP'S USE.
NONE REQD UNDER NORM CNDTNS. WHEN DUSTY CNDTNS ENCOUNTERED, WEAR NIOSH APPRVD
H ALF-MASK W/CHEM CARTRIDGE FOR PROT AGAINST CHLORINE GAS & DUST/MIST
PREFILTER & AIR-PURIFYING RESP. AIR PURIFYING RESPS SHOULD BE EQUIPPED
(STATE REG INFO)
Ventilation: USE LOC EXHST VENT, ESP UNDER DUST CNDTNS, W/MINIMUM CAPTURE
VELOCITY OF 150 FT/MIN (0.75 M/SEC) AT POINT OF VAP EVOLUTION. REFER TO
(STATE REG INFO)
Protective Gloves: BUTYL RUBBER GLOVES. MATL IS POSS SKIN SENSITIZER. (STATE
REG INFO)
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES & FULL LENGTH FACESHIELD
(FP N).
Other Protective Equipment: ANSI APPROVED EYE WASH AND DELUGE SHOWER (FP N).
USE CHEMICALLY RESISTANT APRON OR OTHER IMPERVIOUS CLOTHING TO AVOID
PROLONGED OR REPEATED SKIN CONTACT.
Work Hygienic Practices: DO NOT EAT, DRINK OR SMOKE UNTIL SHOWERING AND
CHANGING CLOTHES.
Supplemental Safety and Health: SPILL PROC: REMOVE ALL CONTAM CLTHG PROMPTLY.
WEAR PROT CLTHG MADE OF BUTYL RUB TO AVOID SKIN CNTCT. FOR FURTHER INFO, SEE
EXPOS CTLS/PERSONAL PROT, SECTION VIII. PROCEDURES - EVACUATE SPILL AREA. KEE
P DUST TO MINIMUM. TRANSFER SPILLED MATL TO SUITABLE CNTNRS FOR
RECOVERY/DISP. FLUSH CLEANED AREA W/WATER (OTHER INFO)
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Physical/Chemical Properties
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M.P/F.P Text: N/A (DECOMPOSES)
Decomp Temp: >160.C, 320.F
Vapor Pres: 9.35X10(-3)PA
Spec Gravity: 1.8-2 (H*2O=1)
Solubility in Water: 0.2 G/100ML @ 25C
Appearance and Odor: WHITE TO OFF-WHITE TABLET; FAINT HALOGEN ODOR.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: STABLE UNDER NORM CNDTNS OF STORAGE, SHIPMENT
&/OR USE. SEE HNDLG & STOR, SECTION VII, FOR SPECIFIED CNDTNS. AVOID TEMPS
>160C/320F. NOTE: OXIDIZER, MATL YIELDS (STATE REG INFO)
Materials To Avoid: OXIDIZING AGENTS, COMBUSTIBLE ORGANIC MATERIALS, BASES.
Hazardous Decomposition Products: HYDROGEN BROMIDE, BROMINE GAS AND HYDROGEN
CHLORIDE.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Toxicological Information: ACUTE TOX: INHAL LD50-0.53MG/1/4 HR (RAT). DERMAL
LD50->2000MG/KG (RAT). IRRIT-SEV IRRIT, MAY BE CORR (DERMAL-RABBIT).
SENSIT-MILD SENSITIZER (DERMAL-GPG. CHRONIC TOX:NOT AVAIL. MUTAGENIC BY AMES
TEST .
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Ecological Information
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Ecological: AQ TOX - RAINBOW TROUT (96-HR LC50)-0.4 MG/L (STATIC). BLUEGILL
SUNFISH (96-HR LC50)-0.46 MG/L (STATIC). SHEEPSHEAD MINNOW (96-HR LDC50)-1.6
MG/L (ACUTE FLOW THRU). EASTERN OYSTER (96-HR LD50)-1.2 MG/ L (ACUTE FLOW
THRU). MYSID SHRIMP (96-HR LC50) - 1.9 MG/L (ACUTE FLOW THRU). DAPHNIA MAGNA
(48-HR LD50)-0.75 MG/L (STATIC). AVIAN TOX - BOBWHITE QUAIL (ACUTE ORAL
LD50)-1839 MG/KG. BOBWHITE QUAIL (DIE TARY LC50)->5620 PPM. MALLARD DUCK
(DIETARY LD50)->5620 PPM. ENVIRONMENTAL TOX DAT MENTIONED ARE FROM STUDIES
CONDUCTED ON ACTIVE INGRED.
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MSDS Transport Information
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Transport Information: MATL REGULATED AS DOT HAZ MATL. DOT DESCRIPTION FROM HAZ
MATLS TABLE 49 CFR 172.101: LAND (US DOT): OXIDIZING SOLID, N.O.S., 5.1, UN
1479, PGII. LABEL:OXIDIZER (5.1). WATER (IMO): OXIDIZING SOLID, N.O .S.
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Regulatory Information
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Sara Title III Information: SECTION 311/312 CATEGORIZATION (40CFR 370): PROD
CATEGORIZED AS IMMED & DELAYED HLTH & REACTIVITY PHYSICAL HAZ.
