POST APPLE SCIENTIFIC INC -- C3320-3322-3330, CUPRIC NITRATE
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Material Safety Data Sheet
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MSDS Num: CLDRF
MSDS NAME: C3320-3322-3330, CUPRIC NITRATE
Responsible Party
Name: POST APPLE SCIENTIFIC INC
Address: 8893 GULF ROAD
Box: UNKNOW
City: NORTH EAST PA 16428-4298
Info Phone: 814-725-3330 / FAX: 814-725-8103
Emergency Phone Number: 800-424-9300
Chemtrec IND/Phone: (800)424-9300
Published: Y
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Contractor Summary
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Name: CHEM SCIENTIFIC INC
Address: 1250 WASHINGTON ST
City: NORWOOD MA 02062
Phone: 781-440-0900
Contract Number: MDA414-01-P-0838
Name: CHEM SCIENTIFIC INC
Address: 1250 WASHINGTON ST
City: NORWOOD MA 02062
Phone: 781-440-0900
Contract Number: MDA414-01-P-0839
Name: CHEM SCIENTIFIC INC
Address: 1250 WASHINGTON ST
City: NORWOOD MA 02062
Phone: 781-440-0900
Contract Number: MDA414-01-P-2037
Name: POST APPLE SCIENTIFIC INC
Address: 8893 GULF ROAD
Box: UNKNOW
City: NORTH EAST PA 16428-4298
Phone: 814-725-3330
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Ingredients
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Cas: 3251-23-8
RTECS #: QU7400000
Name: CUPRIC NITRATE
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
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Health Hazards Data
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LD50 LC50 Mixture: ORAL RAT LD50: 940 MG/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Effects of Exposure: TARGET ORGANS: BLOOD, KIDNEYS, LIVER, CENTRAL NERVOUS
SYSTEM, VASCULAR SYSTEM. ACUTE: HARMFUL IF SWALLOWED, INHALED, OR ABSORBED
THROUGH SKIN. MATERIAL IS EXTREMELY DESTRUCTIVE TO TISSUE OF MUCOUS ME
MBRANES, UPPER RESPIRATORY TRACT, EYES, AND SKIN. INHALATION MAY BE FATAL AS
RESULT OF SPASM, INFLAMMATION AND EDEMA OF LARYNX AND BRONCHI, CHEMICAL
PNEUMONITIS AND PULMONARY EDEMA. CHRONIC COPPER POI SONING IS TYPIFIED BY
HEPATIC CIRRHOSIS, BRAIN DAMAGE AND DEMYELINATION, KIDNEY DEFECTS, AND COPPER
DEPOSITION IN CORNEA AS EXEMPLIED BY HUMANS WITH WILSON'S DISEASE. IT HAS
ALSO BEEN REPORTED THAT(C ONTD. SEE "TOXICOLOGICAL")
Signs And Symptions Of Overexposure: SYMPTOMS OF EXPOSURE MAY INCLUDE BURNING
SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE,
NAUSEA AND VOMITING, DESTRUCTION OF TISSUE OF THE MUCOUS MEMBRANES AND UPPER
RESPIRAT ORY TRACT, EYES, AND SKIN. INHALATION MAY BE FATAL AS A RESULT OF
SPASM, INFLAMATION, AND EDEMA OF THE LARYNX AND BRONCHI, CHEMICAL PNEUMONITIS
AND PULMONARY EDEMA.
First Aid: IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING
AND SHOES. ASSURE ADEQUATE FLUSHING OF THE EYES BY SEPARAT ING THE EYELIDS
WITH FINGERS. IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF SWALLOWED,
WASH OUT MOUTH WITH WATER PROVIDED PE RSON IS CONSCIOUS. CALL A PHYSICIAN.
REMOVE AND WASH CONTAMINATED CLOTHING PROMPTLY.