SECTION 313 INFO (40CFR 372):PROD DOES NOT CNTN CHEM LISTED IN SECTION 313
AT/ABOVE DE M INIMIS CONCS.
CERCLA:MATL HAS RQ UNDER CERCLA & SARA TITLE III SECTION 304. MAT'S HAZ
WASTE # & RQ IS LISTED BELOW. RELS OF MATL IN EXCESS OF ITS RQ MUST BE
REPORTED TO NRC (800-424-8802) & TO APPROP STATE & LOC EMER RESPONSE
ORGANIZATIONS. IGNITABILITY, 100LBS. WASTE CLASSIFICATION: MATL CLASSIFIED AS
RCRA HAZ WASTE W/CHARACTERISTIC OF IGNITABILITY, HAZ WASTE NUMBER: D001.
Federal Regulatory Information: OSHA HAZ CLASSIFICATION: OXIDIZER, SEV
IRRITANT. WORKPLACE CLASSIFICATION: PROD CONSIDERED HAZ UNDER OSHA HAZ
COMMUNICATION STD (29CFR 1910.1200). PROD IS SUBJECT TO REG UNDER CANADIAN
PEST CONTROL PR ODS ACT (P.C.P. ACT). THEREFORE, PROD IS EXCLUDED FROM
SUPPLIER LABELING & MSDS REQS AS SEPCIFIED IN SECTION 12 OF HAZ PRODS
ACT. UNITED STATES: PROD IS SUBJECT TO REG UNDER US FED INSECTICIDE, FUNGIC
IDE & RODENTICIDE ACT (FIFRA) & IS THEREFORE EXEMPT FROM US TOX
SUBSTANCE CONTROL ACT (TSCA) INVENTO RY LISTING REQS. EEC: REPORTED IN EINECS
(# 2511715)
State Regulatory Information: RESP PROT: W/NIOSH APPRVD CHEM CARTRIDGE FOR PROT
AGAINST HALOGEN GASES. VENT: CURRENT EDITION OF "INDUSTRIAL VENT: A MANUAL OF
RECOM PRACTICE" PUB BY ACGIH FOR INFO ON DESIGN, INSTALLATION, USE & MAI
NT OF EXHST SYSTEMS. PROT GLOVES: AVOID SKIN CNTCT. GLOVES SHOULD BE REMOVED
& REPLACED IMMED IF THERE IS ANY INDICATION OF DEGRADATION OR CHEM
BREAKTHRU. RINSE & REMOVE GLOVES IMMED AFTER USE. WASH H ANDS W/SOAP
& WATER. CNDTNS TO AVOID (STABILITY): OXYGEN READILY TO STIMULATE
COMBUSTION OF ORGANIC MATTER.
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Other Information
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Other Information: MSDS REVISION STATUS: REVISION TO FORMAT OF CLEARON CORP.
REFERENCE: AMERICAN NATL STD FOR HAZ INDUS CHEMS - MSDS - PREPARATION, ANSI
Z400.1-1993. INFO IN THIS MSDS SHOULD BE PROVIDED TO ALL WHO USE, HNDL,
STORE, TRANSPORT OR OTHERWISE BE EXPOSED TO PROD. INFO PREPARED FOR GUIDANCE
OF PLANT ENGINEERING, OPERATIONS & MANAGEMENT & FOR PERS WORKING
WITH/HNDLG PROD. SUPDAT: TO SEWAGE TREATMENT FACILIT Y. SEE DISP
CONSIDERATIONS, SECTION XIII, FOR INFO REGARDING DISP OF CONTAINED SPILLS.
VENT AREA & WASH SPILL SITE AFTER MATL PICKUP COMPLETE. CAUTION:KEEP
SPILLS & CLEANING RUNOFF OUT OF MUNICIPAL SE WERS & OPEN BODIES OF
WATER.
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HAZCOM Label
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MSDS NAME: HALOBROM MSDT
Assigned IND: Y
Company: CLEARON CORP
Street: 95 MACCORKLE AVE SW
City: SOUTH CHARLESTON WV
Zipcode: 25303
Health Emergency Phone: (800)424-9300
Label Required IND: Y
Date Of Label Review: 10/12/1999
Status Code: A
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: Slight
Hazard And Precautions: DECOMPOSITION PRODUCTS MAY BE HARMFUL. ACUTE: CAUSES
BURNS. TOXIC BY INHALATION. MAY CAUSE SKIN SENSITIZATION. EYES: SEVERE
IRRITANT. MAY CAUSE TEMPORARY OR POSSIBLY PERMANENT EYE INJURY. SKIN: EXPOSU
RE TO WET SKIN MAY CAUSE SEVERE BURNS. PROLONGED SKIN CONTACT MAY CAUSE
SUPERFICIAL BURNS. INHALATION: IRRITANT TO UPPER RESPIRATORY TRACT, NOSE,
THROAT AND LUNGS. CAN CAUSE SHORTNESS OF BREATH, HEADA CHES AND NAUSEA.
CHRONIC: MAY CAUSE SKIN SENSITIZATION IN SUSCEPTIBLE INDIVIDUALS.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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