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Handling and Disposal
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Spill Release Procedures: EVACUATE AREA. WEAR SELF CONTAINED BREATHING
APPARATUS, RUBBER BOOTS AND HEAVY RUBBER GLOVES. USE NONSPARKING TOOLS. SWEEP
UP, PLACE IN BAG AND HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATED
AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
Waste Disposal Methods: THIS MATERIAL SHOULD BE DISSOLVED IN 1) WATER; 2) ACID
SOLUTION OR 3) OXIDIZED TO A WATER SOLUBLE STATE. PRECIPITATE THE MATERIAL AS
THE SULFIDE, ADJUSTING THE PH OF THE SOLUTION TO 7 TO COMPLETE PREC
IPITATION. FILTER THE INSOLUBLES AND DISPOSE OF THEM IN A HAZARDOUS WASTE
SITE. DESTROY ANY EXCESS S ULFIDE WITH SODIUM (CONTD. SEE "TOXICOLOGICAL")
Handling And Storage Precautions: KEEP TIGHTLY CLOSED. DO NOT STORE NEAR, NOR
ALLOW CONTACT WITH, CLOTHING AND OTHER COMBUSTIBLE MATERIAL. STORE IN A COOL,
DRY PLACE. USE ONLY IN A CHEMICAL FUME HOOD. DO NOT BREATHE DUST. DO NOT GET
I N EYES, ON SKIN, ON CLOTHING. WASH THOROUGHLY AFTER HANDLING. A CORROSIVE ,
HARMFUL SOLID.
Other Precautions: WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR, CHEMICAL
RESISTANT GLOVES, SAFETY GOGGLES, OTHER PROTECTIVE CLOTHING. WEAR FACESHIELD
(8-INCH MINIMUM). PROVIDE SAFETY SHOWER AND EYE BATH.
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Fire and Explosion Hazard Information
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Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL POWDER, OR APPROPRIATE FOAM.
Fire Fighting Procedures: WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES.
Unusual Fire/Explosion Hazard: OXIDIZER: UNUSUAL FIRE AND EXPLOSIVES HAZARDS.
MAY ACCELERATE COMBUSTION. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE. EMITS
TOXIC FUMES UNDER FIRE CONDITIONS.
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Control Measures
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Respiratory Protection: WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR
Ventilation: USE ONLY IN CHEMICAL FUME HOOD.
Protective Gloves: WAR CHEMICAL RESISTANT GLOVES.
Eye Protection: WEAR SAFETY GOGGLES.
Other Protective Equipment: WEAR OTHER PROTECTIVE CLOTHING, RUBBER BOOTS, HEAVY
RUBBER GLOVES, USE NON SPARKING TOOLS. PROVIDE SAFETY SHOWER AND EYE BATH.,
FACE SHIELD (8-INCH MINIMUM).
Work Hygienic Practices: DO NOT BREATHE DUST. DO NOT GET ON SKIN, IN EYES, ON
CLOTHING. WASH THOROUGHLY AFTER HANDLING. KEEP TIGHTLY CLOSED.
Supplemental Safety and Health: SYNONYMS: COPPER DINITRATE; COPPER (II)
NITRATE; COPPER (2+) NITRATE; CUPRIC DINITRATE; CUPRIC NITRATE. ITEM
NUMBER: C208.
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Physical/Chemical Properties
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HCC: D1
Melt/Freeze Pt: =114.C, 237.2F
Spec Gravity: 2.320
Solubility in Water: WATER SOLUBLE.
Appearance and Odor: SOLID
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: HEAT, MOISTURE.
Materials To Avoid: REDUCING AGENTS, ORGANIC MATERIALS, FINELY POWDERED METALS
Hazardous Decomposition Products: TOXIC FUMES OF NITROGEN OXIDES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
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Toxicological Information
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Toxicological Information: RETECS NO: QU7400000 NITRIC ACID, COPPER (2+)SALT:
IRRITATION DATA: SKIN -RBT 500 MG SEV; EYE-RBT 100 MG SEV; EYE-RBT 100 MG/4S
RINSE SEV. TOXICITY DATA: ORAL-RAT LD50:940 MG/KG; ONLY SELECTED REGISTR Y OF
TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RETECS) DATA IS PRESENTED HERE. SEE
ACTUAL ENTRY IN RTECS FOR COMPLETE INFORMATION. (CONTD. FROM "HEALTH") COPPER
POISONING HAS LEAD TO HEMOLYTIC ANEMIA AND ACCELERATES ARTERIOSCLEROSIS.
(CONTD. FROM "WASTE DISPOSAL") HYPOCHLORITE. NEUTRALIZE THE SOLUTION BEFORE
FLUSHING DOWN THE DRAIN. OBSERVE ALL FEDERAL, STATE, AND LOCAL ENVIRONMENTAL
REGULATIONS.
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Ecological Information
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Ecological: DATA NOT YET AVAILABLE.
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MSDS Transport Information
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Transport Information: CONTACT POST APPLE SCIENTIFIC, INC. FOR TRANSPORTATION
INFORMATION. BY TELEPHONE (814-725-3330): NITRATES, INORGANIC, N.O.S. (CUPRIC
NITRATE); CLASS: 5.1; UN 1477; PKG I I I; IF EQUAL TO OR LESS THAN 5.0 KG
(11 LBS) NET CAPACITY EACH FOR SOLIDS, PACKED IN STRONG OUTER PACKAGINGS,
SHIP AS LIMITED QUANTITY.
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Regulatory Information
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Sara Title III Information: EPA TSCA CHEMICAL INVENTORY, JUNE 1993. THIS
PRODUCT IS SUBJECT TO SARA SECTION 313 REPORTING REQUIREMENTS
Federal Regulatory Information: EPA FIFRA 1988 PESTICIDE SUBJECT TO
REGISTRATION OR RE-REGISTRATION FEREAC 54,7740,89.
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Other Information
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Other Information: DESIGNATIONS: HEALTH: 2; FLAMMABILITY: 0; REACTIVITY: 0. SEE
MANUFACTURER'S MSDS FOR LIST OF EXPOSURE LIMITS FOR VARIOUS COUNTRYS.
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Transportation Information
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Trans ID NO: 157313
MSDS NAME: C3320-3322-3330, CUPRIC NITRATE
MSDS Prepared Date: 12/14/1998
Review Date: 06/05/2001
Tech Entry NOS Shipping Nm: (CUPRIC NITRATE)
Multiple KIT Number: 0
Unit Of Issue: CY
Type Of Container: CYLINDER
Additional Data: TRANSPORTATION DATA PER MANUFACTURER BY TELEPHONE
(814-725-3330). PROPER SHIPPING NAME: NITRATES, IN ORGANIC, N.O.S. (CUPRIC
NITRATE); HAZARD CLASS: 5.1; UN 1477; PKG: I I I. IF EQUAL TO OR LESS THAN
5.0 KG (11 LB) NET CAPACITY EACH, SHIP AS LIMITED QUANTITY.
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Detail DOT Information
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DOT PSN Code: KEJ
DOT Proper Shipping Name: NITRATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN ID Num: UN1477
DOT Packaging Group: III
Label: 5.1
Packaging Exception: 152
Non Bulk Pack: 213
Bulk Pack: 240
Max Qty Pass: 25 KG
Max Qty Cargo: 100 KG
Vessel Stow Req: A
Water/Ship/Other Req: 46
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Detail IMO Information
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IMO PSN Code: KOT
IMO Proper Shipping Name: NITRATES, INORGANIC, N.O.S. o
IMDG Page Number: 5162
UN Number: 1477
UN Hazard Class: 5.1
IMO Packaging Group: II/III
Subsidiary Risk Label: -
EMS Number: 5.1-05
MED First Aid Guide NUM: 235
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Detail IATA Information
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IATA PSN Code: RUS
IATA UN ID Num: 1477
IATA Proper Shipping Name: NITRATES, INORGANIC, N.O.S.
IATA UN Class: 5.1
IATA Label: OXIDIZER
UN Packing Group: III
Packing Note Passenger: 516
Max Quant Pass: 25KG
Max Quant Cargo: 100KG
Packaging Note Cargo: 518
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Detail AFI Information
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AFI PSN Code: RUS
AFI Proper Shipping Name: NITRATES, INORGANIC, N.O.S.
AFI Hazard Class: 5.1
AFI UN ID NUM: UN1477
AFI Packing Group: III
Special Provisions: P5
Back Pack Reference: A9.8
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HAZCOM Label
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MSDS NAME: C3320-3322-3330, CUPRIC NITRATE
Company: POST APPLE SCIENTIFIC INC
Street: 8893 GULF ROAD
PO Box: UNKNOW
City: NORTH EAST PA
Zipcode: 16428-4298
Health Emergency Phone: 800-424-9300
Label Required IND: Y
Date Of Label Review: 06/05/2001
Status Code: A
Label Date: 06/04/2001
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: OXIDIZING, CORROSIVE MATERIAL. CONTACT WITH COMBUSTIBLE
MATERIAL MAY CAUSE FIRE. CAUSES BURNS. HARMFUL BY INHALATION, SKIN CONTACT,
IF SWALLOWED. TARGET ORGANS: BLOOD, KIDNEYS. WEAR SUITABLE PROTECTIV E
CLOTHING, GLOVES, AND EYE/FACE PROTECTION.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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